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Received January 8, 2009
Accepted February 10, 2009
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Absorption of carbon dioxide into glycidyl methacrylate solution with quaternary onium salts
Division of Chemical Engineering, Pusan National University, Busan 609-735, Korea 1School of Environmental Science, Catholic University of Pusan, Busan 609-757, Korea
swpark@pusan.ac.kr
Korean Journal of Chemical Engineering, September 2009, 26(5), 1359-1364(6), 10.1007/s11814-009-0201-z
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Abstract
Carbon dioxide was absorbed into organic solutions of glycidyl methacrylate (GMA) in a semi-batch stirred tank with a plane gas-liquid interface at 101.3 kPa to measure absorption rates of carbon dioxide, from which the reaction kinetics between carbon dioxide and GMA with quaternary onium salts as catalysts was obtained. The reaction rate constants were estimated by the mass transfer mechanism accompanied by the pseudo-first-order reaction method. An empirical correlation formula between the reaction rate constants and the solubility parameters of solvents such as toluene, N-methyl-2-pirrolidinone, and dimethyl sulfoxide was presented.
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Peppel WJ, Ind. Eng. Chem., 50, 767 (1950)
Rokicki G, Makromol. Chem., 186, 331 (1985)
Aida T, Inoue S, J. Am. Chem. Soc., 105, 1304 (1983)
Nishikubo Y, Kato T, Sugimoto S, Tomoi M, Ishigaki S, Macromolecules, 23, 3406 (1990)
Kihara N, Endo T, Macromolecules, 25, 4824 (1992)
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Daraiswany LK, Sharma MM, Heterogeneous reaction: Analysis, example and reactor design, John Wiley & Sons, New York (1980)
Park SW, Choi BS, Lee BD, Park DW, Kim SS, Sep. Sci. Technol., 41(5), 829 (2006)
Park SW, Park DW, Lee JW, Korean J. Chem. Eng., 23(4), 645 (2006)
Park SW, Choi BS, Park DW, Lee JW, React. Kinet. Catal. Lett., 90(2), 215 (2007)
Park SW, Choi BS, Park DW, Lee JW, React. Kinet. Catal. Lett., 91(1), 101 (2007)
Park SW, Choi BS, Park DW, Oh KJ, Lee JW, Green Chem., 9, 605 (2007)
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Brandrup J, Immergut EH, Polymer handbook, Second Ed., John Wiley & Sons, New York (1975)
Starks CM, Liotta CL, Halpern M, Phase-transfer catalysis, Chapman & Hall, New York (1994)
