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Received December 5, 2012
Accepted February 3, 2013
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Density, ultrasonic velocity, viscosity and their excess parameters of the binary mixtures of N,N-dimethylaniline+1-alkanols (C3-C5), +2-alkanols (C3-C4), +2-methyl-1-propanol, +2-methyl-2-propanol at 303.15K
Department of Chemistry, J.K.C. College, Guntur 522006, India 1Department of Chemistry, S.V. University, Tirupathi 517502, India 2Department of Chemistry, S.V. Arts (U.G. & P.G) College (T.T.D’S), Tirupathi 517502, India 3Research Supervisor in Chemistry, Acharya Nagarjuna University, Guntur, India
sivakumarkasi64@gmail.com
Korean Journal of Chemical Engineering, May 2013, 30(5), 1131-1141(11), 10.1007/s11814-013-0014-y
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Abstract
The density, ultrasonic velocity of sound and viscosity of binary mixtures of N,N-dimethyl aniline (N,NDMA) with 1-propanol, +2-propanol, +1-butanol, +2-butanol, +1-pentanol, +2-methyl-1-propanol, +2-methyl-2-propanol were measured at 303.15 K. These experimental data have been used to calculate excess volume VE, excess ultrasonic speeds uE, excess intermolecular free length LfE, excess acoustic impedance ZE, excess isentropic compressibility κsE, deviation in viscosity Δη and excess Gibbs free energy of activation of viscous flow (G*E). The values of Lf_x000D_
Eand κsE are negative over the wide range of composition for all the binary mixtures, while the values of ZE are positive. These results have been used to discuss the nature of interaction between unlike molecules in terms of hydrogen bonding, dipole-dipole interaction, proton-acceptor interaction and dispersive forces. The viscosity data have been correlated using three equations: Grunberg and Nissan, Katti & Chaudhri and Hind et al. The excess/deviations were fitted by a Redlich-Kister equation and the results were analyzed in terms of specific interactions present in these mixtures.
References
Gowrisankar M, Rambabu K, Venkateswarlu P, Raman GK, Phys. Chem. Liq., 28, 29 (1994)
Gowrisankar M, Sivarambabu S, Venkateswarlu P, Siva Kumar K, Bull. Korean Chem. Soc., 33, 1686 (2012)
Gowrisankar M, Venkateswarlu P, Siva Kumar K, Sivarambabu S, J. Mol. Liq., 173, 172 (2012)
Gowrisankar M, Venkateswarlu P, Siva Kumar K, Sivarambabu S, J. Soln. Chem., In press (2012)
Das JK, Dash SK, Swain N, Swain BB, J. Mol. Liq., 81, 163 (1999)
Roy MN, Sinha A, Sinha B, J. Soln.Chem., 34, 1311 (2005)
Nikam PS, Shirsat LN, Hasan M, J. Chem. Eng. Data, 43(5), 732 (1998)
Lomte SB, Bawa MJ, Lande MK, Arbad BR, J. Chem. Eng. Data, 54(1), 127 (2009)
Weng WL, J. Chem. Eng. Data, 44(1), 63 (1999)
Vadamalar R, Mani D, Balakrishnan R, Research J. Chem.Sci., 19, 79 (2011)
Parveen S, Singh S, Shukla D, Singh KP, Gupta M, Shukla JP, Acta Phy., Polo., 116, 1011 (2009)
Nain AK, Fluid Phase Equilib., 259(2), 218 (2007)
Redlich O, Kister AT, Ind. Eng. Chem., 40, 345 (1948)
Palepu R, Joan O, Campell D, J. Chem. Eng. Data., 30, 355 (1985)
Riddick JA, Bunger WB, Sakano TK, Organic solvents Physical properties and method of purifications, Wiley Interscience, New York, 2 (1986)
Riggio R, Martinez HE, De Salas NZ, Can. J. Chem., 70, 2859 (1992)
Krishnaiah A, Surendranath KN, J. Chem. Eng. Data, 41(5), 1012 (1996)
Jacobson B, J. Chem. Phys., 20, 927 (1952)
Grunberg L, Nissan AH, Mixture Law for Viscosity, Nature., 164, 799 (1949)
Katti PK, Chaudhri MH, J. Chem. Eng. Data., 9, 442 (1964)
Hind RK, McLaughlin E, A. R. Ubbelohde Trans Faraday Soc., 56, 328 (1960)
