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Received February 1, 2012
Accepted May 22, 2012
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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One-step synthesis of mesoporous sulfated zirconia nanoparticles with anionic template
Faculty of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650093, P. R. China
Korean Journal of Chemical Engineering, October 2012, 29(10), 1285-1288(4), 10.1007/s11814-012-0074-4
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Abstract
Mesoporous sulfated zirconia nanoparticles (MSZNP) with high surface area have been synthesized by using sodium dodecyl sulfate (C12H25OSO3Na, SDS), both as a template and a sulfating agent via one-step route. On the basis of FT-IR, EDS together with NH3-TPD analyses, the SO42. anion, originated from the hydrophilic head of SDS, can be incorporated into ZrO2 to form MSZNP with super-acidity. The phase transition of ZrO2 from tetragonal to monoclinic phase was effectively inhibited by the presence of SO42., and the formation mechanism was illustrated in detail. MSZNP(550) achieved far higher activity than CSZ(550) in transesterification of soybean oil with methanol due to the synergistic effect of strong acidity, high BET surface area and the formation of mesostructure.
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Suh YW, Lee JW, Rhee HK, Appl. Catal. A: Gen., 274(1-2), 159 (2004)
Devulapelli VG, Weng HS, Catal. Commun., 10, 1711 (2009)
Lutecki M, Solcova O, Werner S, Breitkopf C, J. Sol.-Gel. Sci.Technol., 53, 13 (2010)
McIntosh DJ, Kydd RA, Micropor. Mesopor. Mater, 37, 281 (2000)
Signoretto M, Breda A, Somma F, Pinna F, Cruciani G, Micropor. Mesopor. Mater., 91, 23 (2006)
Sun YY, Yuan LN, Wang W, Chen CL, Xiao FS, Catal. Lett., 87(1-2), 57 (2003)
Das SK, Bhunia MK, Sinha AK, Bhaumik A, J. Phys.Chem. C., 113, 8918 (2009)
Melada S, Ardizzone SA, Bianchi CL, Micropor. Mesopor.Mater., 73, 203 (2004)
Sun YY, Ma SQ, Du YC, Yuan L, Wang SC, Yang J, Deng F, Xiao FS, J. Phys. Chem. B, 109(7), 2567 (2005)
Ciesla U, Schacht S, Stucky GD, Schuth F, Angew. Chem.Int. Ed., 35, 541 (1996)
Pacheco G, Zhao E, Garcia A, Sklyarov A, Fripiat JJ, Chem.Commun., 491 (1997)
Ozawa M, Yokoi D, Suzuki S, J. Mater. Sci. Lett., 22(21), 1543 (2003)
Tanev PT, Pinnavaia TJ, Science, 267(5199), 865 (1995)
Cabrera S, El Haskouri J, Alamo J, Beltran A, Beltran D, Mendioroz S, Marcos MD, Amoros P, Adv. Mater., 11(5), 379 (1999)
Luo YM, Hou ZY, Jin DF, Gao J, Zheng XM, Mater. Lett., 60, 393 (2006)
Babou F, Coudurier G, Vedrine JC, J. Catal., 152(2), 341 (1995)
Lochar V, Appl. Catal. A: Gen., 309(1), 33 (2006)
Bernal HG, Caero LC, Finocchio E, Busca G, Appl. Catal. A: Gen., 369(1-2), 27 (2009)
Pacheco G, Zhao E, Valdes ED, Garcia A, Fripiat JJ, Micropor. Mesopor. Mater., 32, 175 (1999)
Yamaguchi T, Catal. Today., 20, 199 (1994)
Reddy BM, Sreekanth PM, Reddy VR, J. Mol. Catal. A-Chem., 225(1), 71 (2005)
D’Epifanio A, Navarra MA, Weise FC, Mecheri B, Farrington J, Licoccia S, Greenbaum S, Chem. Mater., 22, 813 (2010)
Hristovski KD, Westerhoff PK, Crittenden JC, Olson LW, Environ. Sci. Technol., 42, 3786 (2008)
Hristovski K, Baumgardner A, Westerhoff P, J. Hazard. Mater., 147(1-2), 265 (2007)
Wang H, Han CY, Pu HP, Zhang LY, Zou ZH, Luo YM, Bull. Chem. Soc. Jpn., 83, 852 (2010)
Luo YM, Hou ZY, Li RT, Zheng XM, Can. J. Chem., 85, 379 (2007)
Harmer MA, Farneth WE, Sun Q, Adv. Mater., 10(15), 1255 (1998)
van Rhijn WM, de Vos DE, Sels BF, Bossaert WD, Jacobs PA, Chem. Commun., 317 (1998)