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Received May 12, 2009
Accepted November 8, 2009
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Removal of acid dye (violet 54) and adsorption kinetics model of using musa spp. waste: A low-cost natural sorbent material
Department of Chemical Engineering, A. C. Tech., Anna University, Chennai-600025, India 1Center for Environmental Studies/Green Energy Center, Department of Environmental Science and Engineering, Kyung Hee University, Gyeonggi-do 446-701, Korea
Korean Journal of Chemical Engineering, September 2010, 27(5), 1469-1475(7), 10.1007/s11814-010-0226-3
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Abstract
Experimental studies and biosorption kinetics of an intraparticle diffusion model for acid dye removal using a musa spp. waste sorbent were carried out to find the removal effects and dynamics of various operating parameters, such as initial dye concentration, sorbent dosage, pH and temperature. Experimental data were modeled with kinetic models and two biosorption isotherms of intraparticle diffusion models as well as the physiochemical data of sorbents_x000D_
characterized by SEM and FT-IR. Kinetic studies showed that the sorption process follows second-order rate kinetics with an average rate constant of 0.0018675 (g/mg·min). Thermodynamic parameters such as entropy of biosorption (ΔS°), enthalpy of biosorption (ΔH°) and Gibbs free energy of biosorption (ΔG°) were obtained and analyzed. Sorbent, musa spp. waste (banana peel) was characterized by FTIR and SEM. The results showed that musa spp. waste can be considered as potential sorbent for the sorption of acid violet 54 from dilute aqueous solution.
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Arami M, Limaee NY, Mahmoodi NM, Tabrizi NS, J. Hazard. Mater., B135, 171 (2006)
Akar T, Ozcan AS, Tunali S, Ozcan A, Bioresour. Technol., 99(8), 3057 (2008)
Hameed BH, Mahmoud DK, Ahmad AL, J. Hazard. Mater., 158(1), 65 (2008)
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Shibi IG, Anirudhan TS, Chemosphere., 58, 1117 (2005)
Srivastava SK, Gupta VK, Mohan D, J. Env. Modeling Assessment., 1, 281 (1998)
Sumanjit, Walia TPS, Kaur R, J. Health Allied Scs., 3, 3 (2007)
Vijayakumar G, Dharmendirakumar M, Renganathan S, Sivanesan S, Baskar G, Elango KP, Clean-soil Air Water., 37(4-5), 355 (2009)
Nandi BK, Goswami A, Das AK, Mondal B, Purkait MK, Sep. Sci. Technol., 43(6), 1382 (2008)
Vadivelan V, Vasanthakumar K, J. Colloid Interf. Sci., 286, 91 (2005)
Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
Hall KR, Eagleton LC, Acrivos A, Vermeulen T, IEC Fundam., 5, 212 (1966)
Freundlich H, J. Phys. Chem., 57, 384 (1906)
Treybal RE, Mass Transfer Operations, 2nd Ed., McGraw Hill, New York (1968)
Ho YS, McKay G, Chem. Eng. J., 70, 115 (1978)
Lagergren S, Handlingar., 24, 1 (1898)
McKay G, Ho YS, Water Res., 33, 578 (1999)
Weber WJ, Morris JC, Proceedings of the International Conference on Water Pollution Symposium 2, Pergamon, Oxford, 231 (1962)
Weber WJ, Morris JJC, J. Sanitary Eng. Div. Proceed. Am. Soc. Civil Eng., 89, 31 (1963)
