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Received June 10, 2011
Accepted September 23, 2011
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Absorption of carbon dioxide into aqueous solution of 2-amino-2-methy-1-propanol and 1, 8-diamino-p-menthane
School of Civil and Environmental Engineering, Pusan National University, Busan 609-735, Korea 1Greenhouse Gas Research Center, Korea Institute of Energy Research, Daejeon 305-343, Korea 2Department of Environmental Administration, Catholic University of Pusan, Busan 609-757, Korea 3School of Chemical and Biomolecular Engineering, Pusan National University, Busan 609-735, Korea
swpark@pusan.ac.kr
Korean Journal of Chemical Engineering, July 2012, 29(7), 946-951(6), 10.1007/s11814-011-0249-4
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Abstract
Carbon dioxide was absorbed into an aqueous solution containing two reactants of 2-amino-2-methyl-1-propanol (AMP) and 1,8-diamino-p-menthane (DAM) in a stirred semi-batch tank with a planar gas-liquid interface within a range of 0-3.0 kmol/m3 of AMP, 0-0.2 kmol/m3 of DAM, and 298.15-323.15 K at 15% of CO2 and 101.3 kPa. Diffusivity, Henry constant and mass transfer coefficient of CO2 in the mixed solution of AMP and DAM were used to calculate the theoretical enhancement factor of CO2, which was obtained by an approximated solution of mass balances_x000D_
with the instantaneous and fast regime in CO2-AMP-DAM system. The method of the classification of the chemical regime in the heterogeneous system was used to determine the enhancement factor by adding DAM under the limited concentration of AMP.
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Mimura T, Suda T, Iwaki I, Honda A, Kumazawa H, Chem. Eng. Commun., 170, 245 (1998)
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Chakravarty T, Phulkan UK, Weiland RH, Chem. Eng. Prog., 81, 32 (1985)
Hagewiesche DP, Ashour SS, Alghawas HA, Sandall OC, Chem. Eng. Sci., 50(7), 1071 (1995)
Sun WC, Yong CB, Li MH, Chem. Eng. Sci., 60(2), 503 (2005)
Samanta A, Bandyopadhyay SS, Chem. Eng. Sci., 64(6), 1185 (2009)
Puxty G, Rowland R, Attalla M, Chem. Eng. Sci., 65(2), 915 (2010)
Paul S, Ghoshal AK, Mandal B, Chem. Eng. Sci., 64(2), 313 (2009)
Seo JB, Jeon SB, Choi WJ, Kim JW, Lee GH, Oh KJ, Korean J. Chem. Eng., 28(1), 170 (2011)
Park SW, Park DW, Oh KJ, Kim SS, Sep. Sci. Technol., 44(3), 543 (2009)
Hwang KS, Kim DW, Park SW, Park DW, Oh KJ, Kim SS, Sep. Sci. Technol., 44(16), 3888 (2009)
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da Silva EF, Svendsen HF, Ind. Eng. Chem. Res., 43(13), 3413 (2004)
Daraiswany LK, Sharma MM, Heterogeneous reaction: Analysis, example and reactor design, John Wiley, New York (1984)
Yu W, Astarita G, Savage DW, Chem. Eng. Sci., 40, 1585 (1985)
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Cussler EL, Diffusion, Cambridge University Press, New York (1984)
Danckwerts PV, Gas-liquid reactions, McGraw-Hill, New York (1970)
Carta G, Pigford RL, Ind. Eng. Chem. Fundam., 22, 329 (1983)