Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received December 27, 2011
Accepted May 19, 2012
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Tie-line data for aqueous mixtures of butyric acid with isobutyl acetate at various temperatures
Department of Chemical Engineering, University of Guilan, 41335 Rasht, Iran 1Department of Chemistry, University of Guilan, 41335 Rasht, Iran
hggilani@guilan.ac.ir
Korean Journal of Chemical Engineering, November 2012, 29(11), 1615-1621(7), 10.1007/s11814-012-0067-3
Download PDF
Abstract
Experimental liquid-liquid equilibrium (LLE) data for the system of (water+butyric acid+iso-butyl acetate) were obtained at T=(298.2, 303.2, 308.2, and 313.2) K and atmospheric pressure. This ternary system exhibits type-1 behavior of LLE. The experimental tie-line data were correlated using the UNIQUAC and NRTL models. The reliability of the experimental tie-line data was determined by applying the Othmer.Tobias and Hand correlations. Distribution coefficients and separation factors were calculated over the immiscibility regions.
References
Senol A, Fluid Phase Equilib., 243(1-2), 51 (2006)
Ozmen D, J. Chem. Thermodyn., 39(1), 123 (2007)
Ozmen D, Fluid Phase Equilib., 269(1-2), 12 (2008)
Uslu H, Kirbaslar SI, Fluid Phase Equilib., 287(2), 134 (2010)
Sahin S, Kirbaslar SI, Bilgin M, J. Chem. Thermodyn., 41(1), 97 (2009)
Kirbaslar SI, Sahin S, Bilgin M, J. Chem. Thermodyn., 39(11), 1463 (2007)
Bilgin M, Arisoy C, Fluid Phase Equilib., 250(1-2), 59 (2006)
Almuhtaseb SA, Fahim MA, Fluid Phase Equilib., 123(1-2), 189 (1996)
Vandak D, Zigova J, Syturdik E, Schlosser S, Process Biochem., 32, 245 (1977)
Sabolova E, Schlosser S, Martak J, J. Chem. Eng. Data., 46, 735 (2001)
Li ZY, Qin W, Dai YY, J. Chem. Eng. Data, 47(4), 843 (2002)
Kirbaslar SI, Sahin S, Bilgin M, J. Chem. Thermodyn., 39(9), 1279 (2007)
Kirbaslar SI, J. Chem. Thermodyn., 38(6), 696 (2006)
Kirbaslar SI, Bilgin M, Batr D, J. Chem. Thermodyn., 37(2), 175 (2005)
Bilgin M, J. Chem. Thermodyn., 38, 1643 (2006)
Bilgin M, Kirbaslar SI, Ozcan O, Dramur U, J. Chem. Thermodyn., 37(4), 297 (2005)
Gok A, Kirbaslar SI, Uslu H, Gilani HG, Fluid Phase Equilib., 303(1), 71 (2011)
Ghanadzadeh H, Ghanadzadeh A, Asgharzadeh S, Dastmoozeh N, Thermochim. Acta, 523(1-2), 154 (2011)
Ghanadzadeh H, Ghanadzadeh A, Aghajani Z, Abbasnejad S, Shekarsaraee S, J. Chem. Thermodyn., 42(6), 695 (2010)
Abrams DS, Prausnitz JM, AIChE J., 21, 116 (1975)
Renon H, Prausnitz JM, AIChE J., 14, 135 (1968)
Peschke N, Sandler SI, J. Chem. Eng. Data, 40(1), 315 (1995)
Li HD, Tamura K, Fluid Phase Equilib., 263(2), 223 (2008)
Merzougui A, Hasseine A, Kabouche A, Korichi M, Fluid Phase Equilib., 309(2), 161 (2011)
