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Received October 3, 2008
Accepted April 8, 2009
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Preparation of molecularly imprinted polymer membrane with blending trimethoprim-MIP and polysulfone and its transport properties
Key Laboratory of Hollow Fiber Membrane Materials and Membrane Process of the Ministry of Education,School of Materials Science and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300160, China
Korean Journal of Chemical Engineering, November 2009, 26(6), 1813-1820(8), 10.1007/s11814-009-0256-x
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Abstract
An imprinted polymer membrane (IPM) with blending trimethoprim-MIP and polysulfone (PSF) was prepared by bulk polymerization and membrane preparation. In the process of the preparation, the influencing factors on membrane structure and properties, such as the concentration of PSF, the content of additive polyethelene glycol (PEG) and TMP imprinted polymer, were thoroughly investigated by scanning electron microscopy (SEM) and the membrane performance tester. The adsorption properties and selectivity properties of IPM to different substrates were estimated by using the method of equilibrium binding experiments. Finally, the transport properties of the membranes were investigated by using the diffusion chambers. The results showed that the imprinted polymer membrane exhibited a high selectivity for TMP.
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References
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Wulff G, Sarhan A, Zabrocki K, Tetrahedron Lett., 44, 4329 (1973)
Yoshikawa M, Izumi J, Kitao T, React. Funct. Polym., 42(1), 93 (1999)
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Ramamoorthy M, Ulbricht M, J. Membr. Sci., 217(1-2), 207 (2003)
Malaisamy R, Ulbricht M, Sep. Purif. Technol., 39(3), 211 (2004)
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He X, He G, Zeng B, Sun H, Yang H, Chen S, Zhou H, Journal of Xiamen University (Natural Science), 40, 495 (2001)
Zhang Y, Technology of Water Treatment, 27, 99 (2001)
Zhou J, He X, Yang W, Shi H, Chemical Journal of Chinese Universities, 19, 1388 (1998)
Hawkins DM, Trache A, Ellis EA, Stevenson D, Holzenburg A, Meininger GA, Reddy SM, Biomacromolecules, 7(9), 2560 (2006)
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