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Received December 3, 2012
Accepted February 11, 2013
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Kinetics of transesterification of methyl acetate and n-octanol catalyzed by cation exchange resins
Institute of Fine Chemistry and Engineering, College of Chemistry and Chemical Engineering, Henan University, Jinming Avenue, Kaifeng, Henan 475004, China 1College of Food Science and Technology, Henan University of Technology, Lianhua Street, Zhengzhou, Henan 450001, China
Korean Journal of Chemical Engineering, May 2013, 30(5), 1039-1042(4), 10.1007/s11814-013-0023-x
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Abstract
The transesterification kinetics of methyl acetate with n-octanol to octyl acetate and methanol were studied using Amberlyst 15 as catalyst in a batch stirred reactor. The influence of the agitation speed, particle size, temperature, catalyst loading, and initial reactants molar ratio was investigated in detail. A pseudo-homogeneous (PH) kinetic model was applied to correlate the experimental data in the temperature range of 313.15 K to 328.15 K. The estimated kinetic_x000D_
parameters made the calculated results in good agreement with the experimental data. A kinetic model describing the transesterification reaction catalyzed by cation exchange resins was developed.
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Liu Y, Zhou Z, Yang GD, Wu YT, Zhang ZB, Ind. Eng. Chem. Res., 49(7), 3170 (2010)
Yang GD, Liu Y, Zhou Z, Zhang ZB, Chem. Eng. J., 168(1), 351 (2011)
Kolah AK, Asthana NS, Vu DT, Lira CT, Miller DJ, Ind. Eng. Chem. Res., 46(10), 3180 (2007)
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