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Received February 21, 2013
Accepted April 20, 2013
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Fabrication and modification of polyvinylchloride based heterogeneous cation exchange membranes by simultaneously using Fe-Ni oxide nanoparticles and Ag nanolayer: Physico-chemical and antibacterial characteristics
Thin Film Laboratory, Department of Physic, Faculty of Science, Arak University, Arak 38156-8-8349, Iran 1Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran 2Membrane Research Centre, Department of Chemical Engineering, Faculty of Engineering, Razi University, Kermanshah 67149, Iran
A-zendehnam@araku.ac.ir
Korean Journal of Chemical Engineering, June 2013, 30(6), 1265-1271(7), 10.1007/s11814-013-0063-2
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Abstract
Polyvinylchloride-blend-styrene butadiene rubber based nanocomposite cation exchange membranes were prepared by solution casting technique. Iron-oxide nanoparticles and Ag-nanolayer were simultaneously utilized as filler and surface modifier in membrane fabrication. The effects of Ag-nanolayer film thickness on membrane physicochemical and antibacterial characteristics of nanocomposite PVC-blend-SBR/Iron-oxide nanoparticles were studied. SEM images showed membrane roughness decreasing by Ag nanolayer thickness increasing. Membrane charge density and selectivity declined by Ag nanolayer coating up to 5 nm in membranes and then showed increasing trend by more nanolayer thickness. Ionic flux also showed increasing trend. Membranes showed good ability in E-Coli removal. 20 nm Ag-nanolayer coated membrane showed better performance compared to others.
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References
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Shahi VK, Thampy SK, Rangarajan R, J. Membr. Sci., 158(1-2), 77 (1999)
Kerres J, Cui W, Disson R, Neubrand W, J. Membr. Sci., 139(2), 211 (1998)
Pourjafar S, Rahimpour A, Rahimpour M, J. Ind. Eng. Chem., 18(4), 1398 (2012)
Liu ZM, Xu ZK, Wan LS, Wu J, Ulbricht M, J. Membr. Sci., 249(1-2), 21 (2005)
Yan MG, Liu LQ, Tang ZQ, Huang L, Li W, Zhou J, Gu LS, Wei XW, Yu HY, Chem. Eng. J., 145(2), 218 (2008)
Yu HY, Xie Y, Hu MX, Wang JL, Wang SY, Xu ZK, J. Membr. Sci., 254(1-2), 219 (2005)
Sardohan T, Kir E, Gulec A, Cengeloglu Y, Sep. Purif. Technol., 74(1), 14 (2010)
Hosseini SM, Madaeni SS, Khodabakhshi AR, Zendehnam A, J. Membr. Sci., 365(1-2), 438 (2010)
Wiks ES, Industrial Polymers Handbook: Products, Processes, Application, Wiley-VCH Press, Germany (2001)
Mark JE, Polymer Data Handbook, Oxford University Press, New York (1999)
Harper CA, Handbook of Plastic and Elastomers, McGraw-Hill, New York (1975)
Erertovr L, Physics of Thin Films, Plenum Press, 2nd Ed. (1986)
Chaloupka K, Malam Y, Seifalian AM, Trends Biotechnol., 28, 580 (2010)
Sondi I, Salopek-Sondi B, J. Colloid Interface Sci., 275(1), 177 (2004)
Wei D, Sun W, Qian W, Ye Y, Ma X, Carbohyd. Res., 344, 2375 (2009)
Tang B, Wang JF, Xu SP, Afrin T, Xu WQ, Sun L, Wang XG, J. Colloid Interface Sci., 356(2), 513 (2011)
Li XF, Wang Z, Lu H, Zhao CJ, Na H, Zhao C, J. Membr. Sci., 254(1-2), 147 (2005)
Nagarale RK, Shahi VK, Thampy SK, Rangarajan R, React.Funct. Polym., 61, 131 (2004)
Nagarale RK, Gohil GS, Shahi VK, Rangarajan R, Colloids Surf. A: Physicochemical and Engineering Aspects., 251, 133 (2004)
Lide DR, CRC Handbook of Chemistry and Physics, 87th Ed., CRC press, Boca Raton, FL (2006-2007).
