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Received January 12, 2012
Accepted July 9, 2012
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Characterization of Ag(I), Co(II) and Cu(II) removal process from aqueous solutions using dolomite powder
Department of Chemical Engineering, Iran University of Science and Technology, P. O. Box 16765-163, Tehran, Iran 1Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, P. O. Box 14155-1339, Amirabad, Tehran, Iran
aghaemi@iust.ac.ir
Korean Journal of Chemical Engineering, January 2013, 30(1), 172-180(9), 10.1007/s11814-012-0113-1
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Abstract
Dolomite, a natural adsorbent, was used for removal of Ag(I), Cu(II) and Co(II) from aqueous solutions. Adsorption parameters including pH, temperature and contact time have been investigated to obtain adsorption mechanism. The results of experiments showed that adsorption of the metal ions increased by increasing pH values up to 5.5. The adsorption process was initially fast. Equilibrium isotherm data were analyzed using Langmuir, Freundlich and Dubinin-Radushkevich isotherm models. Maximum adsorption capacity of Ag(I), Cu(II) and Co(II) was 1.34, 1.63 and 2.84 mg/g at 20 ℃, respectively. Kinetic models including Lagergren first-order and pseudo-second-order were used to test kinetic data. The results showed that pseudo-second-order has good agreement with experimental data. Thermodynamic parameters of the process were also investigated at different temperatures. The negative values of Gibbs free energy and enthalpy changes for Ag(I), Cu(II) and Co(II) indicated the spontaneous and exothermic nature of the adsorption process.
Keywords
References
Pehlivan E, Ozkan AM, Dinc S, Parlayici S, J. Hazard. Mater., 167(1-3), 1044 (2009)
Imran A, Gupta VK, Nature London., 1, 2661 (2006)
Patel KS, Shrivas K, Hoffmann P, Jakubowski N, Environ.Geochem. Health., 28, 11 (2006)
Kocaoba S, J. Hazard. Mater., 147(1-2), 488 (2007)
Zeng J, Ye H, Hu Z, J. Hazard. Mater., B161, 1491 (2009)
Pehlivan E, Altun T, J. Hazard. Mater., B134, 149 (2006)
Prasad M, Xu HY, Saxena S, J. Hazard. Mater., 154(1-3), 221 (2008)
Pagilla K, Canter LW, J. Environ. Eng., 125, 243 (1999)
Omar H, Arida H, Daifullah A, Appl. Clay Sci., 44, 21 (2009)
Demirba E, Adsorp. Sci. Technol., 21, 951 (2003)
Chiu HSH, Wang JJ, J. Environ. Protection Sci., 3, 102 (2009)
Bhatnagara A, Minocha AK, Sillanpaa M, Biochem. Eng. J., 48, 181 (2010)
Aydlna H, Buluta Y, Yerlikaya C, J. Environ. Manage., 87, 37 (2008)
