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Received December 16, 2008
Accepted July 9, 2009
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Extraction of benzene from a narrow cut of naphtha via liquid-liquid extraction using pure-sulfolane and 2-propanol-sulfolane-mixed solvents
School of Chemical, Gas and Petroleum Engineering, Semnan University, Semnan, Iran
mnlotfollahi@semnan.ac.ir
Korean Journal of Chemical Engineering, January 2010, 27(1), 214-217(4), 10.1007/s11814-009-0328-y
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Abstract
The extraction of benzene from a narrow cut of naphtha produced by the Iranian petrochemical company has been studied at the operating temperatures of 40, 45 and 50 ℃, and four solvent-to-feed ratios (S/F) varied over the range of 1-4. Two extraction solvents, sulfolane as a pure-solvent and (sulfolane containing 7 wt% 2-propanol) as a mixed-solvent have been investigated for selective removal of benzene from the naphtha cut. The experimental results demonstrated that the mixed-solvent at 40 ℃ is a suitable solvent to replace sulfolane for an industrial extraction process for the separation of benzene from the naphtha cut because of its lower price and energy savings.
References
Uemasu I, Kushiyama S, Fuel Process. Technol., 85(13), 1519 (2004)
Alsahhaf TA, Kapetanovic E, Fluid Phase Equilib., 118(2), 271 (1996)
Meindersma GW, Podt AJG, de Haan AB, Fuel Process. Technol., 87(1), 59 (2005)
Radwan GM, Almuhtaseb SA, Fahim MA, Fluid Phase Equilib., 129(1-2), 175 (1997)
Domanska U, Pobudkowska A, Krolikowski M, Fluid Phase Equilib., 259(2), 173 (2007)
Lee SJ, Kim HY, J. Chem. Eng. Data, 40(2), 499 (1995)
Krummen M, Gmehling R, Fluid Phase Equilib., 215(2), 283 (2004)
Morawski P, Letcher TM, Naicker PK, J. Chem. Eng. Data, 47, 1453 (2002)
Wang W, Gou ZM, Zhu SL, J. Chem. Eng. Data, 43(1), 81 (1998)
Mohsen-Nia M, Modarress H, Doulabi F, Bagheri H, J. Chem. Thermodyn., 37(10), 1111 (2005)
Krishna R, Goswani AN, Nanoti SM, Rawat BS, Khanna MK, Dobhal J, Indian Journal of Technology, 25, 602 (1987)
Ali SH, Lababidi HMS, Merchant SQ, Fahim MA, Fluid Phase Equilib., 214(1), 25 (2003)
Chen DC, Ye HQ, Wu H, J. Chem. Thermodyn., 39(8), 1182 (2007)
Rappel R, de Gois LMN, Mattedi S, Fluid Phase Equilib., 202(2), 263 (2002)
Gaile AA, Zalishchevskii GD, Erzhenkov AS, Kayfadzhyan EA, Koldobskaya LL, Russian J. Appl. Chem., 80, 591 (2007)
Ko MS, Na S, Cho J, Kim H, Korean J. Chem. Eng., 19(6), 996 (2002)
Alsahhaf TA, Kapetanovic E, Fluid Phase Equilib., 118(2), 271 (1996)
Meindersma GW, Podt AJG, de Haan AB, Fuel Process. Technol., 87(1), 59 (2005)
Radwan GM, Almuhtaseb SA, Fahim MA, Fluid Phase Equilib., 129(1-2), 175 (1997)
Domanska U, Pobudkowska A, Krolikowski M, Fluid Phase Equilib., 259(2), 173 (2007)
Lee SJ, Kim HY, J. Chem. Eng. Data, 40(2), 499 (1995)
Krummen M, Gmehling R, Fluid Phase Equilib., 215(2), 283 (2004)
Morawski P, Letcher TM, Naicker PK, J. Chem. Eng. Data, 47, 1453 (2002)
Wang W, Gou ZM, Zhu SL, J. Chem. Eng. Data, 43(1), 81 (1998)
Mohsen-Nia M, Modarress H, Doulabi F, Bagheri H, J. Chem. Thermodyn., 37(10), 1111 (2005)
Krishna R, Goswani AN, Nanoti SM, Rawat BS, Khanna MK, Dobhal J, Indian Journal of Technology, 25, 602 (1987)
Ali SH, Lababidi HMS, Merchant SQ, Fahim MA, Fluid Phase Equilib., 214(1), 25 (2003)
Chen DC, Ye HQ, Wu H, J. Chem. Thermodyn., 39(8), 1182 (2007)
Rappel R, de Gois LMN, Mattedi S, Fluid Phase Equilib., 202(2), 263 (2002)
Gaile AA, Zalishchevskii GD, Erzhenkov AS, Kayfadzhyan EA, Koldobskaya LL, Russian J. Appl. Chem., 80, 591 (2007)
Ko MS, Na S, Cho J, Kim H, Korean J. Chem. Eng., 19(6), 996 (2002)