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Received December 21, 2011
Accepted June 4, 2012
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Extraction of alkali metals using emulsion liquid membrane by nano-baskets of calix[4]crown
Razi Chemistry Research Center (RCRC), Shahreza Branch, Islamic Azad University, Shahreza, Iran
pourabdollah@iaush.ac.ir
Korean Journal of Chemical Engineering, December 2012, 29(12), 1788-1795(8), 10.1007/s11814-012-0085-1
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Abstract
Nano-assisted inclusion separation of alkali metals from basic solutions was reported by inclusion-facilitated emulsion liquid membrane process. The novelty of this study is the application of nano-baskets of calixcrown in the selective and efficient separation of alkali metals as both the carrier and the surfactant. For this aim, four derivatives of diacid calix[4]-1,2-crowns were synthesized, and their inclusion-extraction parameters were optimized including the calixcrown scaffold (13, 4 wt%) as the carrier/demulsifier, the commercial kerosene as diluent in membrane, sulphonic acid (0.2 M) and ammonium carbonate (0.4 M) as the strip and the feed phases, the phase and the treat ratios of 0.8 and 0.3, mixing speed (300 rpm), and initial solute concentration (100mg/L). The selectivity of membrane over more than ten interfering cations was examined and the results revealed that under the optimized operating condition, the degree of inclusion-extraction of alkali metals was as high as 98-99%.
References
Li NN, Separating hydrocarbons with liquid membranes, U.S. Patent, 3,410,794 (1968)
Kumbasar RA, Sahin I, J. Membr. Sci., 164, 712 (2008)
Chakraborty M, Bhattacharya C, Datta S, Colloids Surf. A: Physicochem. Eng. Aspects., 224, 65 (2003)
Ortiz I, San Roman MF, Corvalan SM, Eliceche AM, Ind. Eng. Chem. Res., 42(23), 5891 (2003)
Correia PFMM, de Carvalho JMR, J. Membr. Sci., 225(1-2), 41 (2003)
Park Y, Skelland AHP, Forney LJ, Kim JH, Water Res., 40, 1763 (2006)
Frankenfeld JW, Chan RP, Li NN, Sep. Sci. Technol., 16, 385 (1981)
Hou WQ, Papadopoulos KD, Chem. Eng. Sci., 51(22), 5043 (1996)
Wang ZH, Jiang YL, Fu JF, J. Membr. Sci., 109(1), 25 (1996)
Bandyopadhyaya R, Bhowal A, Datta S, Sanyal SK, Chem. Eng. Sci., 53(15), 2799 (1998)
Xuan-cai D, Fu-quan X, J. Membr. Sci., 59, 183 (1991)
Li NN, Borwankar RP, Chan CC, Wassan DT, Kurzeja RM, Gu ZM, AIChE J., 34, 753 (1988)
Florence AT, Whitehill D, J. Colloid Interface Sci., 79(1), 243 (1981)
Wan YH, Zhang XJ, J. Membr. Sci., 196(2), 185 (2002)
Ikeda H, Matsuhisa A, Ueno A, Chem. Eur. J., 9, 4907 (2003)
Teresa M, Reis A, de Freitas OMF, Rosinda M, Ismael C, Carvalho JMR, J. Membr. Sci., 305(1-2), 313 (2007)
