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Received October 6, 2010
Accepted January 12, 2011
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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The removal of low concentration formaldehyde over sewage sludge char treated using various methods
1Graduate School of Energy and Environmental Engineering, University of Seoul, Seoul 130-743, Korea 2Department of Environmental Engineering, Sunchon National University, Suncheon 540-742, Korea 3Department of Chemical Engineering, Kongju National University, Cheonan 330-717, Korea 4Department of Environmental Engineering, Kwangwoon University, Seoul 139-701, Korea 5Department of Chemical Engineering, Kangwon National University, Samcheok 245-711, Korea 6School of Environmental Engineering, University of Seoul, Seoul 130-743, Korea
catalica@uos.ac.kr
Korean Journal of Chemical Engineering, July 2011, 28(7), 1556-1560(5), 10.1007/s11814-011-0007-7
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Abstract
Sewage sludge char was activated, using several different methods, to be used for the adsorption of formaldehyde. First, sewage sludge was pyrolyzed at 700℃ for one hour to produce char. The sewage sludge char was then activated with 20% steam gas. To produce a chemically activated char, KOH was used with the char at a weight ratio of KOH/char=0.5. To produce another kind of activated char containing nitrogen functional groups, the sewage sludge char was activated with ammonia at 350℃ . These activated chars were used for indoor low concentration formaldehyde adsorption experiments. All the chars tested in this study were shown to have better performance than activated carbon. In particular, the char activated with both ammonia and KOH showed the best formaldehyde adsorption performance. This result was attributed to the combination of surface basicity due to large amounts of metal components and generation of oxygen and nitrogen functional groups as a result of the KOH and ammonia treatments.
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Busca G, Lamotte J, Lavally JC, Lorenzelli V, J. Am. Chem.Soc., 109, 5197 (1987)
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El-Sayed Y, Bandosz TJ, Stud. Surf. Sci. Catal., 144, 247 (2002)