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Received April 14, 2009
Accepted May 23, 2009
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NO oxidation over supported cobalt oxide catalysts
Division of Energy Systems Research and Division of Chemical Engineering and Materials Engineering, Ajou University, San 5 Wonchun-dong, Yeongtong-gu, Suwon 443-749, Korea 1ivision of Applied Biotechnology, Ajou University, San 5 Wonchun-dong, Yeongtong-gu, Suwon 443-749, Korea
edpark@ajou.ac.kr
Korean Journal of Chemical Engineering, January 2010, 27(1), 49-54(6), 10.1007/s11814-009-0290-8
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Abstract
NO oxidation was conducted over cobalt oxides supported on various supports such as SiO2, ZrO2, TiO2, and CeO2. The N2 physisorption, an inductively coupled plasma-atomic emission spectroscopy (ICP-AES), X-ray diffraction (XRD), NO chemisorptions, the temperature-programmed desorption (TPD) with a mass spectroscopy after NO or CO chemisorptions were conducted to characterize catalysts. Among tested catalysts, Co3O4 supported on ceria with a high surface area showed the highest catalytic activity. This catalyst showed superior catalytic activity to unsupported Co3O4 with a high surface area and 1 wt% Pt/γ-Al2O3. For ceria-supported Co3O4, the catalytic activity, the NO uptake at 298 K and the dispersion of Co3O4 increased with increasing the surface area of CeO2. The active participation of the lattice oxygen in NO oxidation could not be observed. On the other hand, the lattice oxygen participated in the CO oxidation over the same catalyst. The deactivation was observed over Co3O4/CeO2 and 1 wt% Pt/γ-Al2O3 in the presence of SO2 in a feed. 1 wt% Pt/γ-Al2O3 was deactivated by SO2 more rapidly compared with Co3O4/CeO2.
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References
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Koebel M, Elsener M, Kleemann M, Catal. Today, 59(3-4), 335 (2000)
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Amiridis MD, Zhang TJ, Farrauto RJ, Appl. Catal. B: Environ., 10(1-3), 203 (1996)
Castagnola MJ, Neylon MK, Marshall CL, Catal. Today, 96(1-2), 61 (2004)
Regalbuto JR, Zheng T, Miller JT, Catal. Today, 54(4), 495 (1999)
Meunier FC, Ross JRH, Appl. Catal. B: Environ., 24(1), 23 (2000)
Petunchi JO, Hall WK, Appl. Catal. B: Environ., 2, L17 (1993)
Stakheev AY, Lee CW, Park SJ, Chong PJ, Catal. Lett., 38(3-4), 271 (1996)
Stakheev AY, Lee CW, Park SJ, Chong PJ, Appl. Catal. B: Environ., 9(1-4), 65 (1996)
Park PW, Ragle CS, Boyer CL, Balmer ML, Engelhard M, McCready D, J. Catal., 210(1), 97 (2002)
Ohtsuka H, Appl. Catal. B: Environ., 33(4), 325 (2001)
Jayat F, Lembacher C, Schubert U, Martens JA, Appl. Catal. B: Environ., 21(3), 221 (1999)
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Dawody J, Skoglundh M, Fridell E, J. Mol. Catal. A-Chem., 209(1-2), 215 (2004)
Crocoll M, Kureti S, Weisweiler W, J. Catal., 229(2), 480 (2005)
Ji YY, Toops TJ, Graham UM, Jacobs G, Crocker M, Catal. Lett., 110(1-2), 29 (2006)
Schmitz PJ, Kudla RJ, Drews AR, Chen AE, Lowe-Ma CK, McCabe RW, Schneider WF, Goralski CT, Appl. Catal. B: Environ., 67(3-4), 246 (2006)
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Xue E, Seshan K, Ross JR, Appl. Catal. B: Environ., 11(1), 65 (1996)
Xue E, Seshan K, van Ommen JG, Appl. Catal. B: Environ., 2, 183 (1993)
Mulla SS, Chen N, Cumaranatunge L, Blau GE, Zemlyanov DY, Delgass WN, Epling WS, Ribeiro FH, J. Catal., 241(2), 389 (2006)
Li LD, Qu LL, Cheng J, Li JJ, Hao ZP, Appl. Catal. B: Environ., 88(1-2), 224 (2009)
Bennici S, Gervasini A, Appl. Catal. B: Environ., 62(3-4), 336 (2006)
Suarez S, Jung SM, Avila P, Grange P, Blanco J, Catal. Today, 75(1-4), 331 (2002)
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Kikuchi E, Yogo K, Catal. Today, 22, 73 (1994)
Brosius R, Habermacher D, Martens JA, Vradman L, Herskowitz M, apek L, Sobalik Z, Dedecek J, Wichterlova B, Tokarova, Gonsiorov O, Topics Catal., 30-31, 333 (2004)
Capek L, Vradman L, Sazama P, Herskowitz M, Wichterlova B, Zukerman R, Brosius R, Martens JA, Appl. Catal. B: Environ., 70(1-4), 53 (2007)
Yan JY, Kung HH, Sachtler WMH, Kung MC, J. Catal., 175(2), 294 (1998)
Bagnasco G, Turco M, Resini C, Montanari T, Bevilacqua M, Busca G, J. Catal., 225(2), 536 (2004)
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Yung MM, Holmgreen EM, Ozkan US, J. Catal., 247(2), 356 (2007)
Wang Q, Park SY, Choi JS, Chung JS, Appl. Catal. B: Environ., 79(2), 101 (2008)
Wang Q, Park SY, Duan L, Chung JS, Appl. Catal. B: Environ., 85(1-2), 10 (2008)
Irfan MF, Goo JH, Kim SD, Appl. Catal. B: Environ., 78(3-4), 267 (2008)
Bergeret G, Gallezot P, in Handbook of heterogeneous catalysis, Ertl G, Knozinger H, Weitkamp J Eds., VCH, New York, 446-450 (1997)
