Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received October 28, 2009
Accepted January 19, 2010
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Simple one-pot synthesis of a mesoporous superacidic catalyst for the dehydration of glycerol to acrolein
Department of Petrochemical Engineering, Liaoning Shihua University, Fushun 113001, China 1School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, 599 Gwanak-ro, Gwanak-gu, Seoul 151-744, Korea 2GS Caltex Corporation, 104-4, Munji-dong, Yusung-gu, Daejeon 305-380, Korea
Korean Journal of Chemical Engineering, November 2010, 27(6), 1695-1699(5), 10.1007/s11814-010-0256-x
Download PDF
Abstract
Mesoporous silica containing a ZrO2/SO4^(2-) superacid catalyst (SZS) was synthesized via a simple one-pot process. ZrO2/SO4^(2-) (SZ) was introduced during the synthesis of the SBA-15. When the molar ratio of Zr to Si was less than 0.37 : 1, a 2D-hexagonal pore structure was maintained. The superacidic SZ was successfully supported on mesoporous silica resulting in superacidity. The prepared SZS catalysts were applied to the conversion of glycerol to acrolein by dehydration and had considerable catalytic activity. The present study describes the first attempt to utilize mesoporous silica-supported superacid catalysts in the dehydration of glycerol to produce acrolein.
References
Hino M, Kobayashi S, Arata K, J. Am. Chem. Soc., 101, 6439 (1979)
Arata K, Adv. Catal., 37, 165 (1990)
Sun YY, Zhu L, Lu HJ, Wang RW, Lin S, Jiang DZ, Xiao FS, Appl. Catal. A: Gen., 237(1-2), 21 (2002)
Yadav GD, Nair JJ, Micro. Meso. Mater., 33, 1 (1999)
Xia YD, Hua WM, Tang Y, Gao Z, Chem. Commun., 1899 (1999)
Jin T, Yamaguchi T, Tanabe K, J. Phys. Chem., 90, 4797 (1986)
Yadav GD, Kirthivasan N, J. Chem. Soc., Chem. Commun., 203 (1995)
Hino M, Arata K, J. Chem. Soc., Chem. Commun., 851 (1980)
Chen FR, Coudurier G, Joly JF, Vederine JC, J. Catal., 143, 616 (1993)
Lei T, Xu JS, Tang Y, Hua WM, Gao Z, Appl. Catal. A: Gen., 192(2), 181 (2000)
Xia QH, Hidajat K, Kawi S, Chem. Commun., 2229 (2000)
Chen CL, Cheng SF, Lin HP, Wong ST, Mou CY, Appl. Catal. A: Gen., 215(1-2), 21 (2001)
Wei CP, Li SZ, Zhou B, Peng CJ, Zhen KJ, Chem. Res. Chinese U., 22, 371 (2006)
Hua WM, Yue YH, Gao Z, J. Mol. Catal. A-Chem., 170(1-2), 195 (2001)
Matsuhashi H, Tanaka M, Nakamura H, Arata K, Appl. Catal. A: Gen., 208(1-2), 1 (2001)
Ecormier MA, Lee AF, Wilson K, Micro. Meso. Mater., 80, 301 (2005)
Li F, Yu F, Li Y, Li R, Xie K, Micro. Meso. Mater., 101, 250 (2007)
Suppes GJ, Dasari MA, Doskocil EJ, Mankidy PJ, Goff MJ, Appl. Catal. A: Gen., 257(2), 213 (2004)
Chai SH, Wang HP, Liang Y, Xu BQ, J. Catal., 250(2), 342 (2007)
Ott L, Bicker M, Vogel H, Green Chem., 8, 214 (2006)
Tsukuda E, Sato S, Takahashi R, Sodesawa T, Catal. Commun., 8, 1349 (2007)
Yu GX, Zhou XL, Li CL, Chen LF, Wang JA, Catal. Today, 148(1-2), 169 (2009)
