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Received November 14, 2008
Accepted February 7, 2009
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Direct incorporation of vanadium into three-dimensional KIT-6: 1. Optimization of synthesis conditions
Division of Chemical Engineering, Pusan National University, Busan 609-735, Korea
dwpark@pusan.ac.kr
Korean Journal of Chemical Engineering, September 2009, 26(5), 1235-1240(6), 10.1007/s11814-009-0199-2
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Abstract
Three dimensional (3-D) cubic KIT-6 with directly incorporated vanadium was hydrothermally synthesized by using Pluronic P123 and n-butanol as the structure-directing mixture, tetraethyl orthosilicate (TEOS) as the silica source and NH4VO3 as the vanadium source. The molar composition was varied in the range of 0.017 P123/0.08-2.4 V/1.0-2.0 TEOS/1.31-1.70 BuOH/1.83-3.00 HCl/195 H2O. The orderness of mesopore structure was estimated by X-ray diffraction, N2 adsorption, and TEM analysis. The effects of the amount of HCl, TEOS and BuOH on the structure of KIT-6 were discussed. The time and temperature for the synthesis of KIT-6 were also optimized. The amount of vanadium content influenced the framework structure and crystallinity of the Ia3d phase significantly.
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Mathieu M, Van Der Voort P, Weckhuysen BM, Rao RR, Catana G, Schoonheydt RA, Vansant EF, J. Phys. Chem. B, 105(17), 3393 (2001)
