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Received December 28, 2011
Accepted May 16, 2012
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Removal of phenolic compounds from aqueous solutions using Aliquat 336 as a carrier in emulsion liquid membrane
Department of Petrochemical Technology, Anna University of Technology Tiruchirappalli, Tiruchirappalli-620 024, Tamil Nadu, India
venkat.set@gmail.com
Korean Journal of Chemical Engineering, November 2012, 29(11), 1622-1627(6), 10.1007/s11814-012-0066-4
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Abstract
A carrier-mediated separation of phenolic compounds from the dilute aqueous solution was studied with an emulsion liquid membrane, constituted by a solution of ionic liquid (Aliquat 336) in kerosene, sodium hydroxide as a stripping agent and Sorbitan monooleate as a surfactant. The effects on various operating parameters such as surfactant concentration, carrier concentration, emulsification time, strip agent concentration, stirring speed, phase volume ratio, external phase pH and treat ratio were experimentally investigated. Additionally, a stability test was performed_x000D_
under a static condition using Rose Bengal dye. The results showed that the stability of emulsion and extraction was enhanced on adding Aliquat 336 in membrane phase, and it has been verified by FT-IR spectra. By selecting appropriate conditions, the stability and life span of membrane was increased by six times and the percentage of removal of phenol increases upto 99.3% at the treat ratio of 3.
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Kujawski W, Warszawski A, Ratajczak W, Porebski T, Capala W, Ostrowska I, Sep. Purif. Technol., 40(2), 123 (2004)
Moussavi G, Barikbin B, Mahmoudi M, Chem. Eng. J., 158(3), 498 (2010)
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Majumder PS, Gupta SK, Bioresour. Technol., 98(1), 118 (2007)
Gupta VK, Ali I, Saini VK, Environ. Sci. Technol., 38, 4012 (2004)
Kallel M, Belaid C, Mechichi T, Ksibi M, Elleuch B, Chem. Eng. J., 150(2-3), 391 (2009)
Chedeville O, Debacq M, Porte C, Desalination, 249(2), 865 (2009)
Manojlovic D, Ostojic DR, Obradovic BM, Kuraica MM, Krsmanovic VD, Puric J, Desalination, 213(1-3), 116 (2007)
Kujawski W, Warszawski A, Ratajczak W, Porebski T, Capala W, Ostrowska I, Desalination, 163(1-3), 287 (2004)
Parida KM, Pradhan AC, J. Hazard. Mater., 173(1-3), 758 (2010)
Senel S, Kara A, Alsancak G, Denizli A, J. Hazard. Mater., 138(2), 317 (2006)
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Yavuz Y, Koparal AS, Ogutveren UB, Desalination, 258(1-3), 201 (2010)
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Venkatesan S, Begum KMMS, Desalination, 236(1-3), 65 (2009)
Vidal STM, Correia MJN, Marques MM, Ismael MR, Reis MTA, Sep. Sci. Technol., 39(9), 2155 (2004)
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Fan J, Fan YC, Pei YC, Wu K, Wang JJ, Fan MH, Sep. Purif. Technol., 61(3), 324 (2008)
Poole CF, Poole SK, J. Chromatogr. A., 1217, 2268 (2010)
Fan YC, Chen ML, Shen-Tu C, Zhu Y, J. Anal. Chem., 64, 1017 (2009)
Ettinger M, Ruchhoft C, Lishka R, Anal. Chem., 23, 1783 (1951)
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Nosrati S, Jayakumar NS, Hashim MA, J. Hazard. Mater., 192(3), 1283 (2011)
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Goyal RK, Jayakumar NS, Hashim MA, J. Hazard. Mater., 195, 55 (2011)
