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Received June 19, 2012
Accepted June 3, 2013
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Poly[1-(N,N-bis-carboxymethyl)amino-3-allylglycerol-co-dimethylacrylamide] brushes grafted onto siliceous support for preconcentration and determination of cobalt (II) in human plasma and environmental samples
Homayon Ahmad Panahi†
Mahshid Nikpour Nezhati
Rohollah Abedini Kashkoieh
Elham Moniri1
Igor Yu. Galaev2
Department of Chemistry, Central Tehran Branch, Islamic Azad University, Shahrak Ghods, Simaye Iran, Tehran, Iran 1Department of Chemistry, Varamin (Pishva) Branch, Islamic Azad University, Shahrak Naghsh Jahan, Pishva, Iran 2DSM Food Specialties, B.V. Delft The Netherlands
h.ahmadpanahi@iauctb.ac.ir
Korean Journal of Chemical Engineering, September 2013, 30(9), 1722-1728(7), 10.1007/s11814-013-0100-1
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Abstract
A chelating matrix prepared by surface grafting of polymer containing a functional monomer, poly[1-(N,Nbis-carboxymethyl)amino-3-allylglycerol-co-methylacrylamide] (poly(AGE/IDA-co-DMAA) onto a modified silica. The silica surface was modified by silylation with 3-mercaptopropyltrimethoxysilane followed by graft polymerization. Monomer of allyl glycidyl ether-iminodiacetic acid was synthesized by reaction of allyl glycidyl ether with iminodiacetic acid. The chelating sorbent can be reused for 15 cycles of sorption-desorption without any significant change in sorption capacity. The profile of cobalt uptake on the sorbent reflects good accessibility of chelating sites in poly(AGE/IDA-co-DMAA)-grafted silica gel. The equilibrium adsorption data of Co(II) on modified sorbent were analyzed by Langmuir, Freundlich, Temkin and Redlich-Peterson models. The method was applied for cobalt ions determination in human plasma and sea water sample with satisfactory results.
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Kumar M, Rathore DPS, Singh AK, Talanta., 51, 1187 (2000)
Gurnani V, Singh AK, Venkataramani B, Talanta., 61, 889 (2003)
