Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received May 11, 2009
Accepted June 11, 2009
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Adsorption of carbon dioxide onto PDA-CP-MS41 adsorbent
Division of Chemical Engineering, Pusan National University, Busan 609-735, Korea 1School of Environmental Science, Catholic University of Pusan, Busan 609-757, Korea
swpark@pusan.ac.kr
Korean Journal of Chemical Engineering, January 2010, 27(1), 241-248(8), 10.1007/s11814-009-0301-9
Download PDF
Abstract
Carbon dioxide was adsorbed onto mesoporous adsorbent of PDA-CP-MS41, which was synthesized by CP-MS41 with propylene diamine, in a laboratory-scale packed-bed. Experiments were carried out at different adsorption temperatures (30-60 ℃), amounts of adsorbent (1-3 g), and flow rates of nitrogen (15-60 cm3/min) to obtain the breakthrough curves of CO2. These curves were tested by the deactivation model, which combined the adsorption of CO2 and the deactivation of adsorbent particles. The adsorption rate constant and the deactivation rate constant were evaluated through analysis of the experimental breakthrough data using a nonlinear least squares technique. The experimental breakthrough data were fitted very well to the deactivation model than the adsorption isotherm models in the literature.
References
Aresta M, Carbon dioxide recovery and utilization, Kluwer academic Pub., Boston (2003)
Bartoo RK, Chem. Eng. Prog., 80, 35 (1984)
Fuchs W, Syosett NT, U. S. Patent 3,511,595 (1970)
Gidaspow D, Onischak M, U. S. Patent 3,865,924 (1975)
Hirano S, Shigomoto N, Yamada S, Hayashi H, Bull. Chem. Soc. Jpn., 68, 1030 (1995)
Hayashi H, Taniuchi J, Furuyashiki N, Sugiyama S, Hirano S, Shigemoto N, Nonaka T, Ind. Eng. Chem. Res., 37(1), 185 (1998)
Shigemoto N, Yanagihara T, Sugiyama S, Hayashi H, J. Chem. Eng. Jpn., 38(9), 711 (2005)
Okunev AG, Sharnov VE, Aristov YI, Parmon VN, React. Kinet. Catal. Lett., 71, 355 (2004)
Ruhl ML, Chem. Eng. Prog., 89, 1344 (1993)
Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature, 359, 710 (1992)
Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL, J. Am. Chem. Soc., 114, 10834 (1992)
Zhao DY, Feng JL, Huo QS, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD, Science, 279(5350), 548 (1998)
Bhaumik A, Tatsumi T, J. Catal., 189(1), 31 (2000)
Burkett SL, Sim SD, Mann SJ, J. Chem. Soc. Chem. Commun., 1367 (1996)
Lim MH, Blanford CF, Stein A, J. Am. Chem. Soc., 119(17), 4090 (1997)
Fowler CE, Lebeau B, Mann S, J. Chem. Soc. Chem. Commun., 1825 (1998)
Babonneau F, Leite L, Fontlupt S, J. Mater. Chem., 9, 175 (1999)
Huang HY, Yang RT, Chinn D, Munson CL, Ind. Eng. Chem. Res., 42(12), 2427 (2003)
Xu XC, Song CS, Miller BG, Scaroni AW, Fuel Process. Technol., 86(14-15), 1457 (2005)
Udayakumar S, Park SW, Park DW, Choi BS, Catal. Commun., 9, 1563 (2008)
Doraiswamyand LK, Sharma MM, Heterogeneous reactions, John Wiley & Sons, New York (1954)
Ishida M, Wen CY, AIChE J., 14, 311 (1968)
Pamachandran PA, Kulkarni BD, Ind. Eng. Chem. Res. Process Des. Dev., 19, 717 (1980)
Evans JW, Song S, Ind. Eng. Chem. Process Des. Dev., 13, 146 (1974)
Sampath BS, Ramachandran PA, Hughes R, Chem. Eng. Sci., 30, 135 (1975)
Ranade MG, Evans JW, Ind. Eng. Chem. Process Des. Dev., 19, 118 (1980)
Ruthven DM, Principles of adsorption and adsorption processes, John & Wiley, New York (1984)
Suzuki M, Adsorption engineering, Kodansga Ltd., Tokyo (1990)
Orbey N, Dogu G, Dogu T, Can. J. Chem. Eng., 60, 314 (1982)
Yasyerli N, Dogu T, Dogu G, Ar I, Chem. Eng. Sci., 51(11), 2523 (1996)
Kopac T, Kocabas S, Chem. Eng. Commun., 190(5-8), 1041 (2003)
Suyadal Y, Erol M, Oguz H, Ind. Eng. Chem. Res., 39(3), 724 (2000)
Park SW, Sung DH, Choi BS, Oh KJ, Moon KH, Sep. Sci. Technol., 41(12), 2665 (2006)
Park SW, Sung DH, Choi BS, Lee JW, Kumazawa H, J. Ind. Eng. Chem., 12(4), 522 (2006)
Park SW, Choi BS, Lee JW, Sep. Sci. Technol., 42(10), 2221 (2007)
Hwang KS, Park SW, Park DW, Oh KJ, Kim SS, Korean J. Chem. Eng., In Press.
