Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received November 23, 2009
Accepted January 6, 2010
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Cadmium removal from aqueous solutions using biosorbent Syzygium cumini leaf powder: Kinetic and equilibrium studies
Institute of Minerals & Materials Technology (CSIR), Bhubaneswar 751013, Orissa, India 1Department of Chemical Engineering, College of Engineering, Andhra University, Visakhapatnam 530003, Andhra Pradesh, India
Korean Journal of Chemical Engineering, September 2010, 27(5), 1547-1554(8), 10.1007/s11814-010-0243-2
Download PDF
Abstract
Syzygium cumini L. leaf powder and Cd(II) loaded samples were characterized using FTIR and SEM techniques. The biosorption of cadmium ions from aqueous solution was studied in a batch adsorption system as a function of pH, contact time, adsorbate, adsorbent, anion and cation concentrations. The biosorption capacities and rates of transfer of cadmium ions onto S. cumini L. were evaluated. The kinetics could be best described by both linear and nonlinear pseudo-second order models. The isothermic data fitted to various models in the order Freundlich>Redlich-Peterson>Langmuir>Temkin. The maximum adsorption capacity of S. cumini L. leaves at room temperature was estimated to be 34.54 mg g-1. The negative values of ΔG° indicated the feasibility of the adsorption process. The endothermic nature was confirmed by the positive value of the enthalpy change (ΔH°=3.7 kJ mol-1). The positive value of entropy change (ΔS°=16.87 J mol-1K-1) depicted internal structural changes during the adsorption process.
References
Thomson B, Turney W, Wat. Environ. Res., 67, 527 (1995)
Seki K, Saito N, Aoyama M, Wood Sci. Technol., 31, 441 (1997)
Denizli A, Buyuktuncel E, Genc O, Piskin E, Anal. Lett., 31, 2791 (1998)
Friberg L, Nordberg GF, Vouk B (Eds.), Handbook on the Toxicology of Metals, Elsevier/Biomedical Press, North-Holland/Amsterdam (1979)
Patterson JW, Passino R, Metal speciation separation and recovery, Lewis Publishers, Chelsea, MI, USA (1987)
Lehoczky E, Szabo L, Horvath S, Marth P, Szabados I, Soil Sci. Plant Anal., 29, 1903 (1998)
Kjellstrom T, Shiroishi K, Erwin PE, Environ. Res., 98, 318 (1977)
MINAS Pollution Control Acts, Rules, Notification issued there under Central Pollution Control Board, Ministry of Environment and Forests, Government of India, New Delhi, September. (2001)
Beauvais RA, Alexandratos SD, React. Funct. Polym., 36(2), 113 (1998)
Kuyucak N, in: Biosorption of heavy metals, B. Volesky (Ed.), CRC Press, Boca Raton (1990)
King P, Rakesh N, Beenalahari S, Kumar YP, Prasad VSRK, J. Hazard. Mater., 142(1-2), 340 (2007)
Gnanasambandam R, Protor A, Food Chem., 68, 327 (2000)
Li FT, Yang H, Zhao Y, Xu R, Chin. Chem. Lett., 18, 325 (2007)
Guibaud G, Tixier N, Bouju A, Baudu M, Chemosphere., 52, 1701 (2003)
Ashkenazy R, Gottlieb L, Yannai S, Biotechnol. Bioeng., 55(1), 1 (1997)
Sheng PX, Ting YP, Chen JP, Hong L, J. Colloid Interface Sci., 275(1), 131 (2004)
Lagergren S, vetenskapsakad KS, Handlingar., 24(4), 1 (1898)
Ho YS, Ph.D. Thesis, Birmingham, UK, University of Birmingham (1995)
Ho YS, Wat. Res., 40, 119 (2006)
Namasivayam C, Ranganathan K, Wat. Res., 29, 1737 (1995)
Aksu Z, Sep. Purif. Technol., 21(3), 285 (2001)
Chubar N, Carvalho JR, Neiva MJ, Colloid and Surfaces B: Biointerfaces., 230, 57 (2004)
Deliyanni EA, Matis KA, Sep. Purif. Technol., 45(2), 96 (2005)
Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
Treyball RE, Mass-transfer operations., 3rd Ed., McGraw Hill (1980)
Redlich O, Peterson DL, J. Phys. Chem., 63, 1024 (1959)
Aharoni C, Ungarish M, J. Chem. Soc. Faraday Trans., 73, 456 (1977)
Hall KR, Eagleton LC, Acrivos A, Vermeulen T, Ind. Eng.Chem. Fundam., 5, 212 (1966)
Pandey KK, Prasad G, Singh VN, Wat. Res., 19(7), 869 (1985)
Low KS, Lee CK, Liew SC, Process Biochem., 36, 59 (2000)
Leyva-Ramos R, Bernal-Jacome LA, Acosta-Rodriguez I, Sep. Purif. Technol., 45(1), 41 (2005)
Ajmal M, Rao RAK, Anwar S, Ahmad J, Ahmad R, Bioresour. Technol., 86(2), 147 (2003)
Ghodbane I, Nouri L, Hamdaoui O, Chiha M, J. Hazard.Mater., 152(1), 148 (2007)
