Articles & Issues
- Language
- English
- Conflict of Interest
- In relation to this article, we declare that there is no conflict of interest.
- Publication history
-
Received January 4, 2013
Accepted February 6, 2013
-
This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits
unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
Copyright © KIChE. All rights reserved.
All issues
Polymerization of vinyl pivalate in supercritical carbon dioxide and the saponification for the preparation of syndiotacticity-rich poly(vinyl alcohol)
1School of Chemical Engineering, Yeungnam University, 214-1, Dae-dong, Gyeongbuk 712-749, Korea 2Department of Chemistry, Nha Trang University, 2 Nguyen Dinh Chieu, Nha Trang, Vietnam
Korean Journal of Chemical Engineering, May 2013, 30(5), 1153-1161(9), 10.1007/s11814-013-0019-6
Download PDF
Abstract
This paper reports a successful free-radical dispersion polymerization of vinyl pivalate in supercritical carbon dioxide using poly(1H,1H-dihydroperfluorooctyl acrylate) and dimethylsiloxane-g-pyrrolidone carboxylic acid (Monasil PCA) as stabilizers. In both cases, no spherical polymer particles were obtained, which might be due to the high solubility of poly(vinyl pivalate) (PVPi) in supercritical carbon dioxide. The effects of the reaction time, pressure, temperature, monomer loading, stabilizer concentration and initiator concentration on the polymer yield and molecular weight of PVPi were also investigated. In addition, the formation of poly(vinyl alcohol) via saponification of the resulting PVPi is described.
Keywords
References
Fukunishi Y, Akiyama A, Sato T, Sano H, Ohmory A, US Patent, 5,238,995 (1993)
Marten FL, Mark HF, Bikales NM, Meges CG, Kroschwitz JI, Eds., Encyclopedia of polymer science and engineering, Wiley, New York (1985)
Masuda M, in Polyvinyl alcohol developments, Finch CA, Eds., Wiley, New York (1991)
Bikales NM, in Encyclopedia of polymer science and technology, Mark HF, Gaylord NG, Eds., Wiley, New York (1971)
Wu TC, West JC, US Patent, 4,463,138 (1984)
Lyoo WS, Kim BC, Lee CJ, Ha WS, Eur. Polym. J., 33, 785 (1997)
Kamachi M, Tohei Y, Sato T, Fukunishi Y, US Patent, 5,187,226 (1993)
Lyoo WS, Blackwell J, Ghim HD, Macromolecules, 31(13), 4253 (1998)
Lyoo WS, Ghim HD, Yeum JH, Park CS, Yoon WJ, Noh TH, Shin DY, US Patent, 20040068039A1 (2004)
Lyoo WS, Ha WS, Polymer, 37(14), 3121 (1996)
Lyoo WS, Kim BC, Ha WS, Polym. J., 30, 424 (1998)
Lyoo WS, Han SS, Kim JH, Yoon WS, Lee CJ, Kwon IC, Lee J, Ji BC, Han MH, Die Angew. Makromol. Chem., 271, 46 (1999)
Fukae R, Kawakami K, Yamamoto T, Sangen O, Kako T, Kamachi M, Polym. J., 27, 1257 (1995)
Lyoo WS, Kim JH, Do Ghim H, Polymer, 42(14), 6317 (2001)
Lyoo WS, Kim SS, Ghim HD, Kim JP, Lee SS, J. Appl. Polym. Sci., 85(9), 1992 (2002)