Dogu T, AIChE J., 32, 849 (1986)
Leal O, Bolivar C, Ovalles C, Garcia JJ, Espidel Y, Inorganica Chimica Acta, 240, 183 (1995)
Yasyerli S, Dogu G, Ar I, Dogu T, Chem. Eng. Commun., 190(5-8), 1055 (2003)
Bartoo RK, Chem. Eng. Prog., 80, 35 (1984)
Fuchs W, Syosett NT, U. S. Patent 3,511,595 (1970)
Gidaspow D, Onischak M, U. S. Patent 3,865,924 (1975)
Hirano S, Shigomoto N, Yamada S, Hayashi H, Bull. Chem. Soc. Jpn., 68, 1030 (1995)
Hayashi H, Taniuchi J, Furuyashiki N, Sugiyama S, Hirano S, Shigemoto N, Nonaka T, Ind. Eng. Chem. Res., 37(1), 185 (1998)
Shigemoto N, Yanagihara T, Sugiyama S, Hayashi H, J. Chem. Eng. Jpn., 38(9), 711 (2005)
Okunev AG, Sharnov VE, Aristov YI, Parmon VN, React. Kinet. Catal. Lett., 71, 355 (2004)
Ruhl ML, Chem. Eng. Prog., 89, 1344 (1993)
Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature, 359, 710 (1992)
Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL, J. Am. Chem. Soc., 114, 10834 (1992)
Zhao DY, Feng JL, Huo QS, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD, Science, 279(5350), 548 (1998)
Bhaumik A, Tatsumi T, J. Catal., 189(1), 31 (2000)
Burkett SL, Sim SD, Mann SJ, J. Chem. Soc. Chem. Commun., 1367 (1996)
Lim MH, Blanford CF, Stein A, J. Am. Chem. Soc., 119(17), 4090 (1997)
Fowler CE, Lebeau B, Mann S, J. Chem. Soc. Chem. Commun., 1825 (1998)
Babonneau F, Leite L, Fontlupt S, J. Mater. Chem., 9, 175 (1999)
Huang HY, Yang RT, Chinn D, Munson CL, Ind. Eng. Chem. Res., 42(12), 2427 (2003)
Xu XC, Song CS, Miller BG, Scaroni AW, Fuel Process. Technol., 86(14-15), 1457 (2005)
Udayakumar S, Park SW, Park DW, Choi BS, Catal. Commun., 9, 1563 (2008)
Doraiswamyand LK, Sharma MM, Heterogeneous reactions, John Wiley & Sons, New York (1954)
Ishida M, Wen CY, AIChE J., 14, 311 (1968)
Pamachandran PA, Kulkarni BD, Ind. Eng. Chem. Res. Process Des. Dev., 19, 717 (1980)
Evans JW, Song S, Ind. Eng. Chem. Process Des. Dev., 13, 146 (1974)
Sampath BS, Ramachandran PA, Hughes R, Chem. Eng. Sci., 30, 135 (1975)
Ranade MG, Evans JW, Ind. Eng. Chem. Process Des. Dev., 19, 118 (1980)
Ruthven DM, Principles of adsorption and adsorption processes, John & Wiley, New York (1984)
Suzuki M, Adsorption engineering, Kodansga Ltd., Tokyo (1990)
Orbey N, Dogu G, Dogu T, Can. J. Chem. Eng., 60, 314 (1982)
Yasyerli N, Dogu T, Dogu G, Ar I, Chem. Eng. Sci., 51(11), 2523 (1996)
Kopac T, Kocabas S, Chem. Eng. Commun., 190(5-8), 1041 (2003)
Suyadal Y, Erol M, Oguz H, Ind. Eng. Chem. Res., 39(3), 724 (2000)
Park SW, Sung DH, Choi BS, Oh KJ, Moon KH, Sep. Sci. Technol., 41(12), 2665 (2006)
Park SW, Sung DH, Choi BS, Lee JW, Kumazawa H, J. Ind. Eng. Chem., 12(4), 522 (2006)
Park SW, Choi BS, Lee JW, Sep. Sci. Technol., 42(10), 2221 (2007)
Hwang KS, Park SW, Park DW, Oh KJ, Kim SS, Korean J. Chem. Eng., In Press.
Dogu T, AIChE J., 32, 849 (1986)
Leal O, Bolivar C, Ovalles C, Garcia JJ, Espidel Y, Inorganica Chimica Acta, 240, 183 (1995)
Yasyerli S, Dogu G, Ar I, Dogu T, Chem. Eng. Commun., 190(5-8), 1055 (2003)
