Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received August 7, 2008
Accepted May 7, 2009
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Study of pyrolysis kinetics of Alberta oil sand by thermogravimetric analysis
Greenhouse Gas Research Center, Korea Institute of Energy Reserch, 102 Gajeong-ro, Yuseong-gu, Daejeon 305-343, Korea
dshun@kier.re.kr
Korean Journal of Chemical Engineering, November 2009, 26(6), 1608-1612(5), 10.1007/s11814-009-0277-5
Download PDF
Abstract
The kinetics of the thermal decomposition of Alberta oil sand has been investigated by thermogravimetric analysis (TGA) for the study of oil sand pyrolysis characteristics. The TGA experiments were carried out at four different heating rates of 10, 20, 30, 40 ℃/min up to 900 ℃ to verify weight variation and reaction temperature. The activation energy of the thermal decomposition of Alberta oil sand obtained from the kinetic analysis was similar to that_x000D_
of the previous researches. Also, bitumen was extracted by solvent (toluene, THF (tetrahydrofuran)) and analyzed. Extracted bitumen was analyzed by using proximate analysis, ultimate analysis, heavy metal analysis, heating value, asphaltenes, API, SIMDIS, density, TLC, and molecular weight. The analyses of the extracted bitumen were similar to those of heavy residue.
References
Masiliyah J, Zhou Z, Xu Z, Czarnecki J, Hamza H, Can. J. Chem., 82, 628 (2004)
Pakdel H, Roy C, Energy Fuels, 17(5), 1145 (2003)
Ball DL, Cooke ED, Cooley JM, Hamilton MC, Schutte R, Can. J. Chem., 59, 1527 (1981)
Khraisha YH, Int. J. Energy Res., 21, 201 (1997)
Fletcher JV, Deo MD, Hanson FV, Fuel, 74, 311 (1995)
Hanson FV, Cha SM, Deo MD, Oblad AG, Fuel, 71, 1455 (1992)
Khraisha YH, Int. J. Energy Res., 23(10), 833 (1999)
Li S, Wang J, Tan H, Wu Z, Fuel, 74, 1191 (1995)
Meng M, Hu HQ, Zhang QM, Li X, Wu B, Energy Fuels, 21(4), 2245 (2007)
Braun RL, Burnham AK, Fuel, 65, 218 (1986)
Dogan OM, Uysal BZ, Fuel, 75, 1424 (1996)
Haddadin RA, Mizyed FA, Ind. & Eng. Chem. Pro. Des. and Develop., 13, 332 (1974)
Li S, Yue C, Fuel, 82, 337 (2003)
Li SY, Yue CT, Fuel Process. Technol., 85(1), 51 (2004)
Skala D, Kopsch H, Sokic M, Neumann HJ, Jovanovic JA, Fuel, 66, 1185 (1987)
Skala D, Kopsch H, Sokic M, Neumann HJ, Jovanovic JA, Fuel, 69, 490 (1990)
Torrente MC, Galan MA, Fuel, 80(3), 327 (2001)
Williams PT, Ahmad N, Appl. Energy, 66(2), 113 (2000)
Ritchie RGS, Roche RS, Steedman W, Fuel, 64, 391 (1985)
Sonibare OO, Egashira R, Adedosu TA, Thermochim. Acta, 405(2), 195 (2003)
Vorndran LDL, Serres AJ, Donnelly JK, Moore RG, Bennion D, Can. J. Chem., 58, 580 (1980)
Ryu HJ, Lim NY, Bae DH, Jin GT, Korean J. Chem. Eng., 20(1), 157 (2003)
Jervis RE, Richard Ho KL, Tiefenbach B, Journal of Radioanalytical Chemistry, 71, 225 (1982)
Pakdel H, Roy C, Energy Fuels, 17(5), 1145 (2003)
Ball DL, Cooke ED, Cooley JM, Hamilton MC, Schutte R, Can. J. Chem., 59, 1527 (1981)
Khraisha YH, Int. J. Energy Res., 21, 201 (1997)
Fletcher JV, Deo MD, Hanson FV, Fuel, 74, 311 (1995)
Hanson FV, Cha SM, Deo MD, Oblad AG, Fuel, 71, 1455 (1992)
Khraisha YH, Int. J. Energy Res., 23(10), 833 (1999)
Li S, Wang J, Tan H, Wu Z, Fuel, 74, 1191 (1995)
Meng M, Hu HQ, Zhang QM, Li X, Wu B, Energy Fuels, 21(4), 2245 (2007)
Braun RL, Burnham AK, Fuel, 65, 218 (1986)
Dogan OM, Uysal BZ, Fuel, 75, 1424 (1996)
Haddadin RA, Mizyed FA, Ind. & Eng. Chem. Pro. Des. and Develop., 13, 332 (1974)
Li S, Yue C, Fuel, 82, 337 (2003)
Li SY, Yue CT, Fuel Process. Technol., 85(1), 51 (2004)
Skala D, Kopsch H, Sokic M, Neumann HJ, Jovanovic JA, Fuel, 66, 1185 (1987)
Skala D, Kopsch H, Sokic M, Neumann HJ, Jovanovic JA, Fuel, 69, 490 (1990)
Torrente MC, Galan MA, Fuel, 80(3), 327 (2001)
Williams PT, Ahmad N, Appl. Energy, 66(2), 113 (2000)
Ritchie RGS, Roche RS, Steedman W, Fuel, 64, 391 (1985)
Sonibare OO, Egashira R, Adedosu TA, Thermochim. Acta, 405(2), 195 (2003)
Vorndran LDL, Serres AJ, Donnelly JK, Moore RG, Bennion D, Can. J. Chem., 58, 580 (1980)
Ryu HJ, Lim NY, Bae DH, Jin GT, Korean J. Chem. Eng., 20(1), 157 (2003)
Jervis RE, Richard Ho KL, Tiefenbach B, Journal of Radioanalytical Chemistry, 71, 225 (1982)
