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Received September 14, 2009
Accepted November 2, 2009
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Adsorption of carbon dioxide onto BDA-CP-MS41
Division of Chemical Engineering, Pusan National University, Busan 609-735, Korea 1School of Environmental Science, Catholic University of Pusan, Busan 609-757, Korea
swpark@pusan.ac.kr
Korean Journal of Chemical Engineering, March 2010, 27(3), 962-969(8), 10.1007/s11814-010-0152-4
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Abstract
Carbon dioxide was adsorbed onto mesoporous adsorbent of butylene diamine immobilized CP-MS41 (BDA-CP-MS41), which was synthesized by chloropropyl functionalized MCM-41 (CP-MS41) with butylene diamine in a laboratory-scale packed-bed. The adsorber was operated batchwise with the charge of adsorbent in the range of 1-3 g to obtain the breakthrough curves of CO2. Experiments were carried out at different adsorption temperatures (20-40 ℃) and flow rates of nitrogen (10-20 cm3/min) to investigate the effects of these experimental variables on the breakthrough curves. The deactivation model was tested for these curves by combining the adsorption of CO2 and the deactivation of adsorbent particles. The observed values of the adsorption rate constant and the deactivation rate constant were evaluated through analysis of the experimental breakthrough data using a nonlinear least squares technique. The experimental breakthrough data fitted very well to the deactivation model than the adsorption isotherm models_x000D_
in the literature.
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Hayashi H, Taniuchi J, Furuyashiki N, Sugiyama S, Hirano S, Shigemoto N, Nonaka T, Ind. Eng. Chem. Res., 37(1), 185 (1998)
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Okunev AG, Sharnov VE, Aristov YI, Parmon VN, React. Kinet. Catal. Lett., 71, 335 (2004)
Ruhl ML, Chem. Eng. Prog., 89, 1344 (1993)
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Bhaumik A, Tatsumi T, J. Catal., 189(1), 31 (2000)
Burkett SL, Sim SD, Mann SJ, J. Chem. Soc. Chem. Commun., 1367 (1996)
Lim MH, Blanford CF, Stein A, J. Am. Chem. Soc., 119(17), 4090 (1997)
Fowler CE, Lebeau B, Mann S, J. Chem. Soc. Chem. Commun., 1825 (1998)
Babonneau F, Leite L, Fontlupt S, J. Mater. Chem., 9, 175 (1999)
Huang HY, Yang RT, Chinn D, Munson CL, Ind. Eng. Chem. Res., 42(12), 2427 (2003)
Xu XC, Song CS, Miller BG, Scaroni AW, Fuel Process. Technol., 86(14-15), 1457 (2005)
Yu JI, Ju HY, Kim KH, Park DW, Korean J. Chem. Eng., 27(2), 446 (2010)
Hwang KS, Son YS, Park SW, Park DW, Oh KJ, Kim SS, Sep. Sci. Technol., 45(1), 85 (2010)
Hwang KS, Han L, Park DW, Oh KJ, Kim SS, Park SW, Korean J. Chem. Eng., 27(1), 241 (2010)
Doraiswamy LK , Sharma MM, Heterogeneous reactions, John Wiley & Sons, New York (1954)
Ishida M, Wen CY, AIChE J., 14, 311 (1968)
Pamachandran PA, Kulkarni BD, Ind. Eng. Chem. Res. Process Des. Dev, 19, 717 (1980)
Evans JW, Song S, Ind. Eng. Chem. Process Des. Dev., 13, 146 (1974)
Sampath BS, Ramachandran PA, Hughes R, Chem. Eng.Sci., 30, 135 (1975)
Ranade MG, Evans JW, Ind. Eng. Chem. Process Des.Dev., 19, 118 (1980)
Ruthven DM, Principles of adsorption and adsorption processes, John & Wiley, New York (1984)
Suzuki M, Adsorption engineering, Kodansga Ltd., Tokyo (1990)
Orbey N, Dogu G, Dogu T, Can. J. Chem. Eng, 60, 314 (1982)
Yasyerli N, Dogu T, Dogu G, Ar I, Chem. Eng. Sci., 51(11), 2523 (1996)
Kopac T, Kocabas S, Chem. Eng. Commun., 190(5-8), 1041 (2003)
Suyadal Y, Erol M, Oguz H, Ind. Eng. Chem. Res., 39(3), 724 (2000)
Park SW, Sung DH, Choi BS, Oh KJ, Moon KH, Sep. Sci. Technol., 41(12), 2665 (2006)
Park SW, Sung DH, Choi BS, Lee JW, Kumazawa H, J. Ind. Eng. Chem., 12(4), 522 (2006)
Park SW, Choi BS, Lee JW, Sep. Sci. Technol., 42(10), 2221 (2007)
Oh KJ, Park DW, Kim SS, Park SW, Korean J. Chem. Eng., 27(2), 632 (2010)
Dogu T, AIChE J., 32, 849 (1986)
Hwang KS, Park SW, Park DW, Oh KJ, Kim SS, Korean J. Chem. Eng., 26(5), 1383 (2009)
Leal O, Bolivar C, Ovalles C, Garcia JJ, Espidel Y, Inorganica Chimica Acta., 240, 183 (1995)
Yasyerli S, Dogu G, Ar I, Dogu T, Chem. Eng. Commun., 190(5-8), 1055 (2003)
