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Received April 5, 2011
Accepted June 8, 2011
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Competitive adsorption of protocatechuic acid and caffeic acid on C18 particles
Department of Chemical Engineering, Inha University, 253 Yonghyun-dong, Nam-gu, Incheon 402-751, Korea
rowkho@inha.ac.kr
Korean Journal of Chemical Engineering, February 2012, 29(2), 135-138(4), 10.1007/s11814-011-0152-z
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Abstract
Comparisons of protocatechuic acid (PA) and caffeic acid (CA) adsorption isotherm on C18 column and competitive adsorption of the two compounds were investigated. By linear and nonlinear regression analysis, the experimental parameters in the equilibrium isotherms were estimated. Adsorption equilibrium data of the two compounds were investigated using six different models including linear, Langmuir, Freundlich, Langmuir-Freundlich, competitive Langmuir and Quadratic. In the moderate range of concentrations, the competitive Langmuir isotherm proved to_x000D_
be the best model for these experimental data. The regression coefficients of the competitive Langmuir adsorption isotherms were 0.9860 for PA and 0.9898 for CA, respectively. The coefficients obtained for the six isotherm models confirmed the superiority of the competitive Langmuir isotherm for analyzing the competitive adsorption data of solutes.
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