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Received November 9, 2010
Accepted December 28, 2010
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Modification and characterization of amberlite XAD-2 with calcein blue for preconcentration and determination of copper(II) from environmental samples by atomic absorption spectroscopy
Elham Moniri†
Homayon Ahmad Panahi1
Meghdad Karimi1
Nasir Ahmad Rajabi1
Mohammad Faridi1
Mahboobeh Manoochehri1
Department of Chemistry, Islamic Azad University, Varamin (Pishva) Branch, Iran 1Department of Chemistry, Islamic Azad University, Central Tehran Branch, Iran
Korean Journal of Chemical Engineering, July 2011, 28(7), 1523-1531(9), 10.1007/s11814-010-0529-4
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Abstract
A chelating resin is produced by coupling a dye calcein blue to Amberlite XAD-2 through an azo spacer. The resulting resin has been characterized by FT-IR, elemental analysis, thermogravimetric analysis (TGA) and scanning electron microscopy (SEM) studied for the preconcentration and determination of trace Cu(II) from solution samples. The optimum pH for adsorption of copper ions was 6. The sorption capacity of functionalized resin is 27 mg·g^(-1). The chelating resin can be reused for 10 cycles without any significant changes in sorption capacity. A recovery of 100% was obtained for Cu(II) when eluted with 0.5M nitric acid. Scatchard analysis revealed that homogeneous binding sites were formed in the resin. The equilibrium adsorption data of Cu(II) on modified resin were analyzed by Langmuir, Freundlich and Temkin models. Based on equilibrium adsorption data the Langmuir, Freundlich and Temkin constants_x000D_
were determined 0.036, 2.196 and 0.348 at pH 6 and 20 ℃, respectively. The method was applied for Cu(II) assay in environmental samples.
Keywords
References
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Tokalloglu S, Oymak T, Kartal S, Microchim. Acta., 159, 133 (2007)
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FeizBakhsh A, Ahmad Panahi H, Nikpour Nezhati M, Water Environ. Res., 81(5), 532 (2009)
Nezhati MN, Panahi HA, Moniri E, Kelahrodi SR, Assadian F, Karimi M, Korean J. Chem. Eng., 27(4), 1269 (2010)
Ahmad Panahi H, Morshedian J, Mehmandost N, Moniri E, Galaev IY, J. Chromatogr. A., 1217, 5165 (2010)
Ghaedi M, Shokrollahi A, Kianfar AH, Mirsadeghi AS, Pourfarokhi A, Soylak M, J. Hazard. Mater., 154(1-3), 128 (2008)
Ghaedi M, Ahmadi F, Shokrollahi A, J. Hazard. Mater., 142(1-2), 272 (2007)
Ghaedi M, Fathi MR, Marahel F, Ahmadi F, Fresenius Environ. Bull., 14, 1158 (2005)
Ghaedi M, Niknam K, Taheri K, Hossainian H, Soylak M, Food Chem. Toxicol., 48(3), 891 (2010)
Langmuir L, J. Am. Chem. Soc., 40, 1361 (1918)
Hall KL, Eagleton LC, Acrivos A, Vermeulen T, Ind. Eng. Chem. Fundam., 5, 212 (1966)
Frendlich HMA, J. Phys. Chem., 57, 385 (1906)
Ho Y, Augustine E, Biochem. Eng. J., 30, 117 (2006)
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Feist B, Mikula B, Pytlakowska K, Puzio B, Buhl F, J. Hazard. Mater., 152(3), 1122 (2008)
Umashankar V, Radhamani R, Ramadoss K, Murty DSR, Talanta., 57, 1029 (2002)
Divrikli U, Elci L, Anal. Chim. Acta., 452, 231 (2002)
Soylak M, Saracoglu S, Divrikli U, Elci L, Talanta., 66, 1098 (2005)
Sahin U, Tokahoglu S, Kartal S, Ulgen A, Chem. Anal., 50, 529 (2005)
Ngeontae W, Aeungmaitrepirom W, Tuntulani T, Talanta., 71, 1075 (2007)
Xie F, Lin X, Wu X, Xie Z, Talanta., 74, 836 (2008)
Meesri S, Praphairaksit N, Imyim A, Microchem. J., 87, 47 (2007)
Saracoglu S, Elci L, Anal. Chim. Acta., 452, 77 (2007)
Hirata S, Kajiya T, Takano N, Aihara M, Hondac K, Shikino O, Nakayama E, Anal. Chim. Acta., 499, 157 (2003)
Jankowski K, Yaob J, Kasiura K, Jackowska A, Sieradzka A, Spectrochim. Acta Part B., 60, 369 (2005)
Soylak M, Tuzen M, J. Hazard. Mater., 137(3), 1496 (2006)
Akl MAA, Kenawy IMM, Lasheen RR, Microchem. J., 78, 143 (2004)
