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Received April 25, 2013
Accepted June 10, 2013
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Adsorption thermodynamics and kinetics of disperse dye on poly(p-phenylene benzobisoxazole) fiber pretreated with polyphosphoric acid
1Textile Institute, Sichuan University, Chengdu 610065, P. R. China 2Bureau of Quartermaster Military Representation of the General Logistics Department, PLA, Beijing 100071, P. R. China 3Department of Dyeing and Chemistry, Chengdu Textile College, Chengdu 611731, P. R. China 4Quartermaster Equipment Institute of General Logistics Department, PLA, Beijing 100010, P. R. China, Korea
zhupxscu@163.com
Korean Journal of Chemical Engineering, September 2013, 30(9), 1810-1818(9), 10.1007/s11814-013-0103-y
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Abstract
Adsorption thermodynamic and kinetic studies of C. I. disperse dye 60 on PBO fiber pretreated with polyphosphoric acid (PPA) were carried out under the conditions of pH 6.0±0.2, initial dye concentration 0.05-1.0 g/L and liquor ratio 2,000 : 1. The results showed that the equilibrium adsorption isotherm of the disperse dye on the pretreated PBO fiber was a Langmuir-Nernst mixed Model and the saturated adsorption capacity of the turning point was 1.046mg/g. The thermodynamic parameters were calculated by the equilibrium adsorption isotherm, such as standard affinity, enthalpy change and entropy change, which indicated that the adsorption of disperse dye on the pretreated PBO fiber was an exothermic process. Based on the thermodynamic and kinetic data, the adsorption of the dye on the pretreated PBO fiber was a kinetics controlled process, and the disperse dye could only diffuse into the surface layer of pretreated PBO fiber. Meanwhile, the adsorption kinetics of disperse dye on pretreated PBO fiber well agreed with a pseudofirst-order kinetic model.
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Mao YH, Guan Y, Zheng QK, Feng XN, Wang XX, Cellulose., 18, 271 (2011)
Chiou MS, Li HY, Chemosphere., 50, 1095 (2003)
Aspland JR, Bird CL, J. Soc. Dyers Colour., 77, 9 (1961)
Gerber H, J. Soc. Dyers Colour., 110, 375 (1994)
Kim TK, Son YA, Lim YJ, Dyes Pigm., 72, 246 (2007)
Bird CL, Harris MP, J. Soc. Dyers Colour., 73, 199 (1957)
Park KH, Casetta M, Koncar V, Color. Technol., 118, 319 (2002)
Vickerstaff T, The physical chemistry of dyeing, London, Oliver & Boyd (1954)
Chairat M, Rattanaphani S, Bremner JB, Rattanaphani V, Dyes Pigm., 64, 231 (2005)
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Rattee ID, Breuer MM, The physical chemistry of dye adsorption, London, Academic Press (1974)
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