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Received August 30, 2012
Accepted February 12, 2013
- This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Separative capability of γ-Al2O3 porous ceramic membrane modified by ZIF-8
Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province, China West Normal University, Nanchong, Sichuan 637009, P. R. China
Korean Journal of Chemical Engineering, May 2013, 30(5), 1119-1124(6), 10.1007/s11814-013-0026-7
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Abstract
Several precursors such as zinc nitrite, zinc chloride, zinc acetate and zinc sulfate were used to synthesize ZIF-8. These zeolitic imidazolate frameworks synthesized from different zinc precursors under different reaction conditions were characterized by XRD, SEM and FTIR. The synthesis of ZIF-8 was not sensitive to zinc precursor and reaction parameter. Subsequently, we used ZIF-8 to modify the γ-Al2O3 porous ceramic membrane, expecting improvement of separation performance in the γ-Al2O3 porous ceramic membrane. The experimental results indicated that the permselectivity of hydrogen/nitrogen was enhanced in the γ-Al2O3 porous ceramic membrane modified with ZIF-8, although the gas permeance through the modified membrane slightly decreased. In addition, the modified γ-Al2O3 porous ceramic membrane was used to separate the binary systems containing ethanol-water and acrylic acid-water. The separation factor of ethanol to water is 3.1, while it is 2.6 as for acrylic acid-water. Furthermore, the permeance in the former is about five times than that of the latter.
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References
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Pan Y, Lai Z, Chem. Commun., 47(37), 10275 (2011)
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Wang F, Liu ZS, Yang H, Tan YX, Zhang J, Angew. Chem.Int. Ed., 50(2), 450 (2011)
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Kiss G, Chem. Rev., 101(11), 3435 (2001)
Yu DH, Sun P, Tang ZC, Li ZX, Huang H, Can. J. Chem. Eng., 89(3), 484 (2011)
Yan J, Yu D, Sun P, Huang H, Chinese J. Catal., 32(3-4), 405 (2011)
Zhang J, Zhao Y, Pan M, Feng X, Ji W, Au CT, ACS Catal., 1(1), 32 (2010)
Sun P, Yu DH, Tang ZC, Li H, Huang H, Ind. Eng. Chem. Res., 49(19), 9082 (2010)
Sun P, Yu DH, Fu KM, Gu MY, Wang Y, Huang H, Ying HH, Catal. Commun., 10(9), 1345 (2009)
Tang CM, Li XL, Wang GY, Korean J. Chem. Eng., 29(12), 1700 (2012)
Pan Y, Liu Y, Zeng G, Zhao L, Lai Z, Chem. Commun., 47(7), 2071 (2011)
Manjumol KA, Shajesh P, Baiju KV, Warrier KGK, J. Membr. Sci., 375(1-2), 134 (2011)
Mohammad-Rahimi R, Rezaie HR, Nemati A, Ceram. Int., 37(5), 1681 (2011)
Venna SR, Carreon MA, J. Am. Chem. Soc., 132(1), 76 (2010)
Li XL, Liang B, J. Taiwan Inst. Chem. E., 43, 339 (2012)
Assabumrungrat S, White DA, Chem. Eng. Sci., 53(7), 1367 (1998)
Assabumrungrat S, White DA, Chem. Eng. Sci., 51(24), 5241 (1996)
Wu JC, Yang WS, Lin LW, Petrochem. Technol., 22(11), 735 (1993)
Bux H, Feldhoff A, Cravillon J, Wiebcke M, Li YS, Caro J, Chem. Mater., 23(8), 2262 (2011)
Sekulic J, Luiten MWJ, ten Elshof JE, Benes NE, Keizer K, Desalination, 148(1-3), 19 (2002)