Ghassabzadeh H, Torab-Mostaedi M, Mohaddespour A, Maragheh MG, Ahmadi SJ, Zaheri P, Desalination, 261(1-2), 73 (2010)
Shen W, Guo Q, Zhang Y, Liu Y, Zheng J, Cheng J, Fan J, Physicochem. Eng. Aspects., 273, 147 (2006)
Babel S, Kurniawan TA, J. Hazard. Mater., B97, 219 (2003)
Imran A, Sep. Pur. Rev., 39, 95 (2010)
Ghassabzadeh H, Mohadespour A, Torab-Mostaedi M, Zaheri P, Maragheh MG, Taheri H, J. Hazard. Mater., 177(1-3), 950 (2010)
Boddu VM, Abburi K, Randolph AJ, Smith ED, Sep. Sci. Technol., 43(6), 1365 (2008)
Papandreou A, Stournaras CJ, Panias D, J. Hazard. Mater., 148(3), 538 (2007)
Gupta VK, J. Environ. Manage., 90, 2313 (2009)
Catalfamo P, Pasquale SD, Primerano P, Mavilia L, Corigliano F, Mater. Eng., 7, 67 (1996)
Colella C, Stud. Surf. Sci. Catal., 125, 641 (1999)
Bailey SE, Olin TJ, Brica RM, Adrin DD, Water Res., 33, 2469 (1999)
Salameh Y, Al-Lagtah N, Ahmad MNM, Allen SJ, Walker GM, Chem. Eng. J., 160(2), 440 (2010)
Chen C, Wang X, Appl. Radiat. Isot., 65, 155 (2007)
Zhao G, Li J, Ren X, Chen C, Wang X, Environ. Sci. Technol., 45, 10454 (2011)
Sheng G, Shitong Y, Sheng J, Hu J, Xiaoli T, Xiangke W, Environ. Sci. Technol., 45, 7718 (2011)
Yang S, Hu J, Chen C, Shao D, Wang X, Environ. Sci. Technol., 45, 3621 (2011)
Adebowale KO, Unuabonah IE, Olu-Owolabi BI, J. Hazard. Mater., B134, 130 (2006)
Sarl A, Tuzen M, Soylak M, J. Hazard. Mater., B144, 41 (2007)
Walker GM, Hanna JA, Allen SJ, Water Res., 39, 2422 (2005)
Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
Langmuir I, J. Am. Chem. Sov., 40, 1361 (1918)
Freundlich HM, Zeitschrift fur Physikalische Chemie (Leipzig)., 57A, 385 (1906)
Dubinin MM, Zaverina ED, Radushkevich LV, Zhurnal Fizicheskoi Khimii., 21, 1351 (1947)
Akgul M, Karabakan A, Acar O, Yurum Y, Micropor. Mesopor. Mater., 94, 99 (2006)
Hanzlik P, Jehlicka J, Weishauptova Z, Sebek O, Plant Soil Environ., 50, 257 (2004)
Karabakan A, Karabulut S, Denizli A, Yurum Y, Adsorpt. Sci.Technol., 22, 135 (2004)
da Fonseca MG, de Oliveira MM, Arakaki LNH, Espinola JGP, Airoldi C, J. Colloid Interface Sci., 285(1), 50 (2005)
Yavuz O, Altunkaynak Y, Guzel F, Water Res., 37, 948 (2003)
Demirbas A, Energy Sources Part A-Recovery Util. Environ. Eff., 29(2), 117 (2007)
Rawat JP, Iraqi SMU, Singh RP, Colloids Surf., A., 117, 183 (1996)
Iyer A, Mody K, Jha B, Mar. Pollut. Bull., 50, 340 (2005)
Van Hullebusch ED, Peerbolte A, Zandvoort MH, Lens PNL, Chemosphere., 58, 493 (2005)
Parab H, Joshi S, Sudersanan M, Shenoy N, Lali A, Sarma U, J. Environ. Sci. Health., A45, 603 (2010)
Vijayaraghavan K, Jegan J, Palanivelu K, Velan M, Sep. Purif. Technol., 44(1), 53 (2005)
