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In relation to this article, we declare that there is no conflict of interest.
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Received March 30, 2013
Accepted May 21, 2013
articles This is an Open-Access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/bync/3.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.
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Recovery and enrichment of heavy metals using new hybrid Donnan dialysis systems combining cation exchange textile and solvent impregnated resin

Chemistry Faculty, Hydrometallurgy and Inorganic Molecular Chemistry Laboratory, University of Sciences and Technology (USTHB), BP 32, El-Alia, 16111 Bab Ezzouar, Algiers, Algeria
gebesadz@gmail.com
Korean Journal of Chemical Engineering, July 2013, 30(7), 1485-1492(8), 10.1007/s11814-013-0094-8
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Abstract

The purpose of this work is to apply Donnan dialysis coupled with the cation exchange membrane (CMX), the cation exchange grafted textile (CET) and the solvent impregnated resin (SIR) for recovery and enrichment of heavy metal ions from dilute solutions. The influence of some analytical parameters was investigated. The transport results show that the three barriers enhance the diffusion of silver, lead and copper, but the osmosis phenomenon is limited when the transport is carried out through CET and the SIR. The results of enrichments indicate that SIR and CET increase the enrichment factor of less hydrated ions. For instance, and for a volume ratio equal to 10, the values of silver enrichment factor obtained for (CMX/CMX/CMX), (CMX/CET/CMX) and (CMX/SIR/CMX) are equal to 2.5, 8.92 and 4.98, respectively. In addition, the use of SIR improves the enrichment of lead, whereas the CET improves the silver's one.

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