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Received September 28, 2011
Accepted September 22, 2012
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This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
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Removal of oil from biodiesel wastewater by electrocoagulation method
Faculty of Chemical Engineering, Tarbiat Modares University, Tehran, Iran 1Department of Engineering, Shahrood Branch, Islamic Azad University, Shahrood, Iran
Korean Journal of Chemical Engineering, March 2013, 30(3), 634-641(8), 10.1007/s11814-012-0162-5
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Abstract
An attempt has been made to remove oil and grease (O&G) from biodiesel wastewater as well as O&G and turbidity in the presence of H2O2 and polyaluminum chloride (PAC), as a coagulant-aid by an electrochemical method using iron as sacrificial electrodes. The effects of current density, amount of hydrogen peroxide using as an oxidizing agent and addition of coagulant-aid, on percent removal and energy consumption have been investigated. The removal efficiency of O&G was in the range of 62-86%, whereas O&G removal was 100% in the current density range of 10-_x000D_
12.5 mAcm^(-2) depending on the concentrations of H2O2 and coagulant aid. It is obtained that electrocoagulation in the absence of coagulant aid and oxidant is not too efficient for the treatment of this type of wastewater.
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Alinezhad K, Hosseini M, Movagarnejad K, Salehi M, Korean J. Chem. Eng., 27(1), 198 (2010)
Aydogan S, Kusefoglu S, Akman U, Hortacsu O, Korean J. Chem. Eng., 23(5), 704 (2006)
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Hong A, Fane AG, Burford R, J. Membr. Sci., 222(1-2), 19 (2003)
Chen WJ, Peng JM, Su YL, Zheng LL, Wang LJ, Jiang ZY, Sep. Purif. Technol., 66(3), 591 (2009)
Elmaleh S, Ghaffor N, J. Membr. Sci., 118(1), 111 (1996)
Nicolaisen B, Desalination., 153, 355 (2002)
Hilal N, Al-Zoubi H, Darwish NA, Mohammad AW, Abu Arabi M, Desalination, 170(3), 281 (2004)
Durham B, Bourbigot MM, Pankratz T, Desalination, 138(1-3), 83 (2001)
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Stringfellow WT, Alvarez-Cohen L, Water Res., 33(11), 2535 (1999)
Tellez GT, Nirmalakhandan N, Gardea-Torresdey JL, Adv.Environ. Res., 6, 455 (2002)
Kargi F, Dincer AR, Enzyme Microb. Technol., 19(7), 529 (1996)
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Kobya M, Can OT, Bayramoglu M, J. Hazard. Mater., 100(1-3), 163 (2003)
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Katal R, Pahlavanzadeh H, Desalination, 265(1-3), 199 (2011)
Pouet MF, Grasmick A, Water Sci. Technol., 31, 275 (1995)
Lin SH, Lin CS, Desalination, 120(3), 185 (1998)
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Adhoum N, Monser L, Chem. Eng. Process., 43(10), 1281 (2004)
Inan H, Dimoglo A, Simsek H, Karpuzcu A, Sep. Purif. Technol., 36(1), 23 (2004)
Chen XM, Chen GH, Yue PL, Sep. Purif. Technol., 19(1-2), 65 (2000)
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Xu LJ, Sheldon BW, Larick DK, Carawan RE, Poultry Sci., 81, 785 (2002)
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Canizares P, Carmona M, Lobato J, Martinez F, Rodrigo MA, Ind. Eng. Chem. Res., 44(12), 4178 (2005)
Adhoum N, Monser L, Chem. Eng. Process., 43(10), 1281 (2004)
Kobya M, Can OT, Bayramoglu M, J. Hazard. Mater., 100(1-3), 163 (2003)
Can OT, Kobya M, Demirbas E, andBayramoglu M, Chemosphere., 62, 181 (2006)
Kobya M, Delipinar S, J. Hazard. Mater., 154(1-3), 1133 (2008)
Do JS, Chen ML, J. Appl. Electrochem., 24(8), 785 (1994)
Kobya M, Senturk E, Bayramoglu M, J. Hazard. Mater., 133(1-3), 172 (2006)
Guo ZR, Zhang G, Fang J, Dou X, J. Clean. Prod., 14, 75 (2006)
Sengil IA, Ozacar M, J. Hazard. Mater., 137(2), 1197 (2006)
Chen GH, Sep. Purif. Technol., 38(1), 11 (2004)
Kyriacou A, Lasaridi KE, Kotsou M, Balis C, Pilidis G, Process Biochem., 40(3-4), 1401 (2005)
Un UT, Ugur S, Koparal AS, Ogutveren UB, Sep. Purif. Technol., 52(1), 136 (2006)
Dentel SK, Gossett JM, J. Am. Wat. Wks. Assoc., 80, 187 (1988)
Ching HW, Tanaka TS, Elimelech M, Water Res., 28(3), 559 (1994)
Randatke SJ, J. Am. Wat. Wks. Assoc., 80(5), 40 (1988)
Licsko I, Water Sci. Technol., 27, 245 (1993)
Stumm W, Morgan JJ, J. Am. Wat. Wks. Assoc., 54, 971 (1962)
Jekel MR, Water Res., 20, 1535 (1986)
Oturan MA, Peiroten J, Chartrin P, Acher AJ, Environ. Sci.Technol., 34, 3474 (2000)
Brillas E, Bastida RM, Llosa E, Casado J, J. Electrochem. Soc., 142(6), 1733 (1995)
Guivarch E, Trevin S, Lahitte C, Oturan MA, Environ. Chem.Lett., 1, 38 (2003)