Bondi A, J. Phys. Chem., 68, 441 (1964)
Bondi A, Physical Properties of Molecular Crystals, Liquids and Glasses, John Wiley and Sons Inc., New York (1968)
Banerjee T, Singh MK, Sahoo RK, Khanna A, Fluid Phase Equilib., 234(1-2), 64 (2005)
Othmer DF, Tobias PE, Ind. Eng. Chem., 34, 690 (1942)
Brandani V, Chianese A, Rossi M, J. Chem. Eng. Data., 30, 27 (1985)
Chafer A, de la Torre J, Monton JB, Lladosa E, Fluid Phase Equilib., 265(1-2), 122 (2008)
Ghanadzadeh Gilani H, Golpour M, Abbasi Souraki B, AAPG Bull., 49, 39 (2010)
Ozmen D, J. Chem. Thermodyn., 39(1), 123 (2007)
Ozmen D, Fluid Phase Equilib., 269(1-2), 12 (2008)
Uslu H, Kirbaslar SI, Fluid Phase Equilib., 287(2), 134 (2010)
Sahin S, Kirbaslar SI, Bilgin M, J. Chem. Thermodyn., 41(1), 97 (2009)
Kirbaslar SI, Sahin S, Bilgin M, J. Chem. Thermodyn., 39(11), 1463 (2007)
Bilgin M, Arisoy C, Fluid Phase Equilib., 250(1-2), 59 (2006)
Almuhtaseb SA, Fahim MA, Fluid Phase Equilib., 123(1-2), 189 (1996)
Vandak D, Zigova J, Syturdik E, Schlosser S, Process Biochem., 32, 245 (1977)
Sabolova E, Schlosser S, Martak J, J. Chem. Eng. Data., 46, 735 (2001)
Li ZY, Qin W, Dai YY, J. Chem. Eng. Data, 47(4), 843 (2002)
Kirbaslar SI, Sahin S, Bilgin M, J. Chem. Thermodyn., 39(9), 1279 (2007)
Kirbaslar SI, J. Chem. Thermodyn., 38(6), 696 (2006)
Kirbaslar SI, Bilgin M, Batr D, J. Chem. Thermodyn., 37(2), 175 (2005)
Bilgin M, J. Chem. Thermodyn., 38, 1643 (2006)
Bilgin M, Kirbaslar SI, Ozcan O, Dramur U, J. Chem. Thermodyn., 37(4), 297 (2005)
Gok A, Kirbaslar SI, Uslu H, Gilani HG, Fluid Phase Equilib., 303(1), 71 (2011)
Ghanadzadeh H, Ghanadzadeh A, Asgharzadeh S, Dastmoozeh N, Thermochim. Acta, 523(1-2), 154 (2011)
Ghanadzadeh H, Ghanadzadeh A, Aghajani Z, Abbasnejad S, Shekarsaraee S, J. Chem. Thermodyn., 42(6), 695 (2010)
Abrams DS, Prausnitz JM, AIChE J., 21, 116 (1975)
Renon H, Prausnitz JM, AIChE J., 14, 135 (1968)
Peschke N, Sandler SI, J. Chem. Eng. Data, 40(1), 315 (1995)
Li HD, Tamura K, Fluid Phase Equilib., 263(2), 223 (2008)
Merzougui A, Hasseine A, Kabouche A, Korichi M, Fluid Phase Equilib., 309(2), 161 (2011)
Bondi A, J. Phys. Chem., 68, 441 (1964)
Bondi A, Physical Properties of Molecular Crystals, Liquids and Glasses, John Wiley and Sons Inc., New York (1968)
Banerjee T, Singh MK, Sahoo RK, Khanna A, Fluid Phase Equilib., 234(1-2), 64 (2005)
Othmer DF, Tobias PE, Ind. Eng. Chem., 34, 690 (1942)
Brandani V, Chianese A, Rossi M, J. Chem. Eng. Data., 30, 27 (1985)
Chafer A, de la Torre J, Monton JB, Lladosa E, Fluid Phase Equilib., 265(1-2), 122 (2008)
Ghanadzadeh Gilani H, Golpour M, Abbasi Souraki B, AAPG Bull., 49, 39 (2010)
