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Received December 9, 2008
Accepted February 10, 2009
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Direct incorporation of vanadium into three-dimensional KIT-6: 2. Reactivity test for styrene oxidation
Balasamy Rabindran Jermy
Sang-Yun Kim
Kanattukara Vijayan Bineesh
Manickam Selvaraj
Seung-Kug Song
Jong-Woo Ryu
Dae-Won Park†
Division of Chemical Engineering, Pusan National University, Busan 609-735, Korea
dwpark@pusan.ac.kr
Korean Journal of Chemical Engineering, September 2009, 26(5), 1241-1245(5), 10.1007/s11814-009-0202-y
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Abstract
The direct incorporation of vanadium into the three-dimensional (3-D) cubic Ia3d mesostructure designated as V-KIT-6 was prepared, and the material obtained therein showed a very high specific surface area of ~1,000 m2/g with tunable pore diameters in a narrow distribution of sizes, ~5.7 to 6.0 nm. The coordination and nature of the V sites in V-KIT-6 were characterized by 51V-spin-echo NMR analysis. It shows that after calcination, the V^(4+) species are totally oxidized to the V^(5+) state with 4- and 6-coordinated V-O environments in a highly dispersed state with much less crystalline V2O5 formation. The calcined V-KIT-6 materials showed excellent catalytic activity in the direct oxidation of styrene using tert-butyl hydroperoxide (TBHP) as an oxidant.
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Du GA, Lim SY, Yang YH, Wang C, Pfefferle L, Haller GL, Appl. Catal. A: Gen., 302(1), 48 (2006)
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Kim TW, Kleitz F, Paul B, Ryoo R, J. Am. Chem. Soc., 127(20), 7601 (2005)
Kanmani AS, Vancheesan S, J. Mol. Catal. A: Chem., 150, 95 (1999)
Alajlouni AM, Espenson JH, J. Am. Chem. Soc., 117(36), 9243 (1995)
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Mathieu M, Van Der Voort P, Weckhuysen BM, Rao RR, Catana G, Schoonheydt RA, Vansant EF, J. Phys. Chem. B, 105(17), 3393 (2001)
Knotek P, Capek L, Bulanek R, Adam J, Topics in Catal., 45, 51 (2007)
Eckert H, Wachs IE, J. Phys. Chem., 93, 6796 (1989)
Tuel A, Ben Taarit Y, Appl. Catal. A: Gen., 102, 201 (1993)
Zhang LX, Hua ZL, Dong XP, Li L, Chen HR, Shi JL, J. Mol. Catal. A-Chem., 268(1-2), 155 (2007)
