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Received February 18, 2010
Accepted May 3, 2010
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Calculation of thermodynamic quantities for carbon tetrachloride (CCl4) close to the III-IV phase transition
Department of Physics, Middle East Technical University, 06531, Ankara-Turkey
hamit@metu.edu.tr
Korean Journal of Chemical Engineering, January 2011, 28(1), 252-255(4), 10.1007/s11814-010-0320-6
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Abstract
We calculate the thermal expansion α(p), isothermal compressibility κ(T) and the specific heat, C(p)-C(v), as a function of pressure using the observed V-P data at room temperature close to the III-IV phase transition in CCl(4). Calculated κ(T), α(p) and C(p)-C(v) decrease as the pressure increases from phase III to phase IV in this molecular crystal system, as expected. On the basis of our calculations of the κ(T), α(p) and C(p)-C(v), the Pippard relations are established close to the III-IV phase transition in CCl(4), which can be verified experimentally.
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References
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Cohen S, Powers R, Rudman R, Acta Cryst. B., 35, 1670 (1979)
Adams DM, Sharma SK, J. Chem. Soc. Dalton Trans., 2089 (1976)
Kawamura H, Kobayashi M, Yamamato Y, Matsui N, Akahama Y, Solid State Commnu., 102, 501 (1997)
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Morrison JA, Richards EL, J. Chem. Thermodyn., 8, 1033 (1976)
Badiali JP, Bruneaux-Poulle J, Defrain A, J. Chem. Phys., 73, 113 (1976)
Maruyama M, Kawabata K, Kuribayashi N, J. Cryst. Growth., 200, 161 (2000)
Bean VE, Wood SD, J. Chem. Phys., 72, 5838 (1980)
Xans P, Saint-Gurions H, Dumas JP, J. Phys. C., 10, L267 (1977)
Weber WJ, Goodstein DL, Phys. Rev. B., 73, 195424 (2006)
Koga Y, Morrison JA, J. Chem. Phys., 62, 3359 (1975)
Andersen A, Torrie BH, Tse WS, Chem. Phys. Lett., 61, 119 (1979)
Djabourov M, Levy-Manneheim C, Leblond J, Papon P, J.Chem. Phys., 66, 5748 (1975)
Zuk JD, Kiefte H, Clouler MJ, J. Chem. Phys., 95, 1950 (1991)
Pruzan P, Liebenberg DH, Mills RL, J. Phys. Chem. Solids., 47, 949 (949)
Kavruk DK, Yurtseven H, High Temp. Mater. Processes., 26, 397 (2007)
Yurtseven H, Kavruk D, J. Mol. Liq., 139, 117 (2008)
Yurtseven H, Kavruk D, Mod. Phys. Lett. B., 24, 75 (2010)
Ebisuzaki Y, J. Raman Spect., 8, 331 (1979)
