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Received September 1, 2009
Accepted October 5, 2009
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Dispersion polymerization of N-vinyl-2-pyrrolydone using fluorine-based surfactants in supercritical carbon dioxide
School of Chemical and Biological Engineering and Institute of Chemical Processes, Seoul National University, 559 Gwanangno, Gwanak-gu, Seoul 151-744, Korea 1R&D Institute, Miwon Specialty Chemical Co., Ltd., 405-3, Moknae-dong, Ansan-si, Gyeonggi 425-100, Korea
Korean Journal of Chemical Engineering, March 2010, 27(3), 1021-1027(7), 10.1007/s11814-010-0137-3
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Abstract
We carried out a dispersion polymerization of N-vinyl-2-pyrrolydone using fluorine-based surfactants, which included poly(heptadecafluorodecyl acrylate) (PHDFDA) or poly(heptadecafluorodecyl methacrylate) (PHDFDMA) in supercritical carbon dioxide (scCO2). An FE-SEM and an image analyzer were used to characterize particle morphology, size, and size distribution of the resulting polymer taking into account effect of the surfactant, initiator, and monomer concentrations.
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Hsiao YL, Maury EE, Desimone JM, Mawson S, Johnston KP, Macromolecules, 28(24), 8159 (1995)
Carson T, Lizotte J, Desimone JM, Macromolecules, 33(6), 1917 (2000)
McHugh MA, Krukonis VJ, Supercritical fluid extraction: principle and practice, 2nd Ed. Butterworth-Heinemann, Boston. (1994)
Cooper AI, J. Mater. Chem., 10, 207 (2000)
Beckman EJ, J. Supercrit. Fluids, 28(2-3), 121 (2004)
Kendall JL, Canelas DA, Young JL, DeSimone JM, Chem. Rev., 99(2), 543 (1999)
Canelas DA, Betts DE, DeSimone JM, Macromolecules., 28, 2818 (1996)
Shiho H, DeSimone JM, J. Polym. Sci. A: Polym. Chem., 37(14), 2429 (1999)
Tseng CM, Lu YY, El-Aasser MS, Vanderhoff JW, J.Polym. Sci., Part A: Polym. Chem. Ed., 24, 2995 (1986)
Kawaguchi S, Ito KJ, Adv. Poym. Sci., 175, 299 (2005)
Saenx JM, Asua JM, J. Polym. Sci., Part A: Polym. Chem., 33, 1511 (2000)
Carson T, Lizotte J, Desimone JM, Macromolecules, 33(6), 1917 (2000)
Galia A, Giaconia A, Iaia V, Filardo G, J. Polym. Sci. A: Polym. Chem., 42(1), 173 (2004)
Berger T, McGhee B, Scherf U, Steffen W, Macromolecules, 33(10), 3505 (2000)
Kwon S, Lee K, Bae W, Kim H, J. Supercrit. Fluids, 45(3), 391 (2008)
Shin S, Bae W, Lee YW, Kim H, Korean J. Chem. Eng., 24(4), 664 (2007)
Shin J, Oh KS, Bae W, Lee YW, Kim H, Ind. Eng. Chem. Res., 47(15), 5680 (2008)
Saenx JM, Asua JM, J. Polym. Sci., Part A: Polym. Chem., 33, 1511 (2000)
Shin J, Bae W, Lee YW, Kim H, J. Chem. Eng. Data., 51, 1571 (2006)
Shin J, Bae W, Kim H, Lee YW, J. Chem. Eng. Data., 53, 1523 (2008)
Bae W, Kwon SY, Byun HS, Kim HY, J. Supercrit. Fluids, 30(2), 127 (2004)
Hsiao YL, Maury EE, Desimone JM, Mawson S, Johnston KP, Macromolecules, 28(24), 8159 (1995)
Carson T, Lizotte J, Desimone JM, Macromolecules, 33(6), 1917 (2000)
