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Received February 2, 2010
Accepted December 2, 2010
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Combined effect of co-existing heavy metals and organophosphate pesticide on adsorption of atrazine to river sediments
Energy and Environmental Research Centre, North China Electric Power University, Beijing 102206, China 1Jilin Provincial Center for Sanitary Inspection and Test, Changchun 130062, China
Korean Journal of Chemical Engineering, May 2011, 28(5), 1200-1206(7), 10.1007/s11814-010-0504-0
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Abstract
Adsorption characteristics of atrazine (AT) onto the surfacial sediments (natural surface coating samples) were investigated via thermal adsorption in the presence of pollutants malathion (Ma) and heavy metals (cadmium and copper). The results indicate that cadmium and Ma both have synergetic effect during the adsorption of AT; at the same time, copper caused antagonistic effect on the adsorption of AT. Ma could facilitate the adsorption of AT, no matter that Ma was added after the adsorption of AT or simultaneous adsorption of AT with Ma present. However, Ma inhibited the adsorption of AT when it was added before the adsorption of AT. The adsorption of AT was also enhanced when both cadmium and Ma were present; however, it was inhibited strongly when both copper and Ma were present. The infrared spectra of the surfacial sediments (natural surface coating samples), after the adsorption of AT in the presence of co-existing pollutants, indicated that organic functional groups, such as O-H or N-H and C=O, play important_x000D_
roles on sorption of AT to river sediments.
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Zhou DM, Wang YJ, Cang L, Hao XZ, Luo XS, Chemosphere., 57, 1237 (2004)
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Li Y, Gao Q, Wang XL, Dong DM, Wang A, Chem. Res.Chinese U., 25, 155 (2009)
Li Y, Wang A, Gao Q, Dong DM, Fresen. Environ. Bull., 18, 2373 (2009)
Jang JG, Kim MR, Kim WH, Lee JK, Korean J. Chem. Eng., 19(6), 1097 (2002)
Xing BS, Pignatello JJ, Gigliotti B, Environ. Sci. Technol., 30, 2432 (1996)
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Hernandez-Soriano MC, Mingorance MD, Pena A, Colloid.Surf. A., 306, 49 (2007)
Shi DR, Zhang LD, Ren LP, Yu JL, Tian Q, J. Agro-Environment Science., 25, 988 (2006)
Gupta VK, Jain CK, Ali I, Chandra S, Agarwal S, Water Res., 36, 2483 (2002)
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Pape-Lindstrom PA, Lydy MJ, Environ. Toxicol. Chem., 16, 2415 (1997)
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