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Received March 7, 2009
Accepted March 29, 2009
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Adsorption of zinc (II), cadmium (II), and copper (II) with PTFE Selective Resin containing primary amine N1923 and Cyanex925
College of Chemistry, Jilin University, Changchun 130022, China
jiaqiong@jlu.edu.cn
Korean Journal of Chemical Engineering, November 2009, 26(6), 1729-1732(4), 10.1007/s11814-009-0241-4
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Abstract
In the present study, a synergistic extraction mixture, primary amine N1923 (RNH2) and Cyanex925 (B), was loaded on PTFE powder to prepare PTFE Selective Resin and was employed for the adsorption of zinc, cadmium, and copper from chloride medium. The effects of shaking time, resin amounts, concentration of metal ions, and experimental temperature on the distribution coefficients were determined. The stoichiometry of the adsorbed complexes was_x000D_
determined to be MCl2·(1/2)RNH2·B with the Selective Resin. The equilibrium constants and thermodynamic quantities (ΔH, ΔG, and ΔS) were calculated. Furthermore, the Freundlich isotherm proved to be more suitable than the Langmuir isotherm to indicate the effect of concentration of M2+ on the adsorption with PTFE Selective Resin.
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Djati UH, Hunter KA, Environ. Technol., 27, 25 (2006)
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Vullo DL, Ceretti HM, Daniel MA, Ramirez SAM, Zalts A, Bioresour. Technol., 99, 5574 (2008)
Kim TY, Park SK, Cho SY, Kim HB, Kang Y, Kim SD, Kim SJ, Korean J. Chem. Eng., 22(1), 91 (2005)
Son BC, Park K, Song SH, Yoo YJ, Korean J. Chem. Eng., 21(6), 1168 (2004)
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Stafiej A, Pyrzynska K, Microchem. J., 89, 29 (2007)
Andersen MK, Raulund-Rasmussen K, Strobel BW, Hansen HCB, J. Environ. Qual., 31, 168 (2002)
Wang ZH, Zhang ZP, Wang ZP, Liu LW, Yan XP, Anal. Chim. Acta., 514, 151 (2004)
Fan J, Qin YX, Ye CL, Peng PA, Wu CL, J. Hazard. Mater., 150, 343 (2008)
Kim JS, Chah S, Yi J, Korean J. Chem. Eng., 17(1), 118 (2000)
Pehlivan E, Altun T, J. Hazard. Mater., 140(1-2), 299 (2007)
Lin LC, Juang RS, Chem. Eng. J., 132(1-3), 205 (2007)
Komjarova I, Blust R, Anal. Chim. Acta., 576, 221 (2006)
Rengaraj S, Kim Y, Joo CK, Choi K, Yi J, Korean J. Chem. Eng., 21(1), 187 (2004)
Cortina JL, Miralles N, Aguilar M, Sastre AM, Hydrometallurgy, 40, 195 (1996)
Kabay N, Demircioglu M, Ekinci H, Yuksel M, Saglam M, Streat M, React. Funct. Polym., 38(2), 219 (1998)
Jia Q, Wang ZH, Li DQ, Niu CJ, Sep. Sci. Technol., 38(9), 2025 (2003)
Duan TC, Song XJ, Jin D, Li HF, Xu JW, Chen HT, Talanta, 67, 968 (2005)
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Liao CF, Jiao YF, Qiu DF, Xue JL, J. Chin. Rare Earth Soc., 25, 249 (2007)
Luo WJ, Xie JL, Tian F, Wu JP, Ion Exch. Adsorpt., 19, 547 (2003)
Wang ZL, Zhu JL, Wang XH, Li ZJ, Chin. J. Spectrosc. Lab., 13, 38 (1996)
Preston JS, Du Preez AC, Rep-MINTEK, M228, 43 (1985)
Le SM, Li DQ, Ni JZ, Chin. J. Inorg. Chem., 3, 80 (1987)
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Zhang TL, Ni JZ, Nonferrous Met., 40, 73 (1988)
Luo F, Li DQ, Wei PH, Hydrometallurgy, 73, 31 (2004)