Awadalla FT, Pesic B, Hydrometallurgy., 28, 65 (1992)
Ibanez JP, Umetsu Y, Hydrometallurgy., 64, 89 (2002)
Bhatnagar A, Minocha AK, Jeon BH, Park JM, Sep. Sci. Technol., 42(6), 1255 (2007)
Dewangan T, Tiwari A, Bajpai AK, J. Disp. Sci. Technol., 30, 56 (2009)
Bereket G, Aroguz AZ, Ozel MZ, J. Colloid Interface Sci., 187(2), 338 (1997)
Khazali O, Abu-El-Halawa R, Al-Souod K, J. Hazard. Mater., B139, 67 (2007)
Alkan M, Dogan M, J. Colloid Interface Sci., 243(2), 280 (2001)
Sari A, Tuzen M, Citak D, Soylak M, J. Hazard. Mater., 148(1-2), 387 (2007)
Bhattacharyya KG, Sen Gupta S, Ind. Eng. Chem. Res., 45(21), 7232 (2006)
Karabulut S, Karabakan A, Denizli A, Yurum Y, Sep. Purif. Technol., 18(3), 177 (2000)
Nadaroglu H, Kalkan E, Demir N, Desalination., 9, 138 (2009)
Shukla SR, Pai RS, Sep. Purif. Technol., 43(1), 1 (2005)
Choudhury AT, Khanif YM, Commun. Soil Sci. Plant Anal., 31, 567 (2000)
Gould MS, Genetelli EJ, Water Res., 12, 505 (1978)
Bassi R, Prasher SO, Simpson BK, Sep. Sci. Technol., 35(4), 547 (2000)
Chen XH, Gosset T, Thevenot DR, Water Res., 24, 1463 (1990)
Rao CNR, Iyengar L, Venkobachar C, J. Environ. Eng., 119, 369 (1993)
Mustafa S, Haq I, Environ. Technol. Lett., 9, 1386 (1988)
Huang C, Chung YC, Liou MR, J. Hazard. Mater., 45, 265 (1996)
Gupta VK, Ind. Eng. Chem. Res., 37(1), 192 (1998)
Tan SY, Wang YT, Peng CH, Tang YR, J. Appl. Polym. Sci., 71(12), 2069 (1999)
Schmuhl R, Krieg HM, Keizer K, Water SA., 27, 1 (2001)
Yang ZK, Wang YT, Tang YR, J. Appl. Polym. Sci., 75(10), 1255 (2000)
Ni CH, Xu YW, J. Appl. Polym. Sci., 59(3), 499 (1996)
Kondo K, Nakagawa S, Matsumoto M, Yamashita T, Furukawa I, J. Chem. Eng. Jpn., 30(5), 846 (1997)
Juang RS, Wu FC, Tseng RL, Water Res., 33, 2403 (1999)
Kondo K, Matsumoto M, Okamoto K, J. Chem. Eng. Jpn., 32(2), 217 (1999)
Tan TW, He XJ, Du WX, J. Chem. Technol. Biotechnol., 76(2), 191 (2001)
Wan Ngah WS, Kamari A, Koav YJ, Int. J. Biol. Macromol., 34, 155 (2004)
Debnath S, Ghosh UC, Desalination, 273(2-3), 330 (2011)
Sheng GD, Li JX, Shao DD, Hu J, Chen CL, Chen YX, Wang XK, J. Hazard. Mater., 178(1-3), 333 (2010)
Hasan S, Krishnaiah A, Ghosh TK, Viswanath DS, Boddu VM, Smith ED, Ind. Eng. Chem. Res., 45(14), 5066 (2006)
Imran A, Gupta VK, Nature London., 1, 2661 (2006)
Patel KS, Shrivas K, Hoffmann P, Jakubowski N, Environ.Geochem. Health., 28, 11 (2006)
Kocaoba S, J. Hazard. Mater., 147(1-2), 488 (2007)
Zeng J, Ye H, Hu Z, J. Hazard. Mater., B161, 1491 (2009)
Pehlivan E, Altun T, J. Hazard. Mater., B134, 149 (2006)
Prasad M, Xu HY, Saxena S, J. Hazard. Mater., 154(1-3), 221 (2008)