Demirci A, Cotton JC, Pometto AL, Harkins KR, Hinz PN, Biotechnol. Bioeng., 83(7), 749 (2003)
Kaghazchi T, Kargari A, Yegani R, Zare A, Desalination, 190(1-3), 161 (2006)
Mohagheghi E, Alemzadeh I, Vossoughi M, Sep. Sci. Technol., 43, 307 (2008)
Oshima T, Inoue K, Furusaki S, Goto M, J. Membr. Sci., 217(1-2), 87 (2003)
Bayraktar E, Process Biochem., 37, 169 (2001)
Vasudevan M, Wiencek JM, Ind. Eng. Chem. Res., 35(4), 1085 (1996)
Habaki H, Egashira R, Stevens GW, Kawasaki J, J. Membr. Sci., 208(1-2), 89 (2002)
Lee SC, J. Ind. Eng. Chem., 14(2), 207 (2008)
Mokhtari B, Pourabdollah K, J. Coord. Chem., 64(17), 3081 (2011)
Mokhtari B, Pourabdollah K, J. Coord. Chem., 64, 4029 (2011)
Mokhtari B, Pourabdollah K, Dalali N, Chromatographia., 73(9-10), 829 (2011)
Mokhtari B, Pourabdollah K, J. Incl. Phenom. Macrocycl.Chem., DOI:10.1007/s10847-011-0099-z (2012)
Mokhtari B, Pourabdollah B, Dalali N, J. Incl. Phenom. Macrocycl.Chem., 69(1-2), 1 (2011)
Baeyer A, Chem. Ber., 5(1), 280 (1872)
Zinke A, Ziegler E, Chem. Ber., 77(3-4), 264 (1944)
Gutsche CD, Muthukrishnan R, J. Org. Chem., 43(25), 4905 (1978)
Mokhtari B, Pourabdollah K, Bull. Korean Chem. Soc., 21(11), 3855 (2011)
Mokhtari B, Pourabdollah K, Supramol. Chem., 23(10), 696 (2011)
Mokhtari B, Pourabdollah K, J. Therm. Anal. Calorim., DOI:10.1007/s10973-011-2014-7 (2012)
Mokhtari B, Pourabdollah B, J. Coord. Chem., 64(23), 4079 (2011)
Mokhtari B, Pourabdollah K, J. Incl. Phenom. Macrocycl.Chem., 73, 269 (2012)
Mokhtari B, Pourabdollah K, Bull. Korean Chem. Soc., 32(11), 3979 (2011)
Mokhtari B, Pourabdollah K, Dallali N, J. Radioanal. Nucl.Chem., 287(3), 921 (2011)
Mokhtari B, Pourabdollah K, Asian J. Chem., 23(11), 4717 (2011)
Mokhtari B, Pourabdollah K, J. Coord. Chem., 64(18), 3189 (2011)
Mokhtari B, Pourabdollah K, J. Incl. Phenom. Macrocycl.Chem., 73, 1 (2012)
Mokhtari B, Pourabdollah K, Dalali N, J. Coord. Chem., 64(5), 743 (2011)
Mokhtari B, Pourabdollah K, J. Electrochem. Soc., 159(3), K61 (2012)
Mokhtari B, Pourabdollah K, Electroanalysis., 24, 219 (2012)
Mokhtari B, Pourabdollah K, Desalination., 292, 1 (2012)
Mokhtari B, Pourabdollah K, J. Chilean Chem. Soc., 58(2), 827 (2012)
Mokhtari B, Pourabdollah K, Drug Chem. Toxicol., DOI: 10.3109/01480545.2011.653490 (2012)
Mokhtari B, Pourabdollah K, Supramol. Chem., 24, 255 (2012)
Mokhtari B, Pourabdollah K, J. Sci. Food Agric., DOI:10.1002/jsfa.5688 (2012)
Mokhtari B, Pourabdollah K, Bull. Korean Chem. Soc., DOI:10.5012/bkcs.2012.33.5.1 (2012)
Mokhtari B, Pourabdollah K, Can. J. Chem., 90, 560 (2012)
Mokhtari B, Pourabdollah K, Synth. React. Inorg. Metal Org. Chem., article in press. DOI:10.1080/15533174.2012.654879 (2012)
