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Received November 18, 2011
Accepted June 7, 2012
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Synthesis and characterization of nanocomposite MCM-48-PEHA-DEA and its application as CO2 adsorbent
Research Laboratory of Nanoporous Materials, Faculty of Chemistry, Iran University of Science and Technology, Farjam Street, Narmak, Tehran 16846, Iran
anbia@iust.ac.ir
Korean Journal of Chemical Engineering, December 2012, 29(12), 1776-1781(6), 10.1007/s11814-012-0090-4
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Abstract
Three nanocomposites containing MCM-48-35PEHA-15DEA (35 and 15 as weight percent of amine addition), MCM-48-30PEHA-20DEA and MCM-48-25PEHA-25DEA of mesoporous silica MCM-48 modified by the mixture of pentaethylenehexamine (PEHA) and diethanolamine (DEA) have been synthesized and used to study the adsorption of carbon dioxide (CO2). They are characterized by low angle x-ray diffraction (XRD), Fourier transform infrared (FT-IR) and Brunauer-Emmet-Teller (BET) analysis. MCM-48-35PEHA-15DEA (as optimized adsorbent)_x000D_
shows CO2 adsorption capacity of 0.51 (m·mol CO2/g-adsorbent) at 1 bar and 298 K, much higher than CO2 adsorption capacity on polyethyleneimine, pyrrolidinepropyl and polymerized aminopropyl loaded MCM-48.
Keywords
References
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Kikkinides ES, Yang RT, Cho SH, Ind. Eng. Chem. Res., 32, 2714 (1993)
Hyun SH, Song JK, Kwak BI, Kim JH, Hong SA, J.Mater. Sci., 34, 309 (1999)
Harlick PJE, Sayari A, Ind. Eng. Chem. Res., 46(2), 446 (2007)
Hook RJ, Ind. Eng. Chem. Res., 36(5), 1779 (1997)
Tan CS, Chen JE, Sep. Purif. Technol., 49(2), 174 (2006)
Krutka HM, Sjostrom SJ, Bustard CJ, Paper #08-A--Mega-AWMA., 173 (2008)
Chue KT, Kim JN, Yoo YJ, Cho SH, Yang RT, Ind. Eng. Chem. Res., 34(2), 591 (1995)
Katoh M, Yoshikawa T, Tomonari T, Katayama K, Tomida T, J. Colloid Interface Sci., 226(1), 145 (2000)
Mimura T, Simayoshi H, Suda T, Iijima M, Mituoka S, Energy Convers. Manage., Suppl. S., 57, 38 (1997)
Leci CL, Energy Convers. Manage., Suppl. S., 57, 38 (1997)
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Anbia M, Hariri SA, Desalination, 261(1-2), 61 (2010)
Anbia M, Lashgari M, Chem. Eng. J., 150(2-3), 555 (2009)
Anbia M, Moradi SE, Appl. Surf. Sci., 255(9), 5041 (2009)
Anbia M, Moradi SE, Chem. Eng. J., 148(2-3), 452 (2009)
Anbia M, Mohammadi N, Mohammadi K, J. Hazard. Mater., 176(1-3), 965 (2010)
Shen SC, Chen XY, Kawi S, Langmuir, 20(21), 9130 (2004)
Macario A, Katovic A, Giordano G, Iucolano F, Caputo D, Micropor. Mesopor. Mater., 81, 139 (2005)
Chaffee AL, Delaney SW, Knowles G, Abstr. Pap. 223rd ACS Nat., Meeting P (2002)
Huang HY, Yang RT, Chinn D, Munson CL, Ind. Eng. Chem. Res., 42(12), 2427 (2003)
Chang ACC, Chuang SSC, Gray M, Soong Y, Energy Fuels, 17(2), 468 (2003)
Kim S, Ida J, Guliants VV, Lin JYS, J. Phys. Chem. B, 109(13), 6287 (2005)
Anbia M, Mohammadi N, J. Porous. Mater., 18, 13 (2011)
Alfredsson V, Anderson MW, Chem. Mater., 8, 1141 (1996)
Mercier L, Pinnavaia T, J. Environ. Sci. Technol., 32, 2749 (1998)
Yoshitake H, Yokoi T, Tatsumi T, Chem. Mater., 14, 4603 (2002)
Xu XC, Song CS, Andresen JM, Miller BG, Scaroni AW, Energy Fuels, 16(6), 1463 (2002)
Jaroniec CP, Kruk M, Jaroniec M, Sayari A, J. Phys. Chem. B, 102(28), 5503 (1998)
Pierotti RA, Rouquerol J, Siemieniewska T, J. Pure Appl.Chem., 57, 603 (1985)
Leal O, Bolivar C, Ovalles C, Garcia JJ, Espidel Y, Inorg. Chim. Acta., 240, 183 (1995)
Satyapal S, Filburn T, Trela J, Strange J, Energy Fuels, 15(2), 250 (2001)
Yue MB, Sun LB, Cao Y, Wang ZJ, Wang Y, Yu Q, Zhu JH, Micropor. Mesopor. Mater., 114, 74 (2008)
Kim S, Ida J, Guliants VV, Lin JYS, J. Phys. Chem. B, 109(13), 6287 (2005)
Son WJ, Choi GS, Ahn WS, Micropor. Mesopor. Mater., 113, 31 (2008)