Pagilla K, Canter LW, J. Environ. Eng., 125, 243 (1999)
Omar H, Arida H, Daifullah A, Appl. Clay Sci., 44, 21 (2009)
Demirba E, Adsorp. Sci. Technol., 21, 951 (2003)
Chiu HSH, Wang JJ, J. Environ. Protection Sci., 3, 102 (2009)
Bhatnagara A, Minocha AK, Sillanpaa M, Biochem. Eng. J., 48, 181 (2010)
Aydlna H, Buluta Y, Yerlikaya C, J. Environ. Manage., 87, 37 (2008)
Ghassabzadeh H, Torab-Mostaedi M, Mohaddespour A, Maragheh MG, Ahmadi SJ, Zaheri P, Desalination, 261(1-2), 73 (2010)
Shen W, Guo Q, Zhang Y, Liu Y, Zheng J, Cheng J, Fan J, Physicochem. Eng. Aspects., 273, 147 (2006)
Babel S, Kurniawan TA, J. Hazard. Mater., B97, 219 (2003)
Imran A, Sep. Pur. Rev., 39, 95 (2010)
Ghassabzadeh H, Mohadespour A, Torab-Mostaedi M, Zaheri P, Maragheh MG, Taheri H, J. Hazard. Mater., 177(1-3), 950 (2010)
Boddu VM, Abburi K, Randolph AJ, Smith ED, Sep. Sci. Technol., 43(6), 1365 (2008)
Papandreou A, Stournaras CJ, Panias D, J. Hazard. Mater., 148(3), 538 (2007)
Gupta VK, J. Environ. Manage., 90, 2313 (2009)
Catalfamo P, Pasquale SD, Primerano P, Mavilia L, Corigliano F, Mater. Eng., 7, 67 (1996)
Colella C, Stud. Surf. Sci. Catal., 125, 641 (1999)
Bailey SE, Olin TJ, Brica RM, Adrin DD, Water Res., 33, 2469 (1999)
Salameh Y, Al-Lagtah N, Ahmad MNM, Allen SJ, Walker GM, Chem. Eng. J., 160(2), 440 (2010)
Chen C, Wang X, Appl. Radiat. Isot., 65, 155 (2007)
Zhao G, Li J, Ren X, Chen C, Wang X, Environ. Sci. Technol., 45, 10454 (2011)
Sheng G, Shitong Y, Sheng J, Hu J, Xiaoli T, Xiangke W, Environ. Sci. Technol., 45, 7718 (2011)
Yang S, Hu J, Chen C, Shao D, Wang X, Environ. Sci. Technol., 45, 3621 (2011)
Adebowale KO, Unuabonah IE, Olu-Owolabi BI, J. Hazard. Mater., B134, 130 (2006)
Sarl A, Tuzen M, Soylak M, J. Hazard. Mater., B144, 41 (2007)
Walker GM, Hanna JA, Allen SJ, Water Res., 39, 2422 (2005)
Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
Langmuir I, J. Am. Chem. Sov., 40, 1361 (1918)
Freundlich HM, Zeitschrift fur Physikalische Chemie (Leipzig)., 57A, 385 (1906)
Dubinin MM, Zaverina ED, Radushkevich LV, Zhurnal Fizicheskoi Khimii., 21, 1351 (1947)
Akgul M, Karabakan A, Acar O, Yurum Y, Micropor. Mesopor. Mater., 94, 99 (2006)
Hanzlik P, Jehlicka J, Weishauptova Z, Sebek O, Plant Soil Environ., 50, 257 (2004)
Karabakan A, Karabulut S, Denizli A, Yurum Y, Adsorpt. Sci.Technol., 22, 135 (2004)
da Fonseca MG, de Oliveira MM, Arakaki LNH, Espinola JGP, Airoldi C, J. Colloid Interface Sci., 285(1), 50 (2005)
Yavuz O, Altunkaynak Y, Guzel F, Water Res., 37, 948 (2003)
Demirbas A, Energy Sources Part A-Recovery Util. Environ. Eff., 29(2), 117 (2007)
