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Received November 23, 2009
Accepted January 26, 2010
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Reaction kinetics of phenol synthesis through one-step oxidation of benzene with N2O over Fe-ZSM-5 zeolite
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
lijw@mail.buct.edu.cn
Korean Journal of Chemical Engineering, November 2010, 27(6), 1700-1706(7), 10.1007/s11814-010-0259-7
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Abstract
Based on the information from GC-MS on-line measurement and thermodynamic analysis, the reaction network of gas-phase hydroxylation of benzene with nitrous oxide over Fe-ZSM-5 zeolite was systematically investigated. The main reactions and side reactions were identified, and a kinetic reaction network was proposed as follows: benzene+N2O→phenol→CO/CO2. According to the mechanism, the experimental results were interpreted reasonably. The hydroxylation kinetic experiments were carried out in an isothermal integral microreactor under the conditions of n(benzene)/n(N2O)=8-12, T=663-763 K and atmospheric pressure. Based on the reaction network proposed, the parameters in the rate model of power-law were estimated by means of Gauss-Newton optimal method with the Levenberg-Marquardt modifications, and the results were in good agreement with the experimental data.
References
Schmidt RJ, Appl. Catal. A: Gen., 280(1), 89 (2005)
Yamanaka I, Katagiri M, Takenaka S, Otsuka K, Stud. Surf. Sci. Catal., 130, 809 (2000)
Battistel E, Tassinari R, Fornaroli M, Bonoldi L, J. Mol. Catal. A-Chem., 202(1-2), 107 (2003)
Hamada R, Shibata Y, Nishiyama S, Tsuruya S, Chem. Phys., 5, 956 (2003)
Kuznetsova NI, Kuznetsova LI, Likholobov VA, Pez GP, Catal. Today, 99(1-2), 193 (2005)
Liu YY, Murata K, Inaba M, J. Mol. Catal. A-Chem., 256(1-2), 247 (2006)
Passoni LC, Cruz AT, Buffon R, Schuchardt U, J. Mol. Catal. A: Chem., 120, 117 (1997)
Pirutko LV, Uriarte AK, Chernyavsky VS, Kharitonov AS, Panov GI, Micropor. Mesopor. Mater., 48, 345 (2001)
Panov GI, Cattech, 4, 18 (2000)
Vereshchagin SN, Kirik NP, Shishkina NN, Morozov SV, Vyalkov AI, Anshits AG, Catal. Today, 61(1-4), 129 (2000)
Hensen EJM, Zhu Q, Hendrix MMRM, Overweg AR, Kooyman PJ, Sychev MV, van Santen RA, J. Catal., 221(2), 560 (2004)
Zhu Q, van Teeffelen RM, van Santen RA, Hensen EJM, J. Catal., 221(2), 575 (2004)
Waclaw A, Nowinska K, Schwieger W, Appl. Catal. A: Gen., 270(1-2), 151 (2004)
Jia JF, Pillai KS, Sachtler WMH, J. Catal., 221(1), 119 (2004)
Pillai KS, Jia JF, Sachtler WMH, Appl. Catal. A: Gen., 264(2), 133 (2004)
Parmon VN, Panov GI, Uriarte A, Noskov AS, Catal. Today, 100(1-2), 115 (2005)
Kharitonov AS, Panov GI, Ione KG, Romannikov VN, Sheveleva GA, Vostrikova LA, Sobolev VI
Uriarte AK, Rodkin MA, Gross MJ, Kharitonov AS, Panov GI, Stud. Surf. Sci. Catal., 110, 857 (1997)
Uriarte AK, Stud. Surf. Sci. Catal., 130, 743 (2000)
Notte PP, Top. Catal., 13, 387 (2000)
Perez-Ramirez J, Kapteijn F, Schoffel K, Moulijn JA, Appl. Catal. B: Environ., 44(2), 117 (2003)
Groen JC, Perez-Ramirez J, Zhu W, J. Chem. Eng. Data, 47, 587 (2002)
Kim MY, Lee KW, Park JH, Shin CH, Lee J, Seo G, Korean J. Chem. Eng., 27(1), 76 (2010)
Hafele M, Reitzmann A, Roppelt D, Emig G, Appl. Catal. A: Gen., 150(1), 153 (1997)
Hafele M, Reitzmann A, Klemm E, Emig G, Stud. Surf. Sci. Catal., 110, 847 (1997)
Centi G, Vazzana F, Catal. Today, 53(4), 683 (1999)
Cejka J, Wichterlova B, Krtil J, Krivanek M, Fricke R, Stud. Surf. Sci. Catal., 69, 347 (1991)
Joyner R, Stockenhuber M, J. Phys. Chem. B, 103(29), 5963 (1999)
Reid RC, Prausnitz JM, Poling BE, The properties of gases and liquids, McGraw-Hill, New York (1987)
