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Received September 6, 2010
Accepted December 8, 2010
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Solubility of red pepper (Capsicum annum) oil in nearand supercritical carbon dioxide and quantification of capsaicin
Kyung-Tae Kwon
Md. Salim Uddin
Go-Woon Jung
Jeong-Eun Sim
Seung-Mi Lee
Hee-Chul Woo1
Byung-Soo Chun†
Department of Food Science and Technology, Pukyong National University, Busan 608-737, Korea 1Department of Chemical Engineering, Pukyong National University, Busan 608-737, Korea
bschun@pknu.ac.kr
Korean Journal of Chemical Engineering, June 2011, 28(6), 1433-1438(6), 10.1007/s11814-010-0515-x
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Abstract
Red pepper oil was extracted using near- and supercritical carbon dioxide. Extraction was carried out at pressures ranging from 10 to 35 MPa and temperatures from 30 to 60 oC, with a CO2 flow rate of 24.01 g/min using a semi-continuous high-pressure extraction apparatus. The duration for extraction was 2 h. The highest oil yield was found at high pressure and temperature. The highest solubility of oil (1.18mg/g of CO2) was found at 35 MPa and 60 ℃ . The solubility data of red pepper oil in near- and supercritical CO2 were fitted in Chrastil model. The fatty acid composition of red pepper oil was analyzed by gas chromatography (GC). Linoleic acid was found to be the major fatty acid in the oil. Capsaicin was quantified in different extracts by high performance liquid chromatography (HPLC). The highest capsaicin yield was found at 35 MPa and 60 ℃.
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de la Fuente JC, Valderrama JO, Bottini SB, del Valle JM, J. Supercrit. Fluids, 34(2), 195 (2005)
Morita A, Kajimoto O, J. Phys. Chem., 94, 6420 (1990)
Bai S, Craig MV, Liu LF, Mayne CL, Pugmire RJ, Grant DM, J. Phys. Chem., 101, 2923 (1997)
Bulgarevich DS, Sako T, Sugeta T, Otake K, Takebayashi Y, Kamizawa C, Horikawa Y, Kato M, Ind. Eng. Chem. Res., 41(9), 2074 (2002)
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Sovova H, Zarevucka M, Vacek M, Stransky K, J. Supercrit. Fluids, 20(1), 15 (2001)
Ozkal SG, Yener ME, Bayindirli L, Int. J. Food Sci. Technol., 41, 399 (2006)
Gnayfeed MH, Daood HG, Illes V, Biacs PA, J. Agric. Food Chem., 49, 2761 (2001)
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Daood HG, Illes V, Gnayfeed MH, Meszaros B, Horvath G, Biacs PA, J. Supercrit. Fluids, 23(2), 143 (2002)