Permsubscul A, Vitidsant T, Damronglerd S, Korean J. Chem. Eng., 24(1), 37 (2007)
Ciao CX, Gao Z, Mater. Chem. Phys., 50, 15 (1997)
Corma A, Fornes V, Juanrajadell MI, Nieto JM, Appl. Catal. A: Gen., 116(1-2), 151 (1994)
Yamamoto T, Tanaka T, Takenaka S, Yoshida S, Onari T, Takahashi Y, Kosaka T, Hasegawa S, Kudo M, J. Phys. Chem. B, 103(13), 2385 (1999)
Rodriguez-Castellon E, Jimenez-Lopez A, Maireles-Torres P, Jones DJ, Roziere J, Trombetta M, Busca G, Lenarda M, Storaro L, J. Solid State Chem., 175, 159 (2003)
Yadav GD, Murkute AD, J. Catal., 224(1), 218 (2004)
Yan H, Yang Y, Tong D, Xiang X, Hu C, Catal. Commun., 10, 1588 (2009)
Li R, Yu F, Li F, Zhou M, Xu B, Xie K, J. Solid State Chem., 182, 991 (2009)
Arata K, Adv. Catal., 37, 165 (1990)
Sun YY, Zhu L, Lu HJ, Wang RW, Lin S, Jiang DZ, Xiao FS, Appl. Catal. A: Gen., 237(1-2), 21 (2002)
Yadav GD, Nair JJ, Micro. Meso. Mater., 33, 1 (1999)
Xia YD, Hua WM, Tang Y, Gao Z, Chem. Commun., 1899 (1999)
Jin T, Yamaguchi T, Tanabe K, J. Phys. Chem., 90, 4797 (1986)
Yadav GD, Kirthivasan N, J. Chem. Soc., Chem. Commun., 203 (1995)
Hino M, Arata K, J. Chem. Soc., Chem. Commun., 851 (1980)
Chen FR, Coudurier G, Joly JF, Vederine JC, J. Catal., 143, 616 (1993)
Lei T, Xu JS, Tang Y, Hua WM, Gao Z, Appl. Catal. A: Gen., 192(2), 181 (2000)
Xia QH, Hidajat K, Kawi S, Chem. Commun., 2229 (2000)
Chen CL, Cheng SF, Lin HP, Wong ST, Mou CY, Appl. Catal. A: Gen., 215(1-2), 21 (2001)
Wei CP, Li SZ, Zhou B, Peng CJ, Zhen KJ, Chem. Res. Chinese U., 22, 371 (2006)
Hua WM, Yue YH, Gao Z, J. Mol. Catal. A-Chem., 170(1-2), 195 (2001)
Matsuhashi H, Tanaka M, Nakamura H, Arata K, Appl. Catal. A: Gen., 208(1-2), 1 (2001)
Ecormier MA, Lee AF, Wilson K, Micro. Meso. Mater., 80, 301 (2005)
Li F, Yu F, Li Y, Li R, Xie K, Micro. Meso. Mater., 101, 250 (2007)
Suppes GJ, Dasari MA, Doskocil EJ, Mankidy PJ, Goff MJ, Appl. Catal. A: Gen., 257(2), 213 (2004)
Chai SH, Wang HP, Liang Y, Xu BQ, J. Catal., 250(2), 342 (2007)
Ott L, Bicker M, Vogel H, Green Chem., 8, 214 (2006)
Tsukuda E, Sato S, Takahashi R, Sodesawa T, Catal. Commun., 8, 1349 (2007)
Yu GX, Zhou XL, Li CL, Chen LF, Wang JA, Catal. Today, 148(1-2), 169 (2009)
Permsubscul A, Vitidsant T, Damronglerd S, Korean J. Chem. Eng., 24(1), 37 (2007)
Ciao CX, Gao Z, Mater. Chem. Phys., 50, 15 (1997)
Corma A, Fornes V, Juanrajadell MI, Nieto JM, Appl. Catal. A: Gen., 116(1-2), 151 (1994)
Yamamoto T, Tanaka T, Takenaka S, Yoshida S, Onari T, Takahashi Y, Kosaka T, Hasegawa S, Kudo M, J. Phys. Chem. B, 103(13), 2385 (1999)
Rodriguez-Castellon E, Jimenez-Lopez A, Maireles-Torres P, Jones DJ, Roziere J, Trombetta M, Busca G, Lenarda M, Storaro L, J. Solid State Chem., 175, 159 (2003)
Yadav GD, Murkute AD, J. Catal., 224(1), 218 (2004)
Yan H, Yang Y, Tong D, Xiang X, Hu C, Catal. Commun., 10, 1588 (2009)
Li R, Yu F, Li F, Zhou M, Xu B, Xie K, J. Solid State Chem., 182, 991 (2009)
