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Received September 28, 2010
Accepted July 6, 2011
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Separation of sinigrin from Indian mustard (Brassica juncea L.) seed using macroporous ion-exchange resin
State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Korean Journal of Chemical Engineering, March 2012, 29(3), 396-403(8), 10.1007/s11814-011-0175-5
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Abstract
Sinigrin is a major glucosinolate present in Indian mustard (Brassica juncea L.) seeds as the precursor of the anticancer compound allyl isothiocyanate. In the present study, the adsorption and desorption characteristics of six macroporous ion-exchange resins for the separation of sinigrin from crude aqueous extracts have been compared. The results indicated that D261 resin showed the best adsorption and desorption capacity to sinigrin, and its adsorption data fit best to the Freundlich isotherm. The dynamic adsorption/desorption experiments were carried out to optimize the separation process. After treatment with D261 resin in one run, the purity of sinigrin in the product was increased 15.57-fold from 3.75% to 58.37% with the recovery of 79.82%. Meanwhile, the separation effect of D261 resin was also supported by UV and IR. The separation process using macroporous ion-exchange resin in our paper provides a novel, rapid and economical method for separation of sinigrin.
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Zagorodni AA, Kotova DL, Selemenev VF, React. Funct. Polym., 53, 157 (2002)
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Wang YF, Gao HZ, Yeredla R, Xu HF, Abrecht M, J. Colloid Interface Sci., 305(2), 209 (2007)
Silva EM, Pompeu DR, Larondelle Y, Rogez H, Sep. Purif. Technol., 53(3), 274 (2007)
Zhang B, Yang RY, Zhao Y, Liu CZ, J. Chromatogr. B., 867, 253 (2008)
Baskaralingam P, Pulikesi M, Elango D, Ramamurthi V, Sivanesan S, J. Hazard. Mater., 128(2-3), 138 (2006)
Jung MW, Ahn KH, Lee YH, Kim KP, Insook RP, Rhee JS, Park JT, Paeng KJ, J. Chromatogr. A., 917, 87 (2001)
Traybal RE, Mass Transfer Operation, Tata McGraw Hill, Singapore (1981)
Kuang PQ, Liang H, Yuan QP, Sep. Sci. Technol., 46(1), 179 (2011)