Lyoo WS, Do Ghim H, Kim JH, Noh SK, Yeum JH, Ji BC, Jung HT, Blackwell J, Macromolecules, 36(14), 5428 (2003)
Lyoo WS, Yeum JH, Ghim HD, Lee JS, Ji BC, Yoon NS, Ha JB, Lee J, J. Appl. Polym. Sci., 90(1), 227 (2003)
Lyoo WS, Park CS, Yeum JH, Ji BC, Lee CJ, Lee SS, Lee JY, Colloid Polym. Sci., 280, 1075 (2002)
Lyoo WS, Park CS, Kim JH, Ghim GH, Lee JY, Lee J, Lee CJ, J. Appl. Polym. Sci., 88(3), 832 (2003)
Lyoo WS, Kwak JW, Yeum JH, Ji BC, Lee CJ, Noh SK, J. Polym. Sci. A: Polym. Chem., 43(4), 789 (2005)
Yamamoto T, Yoda S, Sangen O, Fukae R, Kamachi M, Polym.J., 21, 1052 (1989)
Yamamoto T, Yoda S, Takase H, Saso T, Sangen O, Fukae R, Kamachi M, Sato T, Polym. J., 23, 185 (1991)
Song DH, Lyoo WS, J. Appl. Polym. Sci., 104(1), 410 (2007)
Kendall JL, Canelas DA, Young JL, DeSimone JM, Chem. Rev., 99(2), 543 (1999)
McHugh MA, Krukonis VJ, Supercritical fluid extraction: Principles and practice, Butterworth-Heineman, Stoneham (1993)
DeSimone JM, Guan Z, Elsbernd CS, Science., 257, 945 (1992)
Desimone JM, Maury EE, Menceloglu YZ, Mcclain JB, Romack TJ, Combes JR, Science, 265(5170), 356 (1994)
Cooper AI, J. Mater. Chem., 10, 207 (2000)
Hsiao YL, Maury EE, Desimone JM, Mawson S, Johnston KP, Macromolecules, 28(24), 8159 (1995)
Park JY, Shim JJ, J. Supercrit. Fluids, 27(3), 297 (2003)
Canelas DA, Betts DE, Desimone JM, Macromolecules, 29(8), 2818 (1996)
Canelas DA, Desimone JM, Macromolecules, 30(19), 5673 (1997)
Canelas DA, Betts DE, DeSimone JM, Yates MZ, Johnston KP, Macromolecules, 31(20), 6794 (1998)
Kurata M, Tsunashima Y, Brandru J, Immergut EH, Polymer Handbook, Wiley, New York (1989)
Naito R, Kobunshi Kagaku., 15, 597 (1958)
Matsuzawa S, Abe Y, Polym. Inter., 41, 53 (1996)
Odian G, Principles of polymerization, Wiley, New York (1981)
Kumar A, Gupta RK, Fundamentals of polymer engineering, CRC (2003)
Oh KS, Bae W, Cho DW, Lee YW, Kim H, Korean J. Chem. Eng., 25(4), 854 (2008)
Giles MR, Hay JN, Howdle SM, Macromol. Rapid Commun., 21(15), 1019 (2000)
Yates MZ, Shah PS, Johnston KP, Lim KT, Webber S, J. Colloid Interface Sci., 227(1), 176 (2000)
O'Neill ML, Yates MZ, Johnston KP, Smith CD, Wilkinson SP, Macromolecules, 31(9), 2838 (1998)
Marten FL, Mark HF, Bikales NM, Meges CG, Kroschwitz JI, Eds., Encyclopedia of polymer science and engineering, Wiley, New York (1985)
Masuda M, in Polyvinyl alcohol developments, Finch CA, Eds., Wiley, New York (1991)
Bikales NM, in Encyclopedia of polymer science and technology, Mark HF, Gaylord NG, Eds., Wiley, New York (1971)
Wu TC, West JC, US Patent, 4,463,138 (1984)
Lyoo WS, Kim BC, Lee CJ, Ha WS, Eur. Polym. J., 33, 785 (1997)
Kamachi M, Tohei Y, Sato T, Fukunishi Y, US Patent, 5,187,226 (1993)