Rawat JP, Iraqi SMU, Singh RP, Colloids Surf., A., 117, 183 (1996)
Iyer A, Mody K, Jha B, Mar. Pollut. Bull., 50, 340 (2005)
Van Hullebusch ED, Peerbolte A, Zandvoort MH, Lens PNL, Chemosphere., 58, 493 (2005)
Parab H, Joshi S, Sudersanan M, Shenoy N, Lali A, Sarma U, J. Environ. Sci. Health., A45, 603 (2010)
Vijayaraghavan K, Jegan J, Palanivelu K, Velan M, Sep. Purif. Technol., 44(1), 53 (2005)
Awadalla FT, Pesic B, Hydrometallurgy., 28, 65 (1992)
Ibanez JP, Umetsu Y, Hydrometallurgy., 64, 89 (2002)
Bhatnagar A, Minocha AK, Jeon BH, Park JM, Sep. Sci. Technol., 42(6), 1255 (2007)
Dewangan T, Tiwari A, Bajpai AK, J. Disp. Sci. Technol., 30, 56 (2009)
Bereket G, Aroguz AZ, Ozel MZ, J. Colloid Interface Sci., 187(2), 338 (1997)
Khazali O, Abu-El-Halawa R, Al-Souod K, J. Hazard. Mater., B139, 67 (2007)
Alkan M, Dogan M, J. Colloid Interface Sci., 243(2), 280 (2001)
Sari A, Tuzen M, Citak D, Soylak M, J. Hazard. Mater., 148(1-2), 387 (2007)
Bhattacharyya KG, Sen Gupta S, Ind. Eng. Chem. Res., 45(21), 7232 (2006)
Karabulut S, Karabakan A, Denizli A, Yurum Y, Sep. Purif. Technol., 18(3), 177 (2000)
Nadaroglu H, Kalkan E, Demir N, Desalination., 9, 138 (2009)
Shukla SR, Pai RS, Sep. Purif. Technol., 43(1), 1 (2005)
Choudhury AT, Khanif YM, Commun. Soil Sci. Plant Anal., 31, 567 (2000)
Gould MS, Genetelli EJ, Water Res., 12, 505 (1978)
Bassi R, Prasher SO, Simpson BK, Sep. Sci. Technol., 35(4), 547 (2000)
Chen XH, Gosset T, Thevenot DR, Water Res., 24, 1463 (1990)
Rao CNR, Iyengar L, Venkobachar C, J. Environ. Eng., 119, 369 (1993)
Mustafa S, Haq I, Environ. Technol. Lett., 9, 1386 (1988)
Huang C, Chung YC, Liou MR, J. Hazard. Mater., 45, 265 (1996)
Gupta VK, Ind. Eng. Chem. Res., 37(1), 192 (1998)
Tan SY, Wang YT, Peng CH, Tang YR, J. Appl. Polym. Sci., 71(12), 2069 (1999)
Schmuhl R, Krieg HM, Keizer K, Water SA., 27, 1 (2001)
Yang ZK, Wang YT, Tang YR, J. Appl. Polym. Sci., 75(10), 1255 (2000)
Ni CH, Xu YW, J. Appl. Polym. Sci., 59(3), 499 (1996)
Kondo K, Nakagawa S, Matsumoto M, Yamashita T, Furukawa I, J. Chem. Eng. Jpn., 30(5), 846 (1997)
Juang RS, Wu FC, Tseng RL, Water Res., 33, 2403 (1999)
Kondo K, Matsumoto M, Okamoto K, J. Chem. Eng. Jpn., 32(2), 217 (1999)
Tan TW, He XJ, Du WX, J. Chem. Technol. Biotechnol., 76(2), 191 (2001)
Wan Ngah WS, Kamari A, Koav YJ, Int. J. Biol. Macromol., 34, 155 (2004)
Debnath S, Ghosh UC, Desalination, 273(2-3), 330 (2011)
Sheng GD, Li JX, Shao DD, Hu J, Chen CL, Chen YX, Wang XK, J. Hazard. Mater., 178(1-3), 333 (2010)
Hasan S, Krishnaiah A, Ghosh TK, Viswanath DS, Boddu VM, Smith ED, Ind. Eng. Chem. Res., 45(14), 5066 (2006)