Benaissa H, Benguella B, Environ. Poll., 130, 157 (2004)
Mohapatra M, Padhi T, Dash T, Singh P, Anand S, Mishra BK, Communicated to J. Hazard. Mater. (2009)
Pehlivan E, Yanik BH, Ahmetli G, Pehlivan M, Bioresour. Technol., 99(9), 3520 (2008)
Rao KS, Anand S, Venkateswarlu P, Bioresources., 5(1), 438 (2010)
Mohan D, Pittman CU, Steele PH, J. Colloid Interface Sci., 297(2), 489 (2006)
Ozer A, Pirincci HB, J. Hazard. Mater., 137(2), 849 (2006)
Martinez M, Miralles N, Hidalgo S, Fiol N, Villaescusa I, Poch J, J. Hazard. Mater., 133(1-3), 203 (2006)
Ho YS, Wang CC, Process Biochem., 39, 759 (2004)
Nouri L, Ghodbane I, Hamdaoui O, Chiha M, J. Hazard. Mater., 149(1), 115 (2007)
Cay S, Uyanik A, Ozasik A, Sep. Purif. Technol., 38(3), 273 (2004)
Iqbal M, Saeed A, Akhtar N, Bioresour. Technol., 81(2), 151 (2002)
Seki K, Saito N, Aoyama M, Wood Sci. Technol., 31, 441 (1997)
Denizli A, Buyuktuncel E, Genc O, Piskin E, Anal. Lett., 31, 2791 (1998)
Friberg L, Nordberg GF, Vouk B (Eds.), Handbook on the Toxicology of Metals, Elsevier/Biomedical Press, North-Holland/Amsterdam (1979)
Patterson JW, Passino R, Metal speciation separation and recovery, Lewis Publishers, Chelsea, MI, USA (1987)
Lehoczky E, Szabo L, Horvath S, Marth P, Szabados I, Soil Sci. Plant Anal., 29, 1903 (1998)
Kjellstrom T, Shiroishi K, Erwin PE, Environ. Res., 98, 318 (1977)
MINAS Pollution Control Acts, Rules, Notification issued there under Central Pollution Control Board, Ministry of Environment and Forests, Government of India, New Delhi, September. (2001)
Beauvais RA, Alexandratos SD, React. Funct. Polym., 36(2), 113 (1998)
Kuyucak N, in: Biosorption of heavy metals, B. Volesky (Ed.), CRC Press, Boca Raton (1990)
King P, Rakesh N, Beenalahari S, Kumar YP, Prasad VSRK, J. Hazard. Mater., 142(1-2), 340 (2007)
Gnanasambandam R, Protor A, Food Chem., 68, 327 (2000)
Li FT, Yang H, Zhao Y, Xu R, Chin. Chem. Lett., 18, 325 (2007)
Guibaud G, Tixier N, Bouju A, Baudu M, Chemosphere., 52, 1701 (2003)
Ashkenazy R, Gottlieb L, Yannai S, Biotechnol. Bioeng., 55(1), 1 (1997)
Sheng PX, Ting YP, Chen JP, Hong L, J. Colloid Interface Sci., 275(1), 131 (2004)
Lagergren S, vetenskapsakad KS, Handlingar., 24(4), 1 (1898)
Ho YS, Ph.D. Thesis, Birmingham, UK, University of Birmingham (1995)
Ho YS, Wat. Res., 40, 119 (2006)
Namasivayam C, Ranganathan K, Wat. Res., 29, 1737 (1995)
Aksu Z, Sep. Purif. Technol., 21(3), 285 (2001)
Chubar N, Carvalho JR, Neiva MJ, Colloid and Surfaces B: Biointerfaces., 230, 57 (2004)
Deliyanni EA, Matis KA, Sep. Purif. Technol., 45(2), 96 (2005)
Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
Treyball RE, Mass-transfer operations., 3rd Ed., McGraw Hill (1980)
Redlich O, Peterson DL, J. Phys. Chem., 63, 1024 (1959)
Aharoni C, Ungarish M, J. Chem. Soc. Faraday Trans., 73, 456 (1977)
Hall KR, Eagleton LC, Acrivos A, Vermeulen T, Ind. Eng.Chem. Fundam., 5, 212 (1966)
Pandey KK, Prasad G, Singh VN, Wat. Res., 19(7), 869 (1985)
Low KS, Lee CK, Liew SC, Process Biochem., 36, 59 (2000)
Leyva-Ramos R, Bernal-Jacome LA, Acosta-Rodriguez I, Sep. Purif. Technol., 45(1), 41 (2005)
Ajmal M, Rao RAK, Anwar S, Ahmad J, Ahmad R, Bioresour. Technol., 86(2), 147 (2003)
Ghodbane I, Nouri L, Hamdaoui O, Chiha M, J. Hazard.Mater., 152(1), 148 (2007)
Benaissa H, Benguella B, Environ. Poll., 130, 157 (2004)
Mohapatra M, Padhi T, Dash T, Singh P, Anand S, Mishra BK, Communicated to J. Hazard. Mater. (2009)
Pehlivan E, Yanik BH, Ahmetli G, Pehlivan M, Bioresour. Technol., 99(9), 3520 (2008)
Rao KS, Anand S, Venkateswarlu P, Bioresources., 5(1), 438 (2010)
Mohan D, Pittman CU, Steele PH, J. Colloid Interface Sci., 297(2), 489 (2006)
Ozer A, Pirincci HB, J. Hazard. Mater., 137(2), 849 (2006)
Martinez M, Miralles N, Hidalgo S, Fiol N, Villaescusa I, Poch J, J. Hazard. Mater., 133(1-3), 203 (2006)
Ho YS, Wang CC, Process Biochem., 39, 759 (2004)
Nouri L, Ghodbane I, Hamdaoui O, Chiha M, J. Hazard. Mater., 149(1), 115 (2007)
Cay S, Uyanik A, Ozasik A, Sep. Purif. Technol., 38(3), 273 (2004)
Iqbal M, Saeed A, Akhtar N, Bioresour. Technol., 81(2), 151 (2002)
