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In relation to this article, we declare that there is no conflict of interest.
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Received February 20, 2011
Accepted April 26, 2011
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Green synthesis of gold nanostructures using pear extract as effective reducing and coordinating agent

Department of Environmental Engineering, Kyungpook National University, 80 Daehak-ro, Buk-gu, Daegu 702-701, Korea
daesung@knu.ac.kr
Korean Journal of Chemical Engineering, December 2011, 28(12), 2329-2335(7), 10.1007/s11814-011-0115-4
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Abstract

Biosynthesis of gold nanoparticles and nanoplates (GNPs) was accomplished using aqueous fractions of pear extract as a safe, reducing, particle-stabilizing, and shape-directing agent. The maximum yields of spherical gold nanoparticles having the average sizes of 40, 20, and 10 nm were achieved at 30, 60, and 90℃ , respectively, at a pear extract concentration of 45% (v/v). The maximum yield of gold nanoplates was obtained with sizes ranging from 20 to 400 nm, particularly at reaction temperatures of 30, 60, and 90℃ , at a pear extract concentration of 5% (v/v). The surface chemistry analysis of the GNPs suggests that the sugars and peptides or proteins as key biomolecules of the pear extract play a crucial role in the reduction of Au(III), subsequently resulting in healthy capping. Therefore, this environmentally friendly synthesis method of GNPs for the particular type of morphologies is expected to be a competitive_x000D_ alternative to existing physical and chemical methods.

References

Chen RJ, Bangsaruntip S, Drouvalakis KA, Kam NWS, Shim M, Li Y, Kim W, Utz PJ, Dai H, Proc. Natl. Acad. Sci., 100, 4984 (2003)
Nowack B, Bucheli TD, Environ. Pollut., 150, 5 (2007)
Meltzer S, Resch R, Koel BE, Thompson ME, Madhukar A, Requicha AAG, Will P, Langmuir, 17(5), 1713 (2001)
Gole A, Murphy CJ, Chem. Mater., 16, 3633 (2004)
Dahl JA, Maddux BLS, Hutchison JE, Chem. Rev., 107(6), 2228 (2007)
Hutchison JE, ACS Nano., 2, 395 (2008)
Li H, Carter JD, LaBean TH, Mater. Today., 12, 24 (2009)
Niemeyer CM, Ceyhan B, Ange. Chem. Inter. Edi., 40, 3685 (2001)
Tsai CJ, Zheng J, Zanuy D, Haspel N, Wolfson H, Aleman C, Nussinov R, Proteins., 68, 1 (2007)
Kumar V, Yadav SK, J. Chem. Technol. Biotechnol., 84(2), 151 (2009)
Mohanpuria P, Rana NK, Yadav SK, J. Nanopart. Res., 10, 507 (2008)
Huang J, Wang W, Lin L, Li Q, Lin W, Li M, Mann S, Chem.Asian J., 4, 1050 (2009)
Castro L, Blazquez ML, Gonzalez F, Munoz JA, Ballester A, Chem. Eng. J., 164(1), 92 (2010)
Shankar SS, Rai A, Ankamwar B, Singh A, Ahmad A, Sastry M, Nat. Mater., 3, 482 (2004)
Tan YN, Lee JY, Wang DIC, J. Phys. Chem. C., 112, 5463 (2008)
Song JY, Jang HK, Kim BS, Process Biochem., 44, 1133 (2009)
Tripathy A, Raichur AM, Chandrasekaran N, Prathna TC, Mukherjee A, J. Nanopart. Res., 12, 237 (2010)
USDA National Nutrient Database for Standard Reference, Release 23. U.S. Department of Agriculture, Agricultural Research Service, Scientific Name: Pyrus pyrifolia (Pears, asian, raw) NDB No: 09340 (2010)
Nie SM, Emery SR, Science, 275(5303), 1102 (1997)
El-Sayed MA, Accounts Chem. Res., 34, 257 (2001)
Liz-Marzan LM, Langmuir, 22(1), 32 (2006)
Shukla R, Nune SK, Chanda N, Katti K, Mekapothula S, Kulkarni RR, Welshons WV, Kannan R, Katti KV, Small., 4, 1425 (2008)

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