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Received August 19, 2009
Accepted November 8, 2009
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In situ IR studies on the mechanism of methanol synthesis from CO/H2 and CO2/H2 over Cu-ZnO-Al2O3 catalyst
State Key Laboratory of Chemical Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai, P. R. China
liwei@ecust.edu.cn
Korean Journal of Chemical Engineering, July 2010, 27(4), 1093-1098(6), 10.1007/s11814-010-0176-9
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Abstract
Methanol synthesis from CO/H2 and CO2/H2 was carried out at atmospheric pressure over Cu/ZnO/Al2O3 catalyst. The formation and variation of surface species were recorded by in situ FT-IR spectroscopy. The result revealed that both CO and CO2 can serve as the primary carbon source for methanol synthesis. For CO/H2 feed gas, only HCOOZn was detected; however, for CO2/H2, both HCOO-Zn and HCOO-Cu were observed, and without CH3O-Cu. HCOOZn was the key intermediate. A scheme of methanol synthesis and reverse water-gas shift (RGWS) reaction was proposed.
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References
Takeguchi T, Yanagisawa K, Inui T, Inoue M, Appl. Catal. A: Gen., 192(2), 201 (2000)
Ng KL, Chadwick D, Toseland BA, Chem. Eng. Sci., 54(15-16), 3587 (1999)
Qi GX, Zheng XM, Fei JH, Hou ZY, J. Mol. Catal. A-Chem., 176(1-2), 195 (2001)
Suh YW, Rhee HK, Korean J. Chem. Eng., 19(1), 17 (2002)
Lee JS, Lee KH, Lee SY, Kim YG, J. Catal., 144(2), 414 (1993)
Kagan YB, Rozovskii AY, Bashkirov AN, In: Shopov D.,Andreev A., Palazov A. Eds. Geterogennyi Katal, Tr Mezhdunar Simp., 3rd, Bulg: Sofia (Russian), 282 (1978)
Saussey J, Lavalley JC, J. Mol. Catal., 50, 343 (1989)
Fujita S, Usui M, Ito H, Takezawa N, J. Catal., 157(2), 403 (1995)
Agny RM, Takoudis CG, Ind. Eng. Chem. Prod. Res. Dev., 24, 50 (1985)
Kazanskii VB, Kinet Katal., 27, 489 (1986)
Saussey J, Lavalley JC, Lamotte J, Rais T, J. Chem. Soc., Chem. Comm. (1982)
Peltier FL, Chaumette P, Saussey J, Bettahar MM, Lavalley JC, J. Mol. Catal. A., 132, 91 (1998)
Sun Q, Liu CW, Pan W, Zhu QM, Deng JF, Appl. Catal. A: Gen., 171(2), 301 (1998)
Yang R, Fu Y, Zhang Y, Tsubaki N, J. Catal., 22, 823 (2004)
Fujita S, Ito H, Takezawa N, Catal. Lett., 33(1-2), 67 (1995)
Nomura N, Tagawa T, Goto S, Appl. Catal. A: Gen., 166(2), 321 (1998)
Millar GJ, Rochester CH, Catal. Lett., 14, 289 (1992)
Peltier FL, Chaumette P, Saussey J, Bettaha MM, Lavalley JC, J. Mol. Catal. A., 122, 131 (1997)
Edwards JF, Schrader GL, J. Catal., 94, 175 (1985)
TopsØe NY, TopsØe H, J. Mol. Catal. A., 141, 95 (1999)
Joo OS, Jung KD, Han SH, Uhm SJ, Lee DK, Ihm SK, Appl. Catal. A: Gen., 135(2), 273 (1996)
Klier K, Chatikavanij V, Herman RG, Simmons GW, J. Catal., 74, 343 (1982)
Ng KL, Chadwick D, Toseland BA, Chem. Eng. Sci., 54(15-16), 3587 (1999)
Qi GX, Zheng XM, Fei JH, Hou ZY, J. Mol. Catal. A-Chem., 176(1-2), 195 (2001)
Suh YW, Rhee HK, Korean J. Chem. Eng., 19(1), 17 (2002)
Lee JS, Lee KH, Lee SY, Kim YG, J. Catal., 144(2), 414 (1993)
Kagan YB, Rozovskii AY, Bashkirov AN, In: Shopov D.,Andreev A., Palazov A. Eds. Geterogennyi Katal, Tr Mezhdunar Simp., 3rd, Bulg: Sofia (Russian), 282 (1978)
Saussey J, Lavalley JC, J. Mol. Catal., 50, 343 (1989)
Fujita S, Usui M, Ito H, Takezawa N, J. Catal., 157(2), 403 (1995)
Agny RM, Takoudis CG, Ind. Eng. Chem. Prod. Res. Dev., 24, 50 (1985)
Kazanskii VB, Kinet Katal., 27, 489 (1986)
Saussey J, Lavalley JC, Lamotte J, Rais T, J. Chem. Soc., Chem. Comm. (1982)
Peltier FL, Chaumette P, Saussey J, Bettahar MM, Lavalley JC, J. Mol. Catal. A., 132, 91 (1998)
Sun Q, Liu CW, Pan W, Zhu QM, Deng JF, Appl. Catal. A: Gen., 171(2), 301 (1998)
Yang R, Fu Y, Zhang Y, Tsubaki N, J. Catal., 22, 823 (2004)
Fujita S, Ito H, Takezawa N, Catal. Lett., 33(1-2), 67 (1995)
Nomura N, Tagawa T, Goto S, Appl. Catal. A: Gen., 166(2), 321 (1998)
Millar GJ, Rochester CH, Catal. Lett., 14, 289 (1992)
Peltier FL, Chaumette P, Saussey J, Bettaha MM, Lavalley JC, J. Mol. Catal. A., 122, 131 (1997)
Edwards JF, Schrader GL, J. Catal., 94, 175 (1985)
TopsØe NY, TopsØe H, J. Mol. Catal. A., 141, 95 (1999)
Joo OS, Jung KD, Han SH, Uhm SJ, Lee DK, Ihm SK, Appl. Catal. A: Gen., 135(2), 273 (1996)
Klier K, Chatikavanij V, Herman RG, Simmons GW, J. Catal., 74, 343 (1982)
