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Received January 2, 2012
Accepted April 17, 2012
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Thermal stabilities of polyphenols and fatty acids in Laminaria japonica hydrolysates produced using subcritical water
Department of Food Science and Technology, Pukyong National University, Yongso-ro 45, Nam-gu, Busan 608-737, Korea 1Department of Chemical Engineering, Pukyong National University, Yongso-ro 45, Nam-gu, Busan 608-737, Korea
bschun@pknu.ac.kr
Korean Journal of Chemical Engineering, November 2012, 29(11), 1604-1609(6), 10.1007/s11814-012-0051-y
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Abstract
We investigated the thermal stability of polyphenols and fatty acids from Laminaria japonica powder by subcritical water hydrolysis among the range of the experimental conditions. The experiment was carried out at temperatures and pressures ranging from 200 to 280 ℃ and 13 to 60 bar, respectively for 28 to 42 min. Polyphenol and fatty acids in hydrolysates obtained from different conditions were analyzed by GC and UV-spectrophotometer. The results were compared with those obtained from Laminaria japonica oils extracted by supercritical CO2. Polyphenol and several fatty acids in hydrolysates produced by subcritical water showed high thermal stability.
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References
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Kohno H, Suzuki R, Noguchi R, Hosokawa M, Miyashita K, Tanaka T, Jpn. J. Cancer Res., 93, 133 (2002)
Kohno H, Suzuki R, Yasui Y, Hosokawa M, Miyashita K, Tanaka T, Cancer Sci., 95, 481 (2004)
Nomura T, Kikuchi M, Kubodera A, Kawakami Y, Biochem.Moi. Biol. Int., 42(2), 361 (1997)
Emmons CL, Peterson DM, Crop Sci., 41, 1676 (2001)
Shahidi F, Naczk M, in Phenolics in food and nutraceuticals, Shahidi F, Naczk M Eds., Boca Raton, Fla. CRC Press, 403 (2004)
Foster NR, Singh H, Jimmy Yun SL, Tomasko DL, McNaughton SJ, Ind. Eng. Chem. Res., 32, 2849 (1993)
McHugh MA, Krukonis VJ, Butterworth-Heinemann, Boston, MA, 2nd, 85 (1994)
Noh MJ, Kim TG, Hong IK, Yoo KP, Korean J. Chem. Eng., 12(1), 48 (1995)
Choi YH, Kim J, Noh MJ, Park EM, Yoo KP, Korean J. Chem. Eng., 13(2), 216 (1996)
York P, PSTT., 2(11), 430 (1999)
Baek JK, Kim S, Lee GS, Shim JJ, Korean J. Chem. Eng., 21(1), 230 (2004)
Muthukumaran P, Gupta RB, Sung HD, Shim JJ, Bae HK, Korean J. Chem. Eng., 16(1), 111 (1999)
Fernandez-Prini RJ, Corti HR, Japas MJ, High-Temperature Aqueous Solutions: Thermodynamic Properties, CRC Press, Boca Raton, FL (1992)
Herrero M, Cifuentes A, Ibanez E, Food Chem., 98(1), 136 (2006)
Schlesier K, Harwat M, Bohm V, Bitsch R, Free Radic Res., 36, 177 (2002)
Determination of substances characteristic of green and black tea.Part 1: Content of total polyphenols in tea, Colorimetric method using Folin-Ciocalteu reagent, ISO 145021-1: (2005)
Watchararuji K, Goto M, Sasaki M, Shotipruk A, Bioresour. Technol., 99(14), 6207 (2008)
Morita A, Kajimoto O, J. Phys. Chem., 94, 6420 (1990)
de Azevedo ABA, Kieckbush TG, Tashima AK, Mohamed RS, Mazzafera P, de Melo SABV, J. Supercrit. Fluids, 44(2), 186 (2008)
Park JY, Lee MK, Uddin MS, Chun BS, Biotechnol. Bioprocess Eng., 13, 298 (2008)
Sanchez-Vicente Y, Cabanas A, Renuncio JAR, Pando C, J. Supercrit. Fluids, 49(2), 167 (2009)
Holliday RL, King JW, List GR, Ind. Eng. Chem. Res., 36(3), 932 (1997)
Lamoolphak W, Goto M, Sasaki M, Suphantharika M, Wangnapoh C, Prommuag C, Shotipruk A, J. Hazard. Mater., 137(3), 1643 (2006)
Khuwijitjaru P, Fujii T, Adachi S, Kimura Y, Matsuno R, Chem. Eng. J., 99(1), 1 (2004)
Sasaki M, Fang Z, Fukushima Y, Adschiri T, Arai K, Ind. Eng. Chem. Res., 39(8), 2883 (2000)
Sereewatthanawut I, Prapintip S, Watchiraruji K, Goto M, Sasaki M, Shotipruk A, Bioresour. Technol., 99(3), 555 (2007)
Cheigh CI, Chung EY, Ko MJ, Cho SW, Chang PS, Food Eng. Prog., 14(4), 335 (2010)
Smith RM, J. Chromatogr. A., 975, 31 (2002)
Andersson T, Parameters affecting the extraction of polycylic aromatic hydrocarbons with pressurized hot water, Academic dissertation, University of Helsinki, Finland (2007)