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Received July 2, 2009
Accepted July 6, 2009
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Calculation of phase equilibrium for water+carbon dioxide system using nonrandom lattice fluid equation of state
Department of Chemical and Biological Engineering, Korea University, 5-1, Anam-dong, Sungbuk-gu, Seoul 136-701, Korea 1Department of Chemical Engineering, Yonsei University, Shinchon-dong, Seodaemun-gu, Seoul 120-749, Korea
jwkagn@korea.ac.kr
Korean Journal of Chemical Engineering, January 2010, 27(1), 278-283(6), 10.1007/s11814-009-0326-0
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Abstract
For the geological sequestration of carbon dioxide to prevent global warming, the phase equilibrium data for water and carbon dioxide mixture play an important role in process design and operation. In this work, the nonrandom lattice fluid equation of state with hydrogen bonding (NLF-HB EOS) was applied for the prediction of phase equilibrium of mixtures containing water and carbon dioxide. A new set of pure component parameters for carbon dioxide above critical condition was found and optimum binary interaction parameters were reported to correlate mutual_x000D_
solubility of mixtures. The calculated results were compared with the Peng-Robinson Equation of State with the conventional mixing rule (PR-EOS) and the Wong-Sandler mixing rule (PR-WS-EOS). The calculation results show that NLF-HB EOS can correlate mutual solubility of water+carbon dioxide mixtures with reasonable accuracy within a single theoretical framework.
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