Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received December 20, 2010
Accepted March 4, 2011
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Experimental and model investigation on the mass balance of a dry circulating fluidized bed for flue gas desulfurization system
Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Thermal Engineering, Tsinghua University, Beijing 100084, China
Korean Journal of Chemical Engineering, September 2011, 28(9), 1956-1963(8), 10.1007/s11814-011-0056-y
Download PDF
Abstract
A moderate temperature dry circulating fluidized bed flue gas desulfurization (CFB-FGD) process was developed using rapidly hydrated sorbent. This technique has the advantages of low cost, no water consumption, and a valuable dry product CaSO4. To keep the system operation stable, a mass balance model, based on cell model considering flow state, particle abrasion, particle residence time, particle segregation and desulfurization processes, was built to predict the system state and optimize the operating condition. Experimental studies were conducted on a pilotscale CFB-FGD system with rapidly hydrated sorbent made from CFB circulating ash and lime (circulating ash sorbent) or coal fly ash and lime (coal fly ash sorbent). Calculated results were compared with experimental results and the relative error was less than 10%. The results indicated that feed sorbent mass, feed sorbent size, superficial gas velocity, particle abrasion coefficient and cyclone efficiency had significant influence on the mass balance of CFB system. The circulating ash sorbent was better than the coal fly ash sorbent, for providing higher desulfurization efficiency and being better for the CFB-FGD system to achieve mass balance.
Keywords
References
Soud H, IEA Coal Research., 18 (1995)
Sai JC, Wu SH, Xu R, Sun R, Zhao Y, Qin YK, Korean J. Chem. Eng., 24, 3 (2007)
Xu GW, Guo QM, Kaneko T, Kato K, Adv. Environ. Res., 4, 9 (2000)
Zaremba T, Mokrosz W, Hehlmann J, Szwalikowska A, Stapinski G, Korean J. Chem. Eng., 93, 2 (2008)
Matsushima N, Li Y, Nishioka M, Sadakata M, Qi HY, Xu XC, Environ. Sci. Technol., 38, 6867 (2004)
Hou B, Qi HY, You CF, Xu XC, Energy Fuels, 19(1), 73 (2005)
Zhang J, You CF, Qi HY, Chen CH, Xu XC, Environ. Sci. Technol., 40, 4300 (2006)
Zhang J, Zhao SW, You CF, Qi HY, Chen CH, Ind. Eng. Chem. Res., 46(16), 5340 (2007)
Li Y, You CF, Song CX, Environ. Sci. Technol., 44, 4692 (2010)
Yang HR, Yue GX, Wang Y, Lv JF, J. Eng. Thermal Energy Power., 20, 291 (2005)
Yang HR, Xiao XB, Wirsum M, Yue GX, Fett FN, Coal Convers., 25, 59 (2002)
Tsuo YP, Gidaspow D, AIChE J., 36, 885 (1990)
Sun B, Gidaspow D, Ind. Eng. Chem. Res., 38(3), 787 (1999)
Ni WD, Li Z, Xu XD, Proceedings of European Simulation Symposium., 9 (1994)
Luo ZY, Li XT, Wang QH, Chen LM, Ni MJ, Cen KF, Power Eng., 14, 19 (1994)
Wen CY, Chen LH, AIChE J., 28, 117 (1982)
Kunni D, Levenspiel O, Powder Technol., 61, 193 (1990)
