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Received April 13, 2013
Accepted September 10, 2013
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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A facile approach to preparing palladium nanoparticles-embedded polyvinylpyrrolidone (PVP) heterogeneous hybrid nanofibers mats by electrospinning
Chemical Engineering College, Inner Mongolia University of Technology, Huhhote 010051, P. R. China
baijie@imut.edu.cn
Korean Journal of Chemical Engineering, December 2013, 30(12), 2142-2150(9), 10.1007/s11814-013-0173-x
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Abstract
Well-dispersed palladium nanoparticles (Pd NPs) were prepared under the condition that trisodium citrate was the reduction agent and polyvinylpyrrolidone (PVP) was the stabilizing agent via sol-gel process. By making good use of the advanced electrospinning technology we obtained Pd NPs/PVP composite nanofibers films. Optical properties were examined by UV-visible absorbance spectra (UV-vis) and Fourier transform infrared spectroscopy (FTIR). The_x000D_
morphology and distribution of Pd NPs in/on PVP matrix were characterized by scanning electron microscope (SEM) and transmission electron microscope (TEM). The results showed that Pd NPs presented as spherical spots and distributed in/on PVP nanofibers uniformly; their diameter was 4-10 nm and decreased with the increase of PVP. The as-prepared Pd NPs/PVP hybrid mats possess catalytic activity, stability and reusability, as verified by performance in Heck reaction.
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Maiyalagan T, Scott K, J. Power Sources, 195(16), 5246 (2010)
Mayer ABR, Mark JE, Hausner SH, J. Appl. Polym. Sci., 70(6), 1209 (1998)
Lim JS, Kim SM, Lee SY, Stach EA, Culver JN, Harris MT, Nano Lett., 10, 3863 (2010)
Metin O, Sxahin S, Ozkar S, Int. J. Hydrog. Energy., 34, 6304 (2009)
Gentsch R, Pippig F, Schmidt S, Cernoch P, Polleux J, Borner HG, Macromolecules, 44(3), 453 (2011)
Bai J, Yang Q, Wang S, Li Y, Korean J. Chem. Eng., 28(8), 1761 (2011)
Wang YZ, Li YX, Sun G, Zhang GL, Liu H, Du JS, Yang SA, Bai J, Yang QB, J. Appl. Polym. Sci., 105(6), 3618 (2007)
Giller C, Gururajan G, Wei J, Zhang W, Hwang W, Chase DB, Rabolt JF, Sita LR, Macromolecules, 44(3), 471 (2011)
Zhang ZT, Zhao B, Hu L, J. Solid State Chem., 121, 105 (1996)
Toebes ML, Nijhuis TA, Hajek J, Bitter JH, van Dillen AJ, Murzin DY, de Jong KP, Chem. Eng. Sci., 60(21), 5682 (2005)
Morales-Torres S, Perez-Cadenas AF, Kapteijn F, Carrasco-Marin F, Maldonado-Hodar FJ, Moulijn JA, Appl. Catal. B: Environ., 89(3-4), 411 (2009)
Zhu J, Zhao TJ, Kvande I, Chen D, Zhou XG, Yuan WK, Chin. J. Catal., 29, 1145 (2008)
Xian JY, Hua Q, Jiang ZQ, Ma YS, Huang WX, Langmuir, 28(17), 6736 (2012)
Demir MM, Gulgun MA, Menceloglu YZ, Erman B, Abramchuk SS, Makhaeva EE, Khokhlov AR, Matveeva VG, Sulman MG, Macromolecules, 37(5), 1787 (2004)
Valmikanathan OP, Stroverkhova O, Mulla IS, Vijayamohanan K, Atre SV, Polymer, 49(16), 3413 (2008)
Francis L, Giunco F, Balakrishnan A, Marsano E, Curr. Appl. Phys., 10(4), 1005 (2010)
