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Received November 18, 2011
Accepted June 18, 2012
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Characterization of modified sawdust, kinetic and equilibrium study about methylene blue adsorption in batch mode
School of Chemical Engineering and Energy, Zhengzhou University, 100# of Kexue Road, Zhengzhou 450001, P. R. China
whzou@zzu.edu.cn
Korean Journal of Chemical Engineering, January 2013, 30(1), 111-122(12), 10.1007/s11814-012-0096-y
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Abstract
Methylene blue (MB) biosorption by citric acid modified pine sawdust (Pinus tabulaeformis) was studied from aqueous solutions. Batch experiments were conducted to determine the biosorption properties of the biomass. The Langmuir isotherm equation could fit the equilibrium data. The maximal equilibrium quantity of MB from Langmuir model was 111.46 mg g^(-1) at 293 K. The Elovich model adequately described the kinetic data in comparison to the pseudo-first-order model and pseudo-second-order model; the process involving rate-controlling step is very complex involving both boundary layer and intra-particle diffusion processes. The effective diffusion parameter Di and Df values were estimated at different initial concentration, and the average values were determined to be 5.76×10^(-8) and 2.12×10^(-7) cm2 s^(-1). Thermodynamic parameters showed that the adsorption of methylene blue onto pine sawdust biomass was feasible, spontaneous and endothermic under studied conditions. The physical and chemical properties of the biosorbent were determined by SEM, TG-DSC, XRD, and the point of zero charge (pHpzc) and the nature of biomass-dye interactions were evaluated by FTIR analysis, which showed the participation of COOH, OH and NH2 groups in the biosorption process. Biosorbents could be regenerated using 0.01 mol L^(-1) HCl solution at least three cycles, with up to 90% recovery. Thus, the biomass used in this work proved to be effective for the treatment of MB bearing aqueous solutions.
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References
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Slokar YM, Majcen Le Marechal A, Dyes Pigm., 37, 335 (1998)
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Ozer D, Dursun G, Ozer A, J. Hazard. Mater., 144(1-2), 171 (2007)
Gupta S, Kumar D, Gaur JP, Chem. Eng. J., 148(2-3), 226 (2009)
Zou WH, Bai HJ, Li K, Shi XL, Adsorp. Sci. Technol., 28, 641 (2010)
Wong KK, Lee CK, Low KS, Haron MJ, Chemosphere., 50, 23 (2003)
Sciban M, Radetic B, Kevresan D, Klasnja M, Bioresour. Technol., 98(2), 402 (2007)
Zhang H, Tang Y, Liu XA, Ke ZG, Su X, Cai DQ, Wang XQ, Liu YD, Huang Q, Yu ZL, Desalination, 274(1-3), 97 (2011)
Vaughan T, Seo CW, Marshall WE, Bioresour. Technol., 78(2), 133 (2001)
Faria PCC, Orfao JJM, Pereira MFR, Water Res., 38, 2043 (2004)
Irbe I, Anderson B, Chirkova J, Kallavus U, Anderson I, Faix O, Int. Biodeterior. Biodegrad., 57, 99 (2005)
Han RP, Zhang LJ, Song C, Zhang MM, Zhu HM, Zhang LJ, Carbohyd. Polym., 79, 1140 (2010)
Tarley CRT, Arruda MAZ, Chemosphere., 54, 987 (2004)
Krishnani KK, Meng XG, Christodoulatos C, Boddu VM, J. Hazard. Mater., 153(3), 1222 (2008)
Wang Z, Cao J, Wang J, J. Anal. Appl. Pyrol., 84, 179 (2009)
Garg VK, Kumar R, Gupta R, Dyes Pigm., 63, 243 (2004)
Senthilkumaar S, Varadarajan PR, Porkodi K, Subbhuraam C, J. Colloid Interface Sci., 284(1), 78 (2005)
Ozcan S, Erdem B, Ozcan A, Colloid Surf. A., 266, 73 (2005)
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Almeida CAP, Debacher NA, Downs AJ, Cottet L, Mello CAD, J. Colloid Interface Sci., 332(1), 46 (2009)
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Langmuir L, J. Am. Chem. Soc., 38, 2221 (1916)
Langmuir L, J. Am. Chem. Soc., 40, 1361 (1918)
Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
Ozcan AS, Erdem B, Ozcan A, J. Colloid Interface Sci., 280(1), 44 (2004)
Redlich O, Peterson DL, J. Phys. Chem., 63, 1024 (1959)
Dubinin MM, Chem. Rev., 60, 235 (1960)
Nibou D, Khemaissia S, Amokrane S, Barkat M, Chegrouche S, Mellah A, Chem. Eng. J., 172(1), 296 (2011)
Low KS, Lee CK, Pertanika., 13, 221 (1990)
Gong RM, Sun YZ, Chen J, Liu HJ, Yang C, Dyes Pigm., 67, 175 (2005)
Rafatullah M, Sulaiman O, Hashim R, Ahmad A, J. Hazard. Mater., 177(1-3), 70 (2010)
Vadivelan V, Kumar KV, J. Colloid Interface Sci., 286(1), 90 (2005)
Lata H, Garg VK, Gupta RK, Dyes Pigm., 74, 653 (2007)
Dogan M, Abak H, Alkan M, Water, Air, Soil Pollut., 192, 141 (2008)
Han RP, Wang YF, Han P, Shi J, Yang J, Lu YS, J. Hazard. Mater., 137(1), 550 (2006)
Annadurai G, Juang RS, Lee DJ, J. Hazard. Mater., 92(3), 263 (2002)
Wang XS, Zhou Y, Jiang Y, Sun C, J. Hazard. Mater., 157(2-3), 374 (2008)
Bhattacharyya KG, Sharma A, Dyes Pigm., 65, 51 (2005)
Batzias FA, Sidiras DK, J. Hazard. Mater., 114(1-3), 167 (2004)
Ho YS, Ng JCY, McKay G, Sep. Purif. Methods, 29(2), 189 (2000)
Ho YS, McKay G, Chem. Eng. J., 70(2), 115 (1998)
Cheung CW, Porter JF, McKay G, Sep. Purif. Technol., 19(1-2), 55 (2000)
Vadivelan V, Kumar KV, J. Colloid Interface Sci., 286(1), 90 (2005)
Srivastava VC, Swamy MM, Mall ID, Prasad B, Mishra IM, Colloids Surf., 272, 89 (2006)
Zou WH, Li K, Bai HJ, Shi XL, Han RP, J. Chem. Eng. Data, 56(5), 1882 (2011)
Boyd GE, Adamson AW, Myers LS, J. Am. Chem. Soc., 69, 2836 (1947)
Singh KK, Rastogi R, Hasan SH, J. Colloid Interface Sci., 290(1), 61 (2005)