Mokhtari B, Pourabdollah K, Electrochim. Acta., 76, 363 (2012)
Mokhtari B, Pourabdollah K, Bull. Korean Chem. Soc., 33, 2320 (2012)
Mokhtari B, Pourabdollah K, J. Incl. Phenom. Macrocycl.Chem., DOI:10.1007/s10847-012-0210-0 (2012)
Mokhtari B, Pourabdollah K, J. Chinese Chem. Soc., DOI:10-1002/jccs.201100737 (2012)
Mokhtari B, Pourabdollah K, J. Liq. Chromatogr. R. T., DOI:10.1080/10826076.2011.643524 (2012)
Mokhtari B, Pourabdollah K, Talanta., 78, 118 (2011)
Teresa M, Reis A, Carvalho JMR, J. Membr. Sci., 84, 201 (1993)
Othman N, Mat H, Goto M, J. Membr. Sci., 282(1-2), 171 (2006)
Bhowal A, Datta S, J. Membr. Sci., 188(1), 1 (2001)
Venkateswaran P, Palanivelu K, Hydrometallurgy., 78, 107 (2005)
Strzelbck J, Charewcz WA, Mackewcz A, Sep. Sci. Technol., 19, 321 (1984)
Thien MP, Hatton TA, Wang DIC, Biotechnol. Bioeng., 35, 853 (1990)
Kumbasar RA, Sahin I, J. Membr. Sci., 164, 712 (2008)
Chakraborty M, Bhattacharya C, Datta S, Colloids Surf. A: Physicochem. Eng. Aspects., 224, 65 (2003)
Ortiz I, San Roman MF, Corvalan SM, Eliceche AM, Ind. Eng. Chem. Res., 42(23), 5891 (2003)
Correia PFMM, de Carvalho JMR, J. Membr. Sci., 225(1-2), 41 (2003)
Park Y, Skelland AHP, Forney LJ, Kim JH, Water Res., 40, 1763 (2006)
Frankenfeld JW, Chan RP, Li NN, Sep. Sci. Technol., 16, 385 (1981)
Hou WQ, Papadopoulos KD, Chem. Eng. Sci., 51(22), 5043 (1996)
Wang ZH, Jiang YL, Fu JF, J. Membr. Sci., 109(1), 25 (1996)
Bandyopadhyaya R, Bhowal A, Datta S, Sanyal SK, Chem. Eng. Sci., 53(15), 2799 (1998)
Xuan-cai D, Fu-quan X, J. Membr. Sci., 59, 183 (1991)
Li NN, Borwankar RP, Chan CC, Wassan DT, Kurzeja RM, Gu ZM, AIChE J., 34, 753 (1988)
Florence AT, Whitehill D, J. Colloid Interface Sci., 79(1), 243 (1981)
Wan YH, Zhang XJ, J. Membr. Sci., 196(2), 185 (2002)
Ikeda H, Matsuhisa A, Ueno A, Chem. Eur. J., 9, 4907 (2003)
Teresa M, Reis A, de Freitas OMF, Rosinda M, Ismael C, Carvalho JMR, J. Membr. Sci., 305(1-2), 313 (2007)
Demirci A, Cotton JC, Pometto AL, Harkins KR, Hinz PN, Biotechnol. Bioeng., 83(7), 749 (2003)
Kaghazchi T, Kargari A, Yegani R, Zare A, Desalination, 190(1-3), 161 (2006)
Mohagheghi E, Alemzadeh I, Vossoughi M, Sep. Sci. Technol., 43, 307 (2008)
Oshima T, Inoue K, Furusaki S, Goto M, J. Membr. Sci., 217(1-2), 87 (2003)
Bayraktar E, Process Biochem., 37, 169 (2001)
Vasudevan M, Wiencek JM, Ind. Eng. Chem. Res., 35(4), 1085 (1996)
Habaki H, Egashira R, Stevens GW, Kawasaki J, J. Membr. Sci., 208(1-2), 89 (2002)
Lee SC, J. Ind. Eng. Chem., 14(2), 207 (2008)
Mokhtari B, Pourabdollah K, J. Coord. Chem., 64(17), 3081 (2011)
Mokhtari B, Pourabdollah K, J. Coord. Chem., 64, 4029 (2011)
Mokhtari B, Pourabdollah K, Dalali N, Chromatographia., 73(9-10), 829 (2011)
