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Received August 23, 2023
Accepted August 23, 2023
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Dehydration of D-xylose into furfural over H-zeolites
Division of Energy Systems Research and Division of Chemical Engineering and Materials Engineering, Ajou University, Wonchun-dong, Yeongtong-gu, Suwon 443-749, Korea 1R&D Center Kolon Industries, Inc, 294 Gajwa-dong, Seo-gu, Incheon 404-250, Korea
edpark@ajou.ac.kr
Korean Journal of Chemical Engineering, March 2011, 28(3), 710-716(7), 10.1007/s11814-010-0417-y
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Abstract
The liquid-phase dehydration of D-xylose into furfural was carried out over various H-zeolites-H-ferrierite, H-β, H-ZSM-5, H-Y and H-mordenite-with various SiO2/Al2O3 molar ratios in different solvent systems: water, dimethyl sulfoxide (DMSO) and a mixture of water and toluene (water/toluene). For comparison, γ-Al2O3 and silica-alumina were also examined. FT-IR spectroscopy after pyridine adsorption was conducted to probe the acidity of the H-zeolites._x000D_
The D-xylose conversion and furfural yield generally decreased with increasing SiO2/Al2O3 molar ratio over the Hzeolites having the same crystal structure irrespective of the kind of solvent system. This is closely related to the accessible acid sites. In a comparison study using the three different solvent systems, the D-xylose conversion and furfural selectivity generally decreased in the following order: water/toluene>DMSO>water. In water and water/toluene, H-β_x000D_
(25) showed the highest furfural selectivity at a similar D-xylose conversion among the tested zeolites. On the other hand, H-mordenite (20) showed the highest furfural selectivity at a similar D-xylose conversion in DMSO.
Keywords
References
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Moreau C, Durand R, Peyron D, Duhamet J, Rivalier P, Ind. Crop. Prod., 7, 95 (1998)
Lima S, Pillinger M, Valente AA, Catal. Commun., 9, 2144 (2008)
O'Neill R, Ahmad MN, Vanoye L, Aiouache F, Ind. Eng. Chem. Res., 48(9), 4300 (2009)
Lima S, Fernandes A, Antunes MM, Pillinger M, Ribeiro F, Valente AA, Catal. Lett., 135(1-2), 41 (2010)
Corma A, Chem. Rev., 95(3), 559 (1995)
Barzetti T, Selli E, Moscotti D, Forni L, J. Chem. Soc. Faraday Trans., 92, 1401 (1996)
Zaki MI, Hasan MA, Al-Sagheer FA, Pasupulety L, Colloid. Surface A., 190, 261 (2001)
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Jing Q, Lu XY, Chin. J. Chem. Eng., 15(5), 666 (2007)
Chheda JN, Dumesic JA, Catal. Today, 123(1-4), 59 (2007)
