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Received December 2, 2010
Accepted December 28, 2010
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Improved performance of Mo-V-Te-Nb-Ox catalysts prepared from a solution containing drying control chemical additives in propane oxidation to acrylic acid
School of Chemical & Biological Engineering and Institute of Chemical Processes, Seoul National University, Seoul 151-744, Korea
shmoon@surf.snu.ac.kr
Korean Journal of Chemical Engineering, June 2011, 28(6), 1364-1371(8), 10.1007/s11814-010-0528-5
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Abstract
Mo1.0V0.4Te0.25Nb0.24Ox catalyst was prepared by hydrothermal synthesis in a solution containing a drying control chemical additive (DCCA) such as propionic acid (PA) or formamide (FA). The performance of the prepared catalysts in propane oxidation for producing acrylic acid (AA) was improved because the catalyst showed an increase in both the activity and AA selectivity. The activity was increased due to an increase in the surface area and in the oxygen_x000D_
mobility. The AA selectivity was increased due to a decrease in the number of acidic sites, which were responsible for the unselective and deep oxidation of intermediates. The catalyst performance was degraded when excess amounts of DCCA were used in the preparation step because the surface area decreased, due to the residues of DCCA, and the surface density of acidic sites increased.
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Moro-oka Y, Ueda W, Adv. Catal., 40, 233 (1994)
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Cavani F, Koutyrev M, Trifiro F, Catal. Today, 24(3), 365 (1995)
Centi G, Trifiro F, Proceedings of Conference on Catalysis of Science and Technology, Tokyo, 225 (1991)
Ueda W, Suzuki Y, Chem. Lett., 24, 541 (1995)
Oliver JM, Nieto JML, Botella P, Mifsud A, Appl. Catal. A: Gen., 257(1), 67 (2004)
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Kaliaguine S, Van Neste A, Szabo V, Gallot JE, Bassir M, Muzychuk R, Appl. Catal. A: Gen., 209(1-2), 345 (2001)
Wu JM, Yang HP, Fan YN, Xu BL, Chen Y, J. Fuel Chem. Technol., 35, 684 (2007)
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Scherer GW, J. Non-Cryst. Solids., 100, 77 (1988)
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Kum SS, Jo BY, Moon SH, Appl. Catal. A: Gen., 365(1), 79 (2009)
Concepcion P, Botella P, Nieto JML, Appl. Catal. A: Gen., 278(1), 45 (2004)
Baca M, Pigamo A, Dubois JL, Millet JMM, Catal. Comm., 6, 215 (2005)
Concepcion P, Botella P, Nieto JML, Appl. Catal. A: Gen., 278(1), 45 (2004)
Ueda W, Vitry D, Katou T, Catal. Today, 99(1-2), 43 (2005)
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Weng LT, Delmon B, Appl. Catal. A., 81, 141 (1992)
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Holmberg J, Grasselli RK, Andersson A, Top. Catal., 23, 55 (2003)
Grasselli RK, Catal. Today, 99(1-2), 23 (2005)