Mokhtari B, Pourabdollah K, J. Incl. Phenom. Macrocycl.Chem., DOI:10.1007/s10847-011-0099-z (2012)
Mokhtari B, Pourabdollah B, Dalali N, J. Incl. Phenom. Macrocycl.Chem., 69(1-2), 1 (2011)
Baeyer A, Chem. Ber., 5(1), 280 (1872)
Zinke A, Ziegler E, Chem. Ber., 77(3-4), 264 (1944)
Gutsche CD, Muthukrishnan R, J. Org. Chem., 43(25), 4905 (1978)
Mokhtari B, Pourabdollah K, Bull. Korean Chem. Soc., 21(11), 3855 (2011)
Mokhtari B, Pourabdollah K, Supramol. Chem., 23(10), 696 (2011)
Mokhtari B, Pourabdollah K, J. Therm. Anal. Calorim., DOI:10.1007/s10973-011-2014-7 (2012)
Mokhtari B, Pourabdollah B, J. Coord. Chem., 64(23), 4079 (2011)
Mokhtari B, Pourabdollah K, J. Incl. Phenom. Macrocycl.Chem., 73, 269 (2012)
Mokhtari B, Pourabdollah K, Bull. Korean Chem. Soc., 32(11), 3979 (2011)
Mokhtari B, Pourabdollah K, Dallali N, J. Radioanal. Nucl.Chem., 287(3), 921 (2011)
Mokhtari B, Pourabdollah K, Asian J. Chem., 23(11), 4717 (2011)
Mokhtari B, Pourabdollah K, J. Coord. Chem., 64(18), 3189 (2011)
Mokhtari B, Pourabdollah K, J. Incl. Phenom. Macrocycl.Chem., 73, 1 (2012)
Mokhtari B, Pourabdollah K, Dalali N, J. Coord. Chem., 64(5), 743 (2011)
Mokhtari B, Pourabdollah K, J. Electrochem. Soc., 159(3), K61 (2012)
Mokhtari B, Pourabdollah K, Electroanalysis., 24, 219 (2012)
Mokhtari B, Pourabdollah K, Desalination., 292, 1 (2012)
Mokhtari B, Pourabdollah K, J. Chilean Chem. Soc., 58(2), 827 (2012)
Mokhtari B, Pourabdollah K, Drug Chem. Toxicol., DOI: 10.3109/01480545.2011.653490 (2012)
Mokhtari B, Pourabdollah K, Supramol. Chem., 24, 255 (2012)
Mokhtari B, Pourabdollah K, J. Sci. Food Agric., DOI:10.1002/jsfa.5688 (2012)
Mokhtari B, Pourabdollah K, Bull. Korean Chem. Soc., DOI:10.5012/bkcs.2012.33.5.1 (2012)
Mokhtari B, Pourabdollah K, Can. J. Chem., 90, 560 (2012)
Mokhtari B, Pourabdollah K, Synth. React. Inorg. Metal Org. Chem., article in press. DOI:10.1080/15533174.2012.654879 (2012)
Mokhtari B, Pourabdollah K, Electrochim. Acta., 76, 363 (2012)
Mokhtari B, Pourabdollah K, Bull. Korean Chem. Soc., 33, 2320 (2012)
Mokhtari B, Pourabdollah K, J. Incl. Phenom. Macrocycl.Chem., DOI:10.1007/s10847-012-0210-0 (2012)
Mokhtari B, Pourabdollah K, J. Chinese Chem. Soc., DOI:10-1002/jccs.201100737 (2012)
Mokhtari B, Pourabdollah K, J. Liq. Chromatogr. R. T., DOI:10.1080/10826076.2011.643524 (2012)
Mokhtari B, Pourabdollah K, Talanta., 78, 118 (2011)
Teresa M, Reis A, Carvalho JMR, J. Membr. Sci., 84, 201 (1993)
Othman N, Mat H, Goto M, J. Membr. Sci., 282(1-2), 171 (2006)
Bhowal A, Datta S, J. Membr. Sci., 188(1), 1 (2001)
Venkateswaran P, Palanivelu K, Hydrometallurgy., 78, 107 (2005)
Strzelbck J, Charewcz WA, Mackewcz A, Sep. Sci. Technol., 19, 321 (1984)
Thien MP, Hatton TA, Wang DIC, Biotechnol. Bioeng., 35, 853 (1990)
