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Received April 4, 2013
Accepted July 1, 2013
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Selective recovery of acetone-butanol-ethanol from aqueous mixture by pervaporation using immobilized ionic liquid polydimethylsiloxane membrane
Department of Biological Engineering, Inha University, Incheon 402-751, Korea 1Department of Chemical Engineering and Nano-Bio Technology, Hannam University, Daejeon 305-811, Korea
Korean Journal of Chemical Engineering, September 2013, 30(9), 1804-1809(6), 10.1007/s11814-013-0116-6
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Abstract
An effective in situ recovery of acetone, butanol and ethanol (ABE) from fermentation broth is requisite to overcome the low productivity of ABE production. Pervaporation has proven to be one of the best methods for recovering ABE from fermentation broth. We fabricated an immobilized ionic liquid-polydimethylsiloxane (PDMS) membrane in which a [Tf2N]. based ionic liquid covalently bound to the PDMS backbone polymer and used it to recover ABE from aqueous solution by pervaporation. Permeate flux of immobilized IL-PDMS membrane was 7.8 times higher than that of conventional supported IL-PDMS membrane (where ILs are physically absorbed on the supported membrane). Butanol enrichment factor of immobilized IL-PDMS membrane was three-times higher than that of PDMS membrane. In addition, high enrichment factor both to acetone and ethanol as well as high operational stability of immobilized IL-PDMS membrane can enhance the efficacy of ABE recovery by employing this membrane.
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References
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Ezeji TC, Qureshi N, Blaschek HP, Appl. Microbiol. Biotechnol., 63(6), 653 (2004)
Ha SH, Mai NL, Koo YM, Process Biochem., 45, 1899 (2010)
Ikegami T, Negishi H, Sakaki K, J. Chem. Technol. Biotechnol., 86(6), 845 (2011)
Izak P, Schwarz K, Ruth W, Bahl H, Kragl U, Appl. Microbiol. Biotechnol., 78(4), 597 (2008)
Matsumura M, Kataoka H, Sueki M, Araki K, Bioprocess Biosyst.Eng., 3, 93 (1988)
Qureshi N, Maddox IS, Food Bioprod Process., 83, 43 (2005)
Qureshi N, Meagher MM, Huang J, Hutkins RW, J. Membr. Sci., 187(1-2), 93 (2001)
Liu GP, Wei W, Wu H, Dong XL, Jiang M, Jin WQ, J. Membr. Sci., 373(1-2), 121 (2011)
Boddeker KW, Gatfield IL, Jahnig J, Schorm C, J. Membr. Sci., 137(1-2), 155 (1997)
Wijmans JG, Baker RW, J. Membr. Sci., 107(1-2), 1 (1995)
George SC, Thomas S, Prog. Polym. Sci., 26, 985 (2001)
Fadeev AG, Meagher MM, Chem. Commun., 295 (2001)
Jitesh K, Pangarkar V, Niranjan K, Bioseparation., 9, 145 (2000)
Fadeev AG, Meagher MM, Kelley SS, Volkov VV, J. Membr. Sci., 173(1), 133 (2000)
Vrana DL, Meagher MM, Hutkins RW, Duffield B, Sep.Sci. Technol., 28, 2167 (1993)
Hussey CL, Pure Appl. Chem., 60, 1763 (1988)
Welton T, Chem. Rev., 99(8), 2071 (1999)
Wasserscheid P, Keim W, Angew. Chem., Int. Ed., 39, 3772 (2000)
Huddleston JG, Rogers RD, Chem. Commun., 1765 (1998)
Seddon KR, J. Chem. Technol. Biotechnol., 68(4), 351 (1997)
Yu J, Li H, Liu HZ, Chem. Eng. Commun., 193(11), 1422 (2006)
Izak P, Friess K, Hynek V, Ruth W, Fei Z, Dyson JP, Kragl U, Desalination, 241(1-3), 182 (2009)
Kohoutova M, Sikora A, Hovorka S, Randova A, Schauer J, Tisma M, Setnickova K, Petrickovic R, Guernik S, Greenspoon N, Izak P, Eur. Polym. J., 45, 813 (2009)
Kohoutova A, Sikora A, Hovorka S, Randova A, Schauer J, Poloncarzora M, Izak P, Desalin Water Treat., 14, 78 (2010)
Neel J, Ed., Introduction to pervaporation, Elsevier, Amsterdam (1991)
Alvira P, Tomas-Pejo E, Ballesteros M, Negro MJ, Bioresour. Technol., 101(13), 4851 (2010)
Lee SH, Lee SB, Chem. Commun., 3469 (2005)
Zhang WD, Sun W, Yang J, Ren ZQ, Appl. Biochem. Biotechnol., 160(1), 156 (2010)