Ramanujappa T, Bhavani JA, Raja Gopal E, Manohara Murthi N, Indian J. Pure Appl. Phys., 38, 301 (2000)
Reddy Y, Naidu PS, Ravindra Prasad K, Indian J. Pure Appl.Phys., 32, 958 (1994)
Sri Devi U, Samatha K, Visvanantasarma A, J. Pure Appl.Ultrasonics., 26, 1 (2004)
Fort RJ, Moore WR, Trans Faraday Soc., 61, 2102 (1965)
Nikam PS, Kapade VM, Mehdimhasan, Indian J. Pure Appl.Ultrasonics., 7, 16 (2000)
Ranjith Kumar B, Sathyanarayana B, Indian J. Pure Appl. Phys., 47, 511 (2009)
Ranjith Kumar B, Sathyanarayana B, Indian J. Pure Appl. Phys., 47A, 1026 (2008)
Anil Kumar N, International J. Thermophy., 28, 1228 (2007)
Nath J, Srivastava AK, Fluid Phase Equilib., 28, 97 (1986)
Illoekhani H, Reddy KD, Rao MVP, Phys. Chem. Liq., 14, 181 (1985)
Fort RJ, Moore WR, Trans Faraday Soc., 62, 1112 (1966)
Gonzalez B, Dominguez A, Tojo J, J. Chem. Eng. Data, 49(6), 1590 (2004)
Reed TM, Taylor TE, J. Phys. Chem., 63, 58 (1959)
Ali A, Nain AK, Ind. J. Phys., 74B, 63 (2000)
Kalra KC, Singh KC, Spah DC, J. Ind. Chem. Soc., 69, 138 (1992)
Gowrisankar M, Sivarambabu S, Venkateswarlu P, Siva Kumar K, Bull. Korean Chem. Soc., 33, 1686 (2012)
Gowrisankar M, Venkateswarlu P, Siva Kumar K, Sivarambabu S, J. Mol. Liq., 173, 172 (2012)
Gowrisankar M, Venkateswarlu P, Siva Kumar K, Sivarambabu S, J. Soln. Chem., In press (2012)
Das JK, Dash SK, Swain N, Swain BB, J. Mol. Liq., 81, 163 (1999)
Roy MN, Sinha A, Sinha B, J. Soln.Chem., 34, 1311 (2005)
Nikam PS, Shirsat LN, Hasan M, J. Chem. Eng. Data, 43(5), 732 (1998)
Lomte SB, Bawa MJ, Lande MK, Arbad BR, J. Chem. Eng. Data, 54(1), 127 (2009)
Weng WL, J. Chem. Eng. Data, 44(1), 63 (1999)
Vadamalar R, Mani D, Balakrishnan R, Research J. Chem.Sci., 19, 79 (2011)
Parveen S, Singh S, Shukla D, Singh KP, Gupta M, Shukla JP, Acta Phy., Polo., 116, 1011 (2009)
Nain AK, Fluid Phase Equilib., 259(2), 218 (2007)
Redlich O, Kister AT, Ind. Eng. Chem., 40, 345 (1948)
Palepu R, Joan O, Campell D, J. Chem. Eng. Data., 30, 355 (1985)
Riddick JA, Bunger WB, Sakano TK, Organic solvents Physical properties and method of purifications, Wiley Interscience, New York, 2 (1986)
Riggio R, Martinez HE, De Salas NZ, Can. J. Chem., 70, 2859 (1992)
Krishnaiah A, Surendranath KN, J. Chem. Eng. Data, 41(5), 1012 (1996)
Jacobson B, J. Chem. Phys., 20, 927 (1952)
Grunberg L, Nissan AH, Mixture Law for Viscosity, Nature., 164, 799 (1949)
Katti PK, Chaudhri MH, J. Chem. Eng. Data., 9, 442 (1964)
Hind RK, McLaughlin E, A. R. Ubbelohde Trans Faraday Soc., 56, 328 (1960)
Ramanujappa T, Bhavani JA, Raja Gopal E, Manohara Murthi N, Indian J. Pure Appl. Phys., 38, 301 (2000)
Reddy Y, Naidu PS, Ravindra Prasad K, Indian J. Pure Appl.Phys., 32, 958 (1994)
Sri Devi U, Samatha K, Visvanantasarma A, J. Pure Appl.Ultrasonics., 26, 1 (2004)
Fort RJ, Moore WR, Trans Faraday Soc., 61, 2102 (1965)
Nikam PS, Kapade VM, Mehdimhasan, Indian J. Pure Appl.Ultrasonics., 7, 16 (2000)
Ranjith Kumar B, Sathyanarayana B, Indian J. Pure Appl. Phys., 47, 511 (2009)
Ranjith Kumar B, Sathyanarayana B, Indian J. Pure Appl. Phys., 47A, 1026 (2008)
Anil Kumar N, International J. Thermophy., 28, 1228 (2007)
Nath J, Srivastava AK, Fluid Phase Equilib., 28, 97 (1986)
Illoekhani H, Reddy KD, Rao MVP, Phys. Chem. Liq., 14, 181 (1985)
Fort RJ, Moore WR, Trans Faraday Soc., 62, 1112 (1966)
Gonzalez B, Dominguez A, Tojo J, J. Chem. Eng. Data, 49(6), 1590 (2004)
Reed TM, Taylor TE, J. Phys. Chem., 63, 58 (1959)
Ali A, Nain AK, Ind. J. Phys., 74B, 63 (2000)
Kalra KC, Singh KC, Spah DC, J. Ind. Chem. Soc., 69, 138 (1992)