Rhodes MJ, Geldart D, Powder Technol., 53, 155 (1987)
Johnsson F, Andersson S, Leckner B, Powder Technol., 68, 117 (1991)
Arena U, Amore MD, Massimilla L, AIChE J., 29, 40 (1983)
Merrick D, Cullinan J, AIChE Symp. Ser., 70, 366 (1974)
Vaux WG, Schruben JS, AIChE Symp. Ser., 79, 97 (1983)
Cook JL, Khang SJ, Lee SK, Keener TC, Powder Technol., 89(1), 1 (1996)
Li Y, Song CX, You CF, Energy Fuels., 24, 1682 (2010)
Hirschberg B, Werther J, AIChE J., 44(1), 25 (1998)
Van den Moortel T, Azario E, Santini R, Tadrist L, Chem. Eng. Sci., 53(10), 1883 (1998)
Shih SM, Ho CS, Song YS, Lin JP, Ind. Eng. Chem. Res., 38(4), 1316 (1999)
Liu CF, Shih SM, Ind. Eng. Chem. Res., 33, 407 (2002)
Irabien A, Cortabitarte F, Ortiz MI, Chem. Eng. Sci., 47, 1533 (2002)
Fernandez J, Garea A, Irabien A, Chem. Eng. Sci., 25, 1091 (1970)
Li Y, Yang L, You C, Qi H, Korean J. Chem. Eng., 26(4), 1155 (2009)
Sai JC, Wu SH, Xu R, Sun R, Zhao Y, Qin YK, Korean J. Chem. Eng., 24, 3 (2007)
Xu GW, Guo QM, Kaneko T, Kato K, Adv. Environ. Res., 4, 9 (2000)
Zaremba T, Mokrosz W, Hehlmann J, Szwalikowska A, Stapinski G, Korean J. Chem. Eng., 93, 2 (2008)
Matsushima N, Li Y, Nishioka M, Sadakata M, Qi HY, Xu XC, Environ. Sci. Technol., 38, 6867 (2004)
Hou B, Qi HY, You CF, Xu XC, Energy Fuels, 19(1), 73 (2005)
Zhang J, You CF, Qi HY, Chen CH, Xu XC, Environ. Sci. Technol., 40, 4300 (2006)
Zhang J, Zhao SW, You CF, Qi HY, Chen CH, Ind. Eng. Chem. Res., 46(16), 5340 (2007)
Li Y, You CF, Song CX, Environ. Sci. Technol., 44, 4692 (2010)
Yang HR, Yue GX, Wang Y, Lv JF, J. Eng. Thermal Energy Power., 20, 291 (2005)
Yang HR, Xiao XB, Wirsum M, Yue GX, Fett FN, Coal Convers., 25, 59 (2002)
Tsuo YP, Gidaspow D, AIChE J., 36, 885 (1990)
Sun B, Gidaspow D, Ind. Eng. Chem. Res., 38(3), 787 (1999)
Ni WD, Li Z, Xu XD, Proceedings of European Simulation Symposium., 9 (1994)
Luo ZY, Li XT, Wang QH, Chen LM, Ni MJ, Cen KF, Power Eng., 14, 19 (1994)
Wen CY, Chen LH, AIChE J., 28, 117 (1982)
Kunni D, Levenspiel O, Powder Technol., 61, 193 (1990)
Rhodes MJ, Geldart D, Powder Technol., 53, 155 (1987)
Johnsson F, Andersson S, Leckner B, Powder Technol., 68, 117 (1991)
Arena U, Amore MD, Massimilla L, AIChE J., 29, 40 (1983)
Merrick D, Cullinan J, AIChE Symp. Ser., 70, 366 (1974)
Vaux WG, Schruben JS, AIChE Symp. Ser., 79, 97 (1983)
Cook JL, Khang SJ, Lee SK, Keener TC, Powder Technol., 89(1), 1 (1996)
Li Y, Song CX, You CF, Energy Fuels., 24, 1682 (2010)
Hirschberg B, Werther J, AIChE J., 44(1), 25 (1998)
Van den Moortel T, Azario E, Santini R, Tadrist L, Chem. Eng. Sci., 53(10), 1883 (1998)
Shih SM, Ho CS, Song YS, Lin JP, Ind. Eng. Chem. Res., 38(4), 1316 (1999)
Liu CF, Shih SM, Ind. Eng. Chem. Res., 33, 407 (2002)
Irabien A, Cortabitarte F, Ortiz MI, Chem. Eng. Sci., 47, 1533 (2002)
Fernandez J, Garea A, Irabien A, Chem. Eng. Sci., 25, 1091 (1970)
Li Y, Yang L, You C, Qi H, Korean J. Chem. Eng., 26(4), 1155 (2009)