Pedley JB, Naylor RD, Kirby SP, Thermochemical data of organic compounds, Chapman and Hill, London (1986)
Weast RC, Astle MJ, Beyer WH, CRC handbook of chemistry and physics, CRC Press, Florida (1988)
Benson SW, Thermochemical kinetics: Methods for the estimation of thermochemical data and rate parameters, John Wiley & Sons, New York (1976)
Benson SW, Crickshank FR, Golden DM, Haugen GR, O’Neal HE, Rodgers AE, Shaw R, Walsh R, Chem. Rev., 69, 279 (1969)
Benson SW, J. Phys. Chem., 103, 11481 (1999)
Dekker FH, Bliek A, Kapteijn F, Moulijn JA, Chem. Eng. Sci., 50(22), 3573 (1995)
Nguyen HH, Jang NJ, Choi SH, Korean J. Chem. Eng., 26(1), 1 (2009)
de Luis A, Lombrana JI, Varona F, Menendez A, Korean J. Chem. Eng., 26(1), 48 (2009)
Yamanaka I, Katagiri M, Takenaka S, Otsuka K, Stud. Surf. Sci. Catal., 130, 809 (2000)
Battistel E, Tassinari R, Fornaroli M, Bonoldi L, J. Mol. Catal. A-Chem., 202(1-2), 107 (2003)
Hamada R, Shibata Y, Nishiyama S, Tsuruya S, Chem. Phys., 5, 956 (2003)
Kuznetsova NI, Kuznetsova LI, Likholobov VA, Pez GP, Catal. Today, 99(1-2), 193 (2005)
Liu YY, Murata K, Inaba M, J. Mol. Catal. A-Chem., 256(1-2), 247 (2006)
Passoni LC, Cruz AT, Buffon R, Schuchardt U, J. Mol. Catal. A: Chem., 120, 117 (1997)
Pirutko LV, Uriarte AK, Chernyavsky VS, Kharitonov AS, Panov GI, Micropor. Mesopor. Mater., 48, 345 (2001)
Panov GI, Cattech, 4, 18 (2000)
Vereshchagin SN, Kirik NP, Shishkina NN, Morozov SV, Vyalkov AI, Anshits AG, Catal. Today, 61(1-4), 129 (2000)
Hensen EJM, Zhu Q, Hendrix MMRM, Overweg AR, Kooyman PJ, Sychev MV, van Santen RA, J. Catal., 221(2), 560 (2004)
Zhu Q, van Teeffelen RM, van Santen RA, Hensen EJM, J. Catal., 221(2), 575 (2004)
Waclaw A, Nowinska K, Schwieger W, Appl. Catal. A: Gen., 270(1-2), 151 (2004)
Jia JF, Pillai KS, Sachtler WMH, J. Catal., 221(1), 119 (2004)
Pillai KS, Jia JF, Sachtler WMH, Appl. Catal. A: Gen., 264(2), 133 (2004)
Parmon VN, Panov GI, Uriarte A, Noskov AS, Catal. Today, 100(1-2), 115 (2005)
Kharitonov AS, Panov GI, Ione KG, Romannikov VN, Sheveleva GA, Vostrikova LA, Sobolev VI
Uriarte AK, Rodkin MA, Gross MJ, Kharitonov AS, Panov GI, Stud. Surf. Sci. Catal., 110, 857 (1997)
Uriarte AK, Stud. Surf. Sci. Catal., 130, 743 (2000)
Notte PP, Top. Catal., 13, 387 (2000)
Perez-Ramirez J, Kapteijn F, Schoffel K, Moulijn JA, Appl. Catal. B: Environ., 44(2), 117 (2003)
Groen JC, Perez-Ramirez J, Zhu W, J. Chem. Eng. Data, 47, 587 (2002)
Kim MY, Lee KW, Park JH, Shin CH, Lee J, Seo G, Korean J. Chem. Eng., 27(1), 76 (2010)
Hafele M, Reitzmann A, Roppelt D, Emig G, Appl. Catal. A: Gen., 150(1), 153 (1997)
Hafele M, Reitzmann A, Klemm E, Emig G, Stud. Surf. Sci. Catal., 110, 847 (1997)
Centi G, Vazzana F, Catal. Today, 53(4), 683 (1999)
Cejka J, Wichterlova B, Krtil J, Krivanek M, Fricke R, Stud. Surf. Sci. Catal., 69, 347 (1991)
Joyner R, Stockenhuber M, J. Phys. Chem. B, 103(29), 5963 (1999)
Reid RC, Prausnitz JM, Poling BE, The properties of gases and liquids, McGraw-Hill, New York (1987)
Pedley JB, Naylor RD, Kirby SP, Thermochemical data of organic compounds, Chapman and Hill, London (1986)
Weast RC, Astle MJ, Beyer WH, CRC handbook of chemistry and physics, CRC Press, Florida (1988)
Benson SW, Thermochemical kinetics: Methods for the estimation of thermochemical data and rate parameters, John Wiley & Sons, New York (1976)
Benson SW, Crickshank FR, Golden DM, Haugen GR, O’Neal HE, Rodgers AE, Shaw R, Walsh R, Chem. Rev., 69, 279 (1969)
Benson SW, J. Phys. Chem., 103, 11481 (1999)
Dekker FH, Bliek A, Kapteijn F, Moulijn JA, Chem. Eng. Sci., 50(22), 3573 (1995)
Nguyen HH, Jang NJ, Choi SH, Korean J. Chem. Eng., 26(1), 1 (2009)
de Luis A, Lombrana JI, Varona F, Menendez A, Korean J. Chem. Eng., 26(1), 48 (2009)
