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Received June 16, 2009
Accepted October 15, 2009
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Rheological property and curing behavior of poly(amide-co-imide)/multi-walled carbon nanotube composites
Research Institute of Advanced Materials (RIAM), Department of Materials Science and Engineering, Seoul National University, Seoul 151-744, Korea 1The Technology Commercialization Center, Hyosung Corporation, Anyang-si, Gyeonggi-do 431-080, Korea 2Advanced Materials Division, Korea Research Institute of Chemical Technology, P.O. Box 107, Yuseong, Daejeon 305-600, Korea
Korean Journal of Chemical Engineering, February 2010, 27(2), 658-665(8), 10.1007/s11814-010-0097-7
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Abstract
Poly(amide-co-imide) (PAI)/multi-walled carbon nanotube (MWCNTs) composites were prepared by using solution mixing with ultrasonication excitation in order to investigate effects of MWCNTs on rheological properties and thermal curing behavior. Steady shear viscosity of the composite showed bell shaped curves with three characteristic patterns: shear thickening, shear thinning, and Newtonian plateau behavior. Both storage modulus and complex viscosity were increased due to higher molecular interaction than that of the pure PAI resin. Especially, hydrogen peroxide treated MWCNT/PAI composites had the highest storage modulus and complex viscosity. Glass transition temperature of the PAI/MWCNT composite was increased with increasing MWCNT content and thermal curing time since the mobility of PAI molecules was reduced as more constraints were generated in PAI molecular chains. It was found that thermal curing conditions of PAI/MWCNT composites are determined by considering effects of weight fraction and surface modification of MWCNTs on internal structure and thermal properties.
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Dealy JM, Wissbrun KF, Melt rheology and its role in plastics processing, Van Nostrand Reinhold, New York (1990)
Lee SH, Kim JH, Choi SH, Kim SY, Kim KW, Youn JR, Polym. Int., 58, 354 (2009)
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Gupta RK, Polymer and composite rheology, Marcel Dekker, New York (2000)
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Xiao KQ, Zhang LC, Zarudi I, Compos. Sci. Technol., 67, 177 (2007)
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Ghosh MK, Mittal KL, Polyimide: Fundamentals and applications, Marcel Dekker, New York (1996)
Chan KC, Chang TC, Polym. J., 30, 897 (1998)
Cai H, Yan F, Xue Q, Mater. Sci. Eng. A, 364, 94 (2004)
Menard KP, Dynamic mechanical analysis: A practical introduction, CRC Press, Boca Raton, FL (1999)
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Feng QP, Xie XM, Liu YT, Zhao W, Gao YF, J. Appl. Polym. Sci., 106(4), 2413 (2007)
Vigolo B, Mamane V, Valsaque F, Le TNH, Thabit J, Ghanbaja J, Aranda L, Fort Y, McRaea E, Carbon, 47, 411 (2009)
