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Received January 21, 2012
Accepted April 17, 2012
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Two-step rapid synthesis of mesoporous silica for green tire
Askwar Hilonga1 2
Jong-Kil Kim3 2
Pradip Bhikaji Sarawade1 4
Dang Viet Quang1
Godlisten Namwel Shao1
Gideon Elineema1
Hee Taik Kim1†
1Department of Chemical Engineering, Hanyang University, 55 Hanyangdaehak-ro, Sangnok-gu, Ansan-si, Gyeonggi-do 426-791, Korea 2Nelson Mandela African Institute of Science and Technology, Arusha, Tanzania, Korea 3Department of Chemical Engineering, Hanyang University, E&B Nanotech. Co., Ltd., 55 Hanyangdaehak-ro, Sangnok-gu, Ansan-si, Gyeonggi-do 426-791, Sa1-dong, Sangrok-gu, Ansan-si, Gyeonggi-do 426-901, Korea 4E&B Nanotech. Co., Ltd., Sa1-dong, Sangrok-gu, Ansan-si, Gyeonggi-do 426-901, Korea
Korean Journal of Chemical Engineering, November 2012, 29(11), 1643-1646(4), 10.1007/s11814-012-0053-9
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Abstract
We report a two-step rapid route of synthesizing inexpensive mesoporous silica using the waste material (hexafluorosilicic acid, H2SiF6) of phosphate fertilizer industry and sodium silicate (Na2O·SiO2). The reaction was performed in a newly innovated manufacturing apparatus. This apparatus produces mesoporous silica with uniform properties through controlled mixing of source materials at predetermined equivalent ratio. The precursors are rapidly mixed within the nozzles to enable uniform control of physical properties of the final product. The obtained mesoporous silica was characterized using N2 physisorption studies, scanning electron microscope (SEM), and EDS. The final product was found to have superior properties that are suitable for green tire (environmentally friendly tire) as inorganic filler. The process reported in this study may significantly reduce the release of hazardous materials into the environment and it might confer economic benefits to the responsible industries. A project on innovative industrial application of our products for the tire industry is in progress.
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Sikdar SK, Moore JH, Recovery of hydrofluoric acid from fluosilicic acid with high pH hydrolysis, US Patent, 4,213,951 (1980)
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Spijker R, Process for the Preparation of Pure Silicon Dioxide, European Patent, 94,139 (1983)
Sarawade PB, Kim JK, Hilonga A, Kim HT, J. Hazard. Mater., 173(1-3), 576 (2010)
Kim JI, Park JK, Kim HK, Materials Science Forum., 544-545, 877 (2007)
Dragicevic T, Hraste M, Chem. Biochem. Eng., 8(3), 141 (1994)
Additives for Polymers., Rhodia Silcea: New silica from Rhodia further improves tyre rolling resistance, 4, 3 (2008)
Chevallier, Rabeyrin, US Patent, 5,403,570, Rhone-Poulenc (1995)