Lyoo WS, Blackwell J, Ghim HD, Macromolecules, 31(13), 4253 (1998)
Lyoo WS, Ghim HD, Yeum JH, Park CS, Yoon WJ, Noh TH, Shin DY, US Patent, 20040068039A1 (2004)
Lyoo WS, Ha WS, Polymer, 37(14), 3121 (1996)
Lyoo WS, Kim BC, Ha WS, Polym. J., 30, 424 (1998)
Lyoo WS, Han SS, Kim JH, Yoon WS, Lee CJ, Kwon IC, Lee J, Ji BC, Han MH, Die Angew. Makromol. Chem., 271, 46 (1999)
Fukae R, Kawakami K, Yamamoto T, Sangen O, Kako T, Kamachi M, Polym. J., 27, 1257 (1995)
Lyoo WS, Kim JH, Do Ghim H, Polymer, 42(14), 6317 (2001)
Lyoo WS, Kim SS, Ghim HD, Kim JP, Lee SS, J. Appl. Polym. Sci., 85(9), 1992 (2002)
Lyoo WS, Do Ghim H, Kim JH, Noh SK, Yeum JH, Ji BC, Jung HT, Blackwell J, Macromolecules, 36(14), 5428 (2003)
Lyoo WS, Yeum JH, Ghim HD, Lee JS, Ji BC, Yoon NS, Ha JB, Lee J, J. Appl. Polym. Sci., 90(1), 227 (2003)
Lyoo WS, Park CS, Yeum JH, Ji BC, Lee CJ, Lee SS, Lee JY, Colloid Polym. Sci., 280, 1075 (2002)
Lyoo WS, Park CS, Kim JH, Ghim GH, Lee JY, Lee J, Lee CJ, J. Appl. Polym. Sci., 88(3), 832 (2003)
Lyoo WS, Kwak JW, Yeum JH, Ji BC, Lee CJ, Noh SK, J. Polym. Sci. A: Polym. Chem., 43(4), 789 (2005)
Yamamoto T, Yoda S, Sangen O, Fukae R, Kamachi M, Polym.J., 21, 1052 (1989)
Yamamoto T, Yoda S, Takase H, Saso T, Sangen O, Fukae R, Kamachi M, Sato T, Polym. J., 23, 185 (1991)
Song DH, Lyoo WS, J. Appl. Polym. Sci., 104(1), 410 (2007)
Kendall JL, Canelas DA, Young JL, DeSimone JM, Chem. Rev., 99(2), 543 (1999)
McHugh MA, Krukonis VJ, Supercritical fluid extraction: Principles and practice, Butterworth-Heineman, Stoneham (1993)
DeSimone JM, Guan Z, Elsbernd CS, Science., 257, 945 (1992)
Desimone JM, Maury EE, Menceloglu YZ, Mcclain JB, Romack TJ, Combes JR, Science, 265(5170), 356 (1994)
Cooper AI, J. Mater. Chem., 10, 207 (2000)
Hsiao YL, Maury EE, Desimone JM, Mawson S, Johnston KP, Macromolecules, 28(24), 8159 (1995)
Park JY, Shim JJ, J. Supercrit. Fluids, 27(3), 297 (2003)
Canelas DA, Betts DE, Desimone JM, Macromolecules, 29(8), 2818 (1996)
Canelas DA, Desimone JM, Macromolecules, 30(19), 5673 (1997)
Canelas DA, Betts DE, DeSimone JM, Yates MZ, Johnston KP, Macromolecules, 31(20), 6794 (1998)
Kurata M, Tsunashima Y, Brandru J, Immergut EH, Polymer Handbook, Wiley, New York (1989)
Naito R, Kobunshi Kagaku., 15, 597 (1958)
Matsuzawa S, Abe Y, Polym. Inter., 41, 53 (1996)
Odian G, Principles of polymerization, Wiley, New York (1981)
Kumar A, Gupta RK, Fundamentals of polymer engineering, CRC (2003)
Oh KS, Bae W, Cho DW, Lee YW, Kim H, Korean J. Chem. Eng., 25(4), 854 (2008)
Giles MR, Hay JN, Howdle SM, Macromol. Rapid Commun., 21(15), 1019 (2000)
Yates MZ, Shah PS, Johnston KP, Lim KT, Webber S, J. Colloid Interface Sci., 227(1), 176 (2000)
O'Neill ML, Yates MZ, Johnston KP, Smith CD, Wilkinson SP, Macromolecules, 31(9), 2838 (1998)
